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The Jarzynski equality equates the mean of the exponential of the negative of the work (per fixed temperature) done by a changing Hamiltonian on a system, initially in thermal equilibrium at that temperature, to the ratio of the final to…
Recently, Jarzynski suggested a striking thermodynamic equation that relates free energy change of a system and work done on the system during arbitrary nonequilibrium processes, which has been believed to hold irrespective of detailed…
Firstly the fluctuation theorems (FT) for expended work in a driven nonequilibrium system, isolated or thermostatted, together with the ensuing Jarzynski work-energy (W-E) relationships, will be discussed and reobtained. Secondly, the…
Entropy production is a key quantity in any finite-time thermodynamic process. It is intimately tied with the fundamental laws of thermodynamics, embodying a tool to extend thermodynamic considerations all the way to non-equilibrium…
Most natural and engineered processes, such as biomolecular reactions, protein folding, and population dynamics, occur far from equilibrium and, therefore, cannot be treated within the framework of classical equilibrium thermodynamics. The…
Despite its simplicity, it seems to my best of knowledge that the possibly simplest approach towards deriving equations governing irreversible thermodynamics from gas-kinetic considerations within the framework of classical mechanics has…
A quantum analogue of the Jarzynski equality is constructed. This equality connects an ensemble average of exponentiated work with the Helmholtz free-energy difference in a nonequilibrium switching process subject to a thermal heat bath. To…
We study the quantum Jarzynski relation for driven quantum models embedded in various environments. We do so by generalizing a proof presented by Mukamel [Phys. Rev. Lett 90, 170604 (2003)] for closed quantum systems. In this way, we are…
Examples of irreversible thermodynamic theory of nonlocal phenomena are given, based on generalized entropy current. Thermodynamic currents and forces are identified to derive the Guyer-Krumhansl and Cahn-Hilliard equations. In the latter…
We derive a general information-theoretic equality for a system undergoing two projective measurements separated by a general temporal evolution. The equality implies the non-negativity of the mutual information between the measurement…
The total entropy production fluctuations are studied in some exactly solvable models. For these systems, the detailed fluctuation theorem holds even in the transient state, provided initially the system is prepared in thermal equilibrium.…
Stochastic thermodynamics extends the notions and relations of classical thermodynamics to small systems that experience strong fluctuations. The definitions of work and heat and the microscopically reversible condition are two key concepts…
The claims by Baras, Garcia, and Malek Mansour [Phys. Rev. E 107, 014106 (2023)] on the validity of path thermodynamics are ill founded and contradict well known results. Following up on a previous comment, I show that, for both models of…
There is a relation between the irreversibility of thermodynamic processes as expressed by the breaking of time-reversal symmetry, and the entropy production in such processes. We explain on an elementary mathematical level the relations…
We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…
This work is concerned with model reduction of stochastic differential equations and builds on the idea of replacing drift and noise coefficients of preselected relevant, e.g. slow variables by their conditional expectations. We extend…
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and…
In this work, I derive the time-dependent probability density function of classical observables using the Hamiltonian mechanics approach, extending the notion of fluctuation theorems for any observables. In particular, the time-dependent…
We propose a formal extension of thermodynamics and kinetic theories to a larger class of entropy functionals. Kinetic equations associated to Boltzmann, Fermi, Bose and Tsallis entropies are recovered as a special case. This formalism…
Thermodynamic uncertainty relations have emerged as universal bounds on current fluctuations in non-equilibrium systems. Here we derive a new bound for a particular class of run-and-tumble type processes using the mathematical framework of…