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Colloidal cuboids have the potential to self-assemble into biaxial liquid crystal phases, which exhibit two independent optical axes. Over the last few decades, several theoretical works predicted the existence of a wide region of the phase…

软凝聚态物质 · 物理学 2021-06-01 Effran Mirzad Rafael , Daniel Corbett , Alejandro Cuetos , Alessandro Patti

Biaxial nematic ($N_B$) liquid crystals have been indicated as promising candidates for the design of next-generation displays with novel electro-optical properties and faster switching times. While at the molecular scale their existence is…

软凝聚态物质 · 物理学 2022-09-13 Álvaro Rodríguez-Rivas , Alessandro Patti , Alejandro Cuetos

Monte Carlo simulations were used to study the assembly of binary mixtures of hard disks with squares, where the components have size ratios that optimize their co-assembly into compositionally disordered solids. It is observed that, along…

软凝聚态物质 · 物理学 2020-04-14 B. P. Prajwal , Fernando A. Escobedo

We investigate the phase behavior of colloidal suspensions of board-like particles under the effect of an external field and assess the still disputed occurrence of the biaxial nematic (N$_\text{B}$) liquid crystal phase. The external field…

软凝聚态物质 · 物理学 2021-07-22 Alejandro Cuetos , Effran Mirzad Rafael , Daniel Corbett , Alessandro Patti

The rich mesophase polymorhism and the phase sequence of board-like colloids depends critically on their shape anisometry. Implementing extensive Monte Carlo simulations, we calculated the full phase diagram of sterically interacting…

软凝聚态物质 · 物理学 2013-09-10 Stavros D. Peroukidis , Alexandros G. Vanakaras

The minimal ingredient to generate a biaxial liquid crystalline ordering is usually considered to be the strongly biaxial interactions breaking the cylindrical symmetry of the uniaxial molecules. Although there is no fundamental reason to…

软凝聚态物质 · 物理学 2018-12-05 Tushar Kanti Bose

Inspired by the observations of a remarkably stable biaxial nematic phase [E.v.d. Pol et al., Phys. Rev. Lett. 103, 258301 (2009)], we investigate the effect of size polydispersity on the phase behavior of a suspension of boardlike…

软凝聚态物质 · 物理学 2015-05-28 S. Belli , A. Patti , M. Dijkstra , R. van Roij

Investigations of the phase diagram of biaxial liquid crystal systems through analyses of general Hamiltonian models within the simplifications of mean-field theory (MFT), as well as by computer simulations based on microscopic models, are…

软凝聚态物质 · 物理学 2015-09-15 B. Kamala Latha , Regina Jose , K. P. N. Murthy , V. S. S. Sastry

Field-induced reorientation of colloidal particles is especially relevant to manipulate the optical properties of a nanomaterial for target applications. We have recently shown that surprisingly feeble external stimuli are able to transform…

软凝聚态物质 · 物理学 2021-07-07 Effran Mirzad Rafael , Luca Tonti , Daniel Corbett , Alejandro Cuetos , Alessandro Patti

Colloidal particles suspended in liquid crystals can exhibit various effective anisotropic interactions that can be tuned and utilized in self-assembly processes. We simulate a two-dimensional system of hard disks suspended in a solution of…

软凝聚态物质 · 物理学 2020-07-30 David Müller , Tobias A. Kampmann , Jan Kierfeld

Using a version of density-functional theory which combines Onsager approximation and fundamental-measure theory for spatially nonuniform phases, we have studied the phase diagram of freely rotating hard rectangles and hard discorectangles.…

软凝聚态物质 · 物理学 2009-11-10 Yuri Martinez-Raton , Enrique Velasco , Luis Mederos

Colloidal droplets are used in a variety of practical applications. Some of these applications require particles of different sizes. These include medical diagnostic methods, the creation of photonic crystals, the formation of…

软凝聚态物质 · 物理学 2024-04-04 P. A. Zolotarev , K. S. Kolegov

We extend our previous work on monolayers of uniaxial particles [J. Chem. Phys. 140, 204906 (2014)] to study the effect of particle biaxiality on the phase behavior of liquid-crystal monolayers. Particles are modelled as board-like hard…

软凝聚态物质 · 物理学 2015-06-23 Miguel Gonzalez-Pinto , Yuri Martinez-Raton , Enrique Velasco , Szabolcs Varga

We use computer simulations to study the existence and stability of a biaxial nematic $N_b$ phase in systems of hard polyhedral cuboids, triangular prisms, and rhombic platelets, characterized by a long ($L$), medium ($M$), and short ($S$)…

软凝聚态物质 · 物理学 2018-05-09 Simone Dussi , Nikos Tasios , Tara Drwenski , René van Roij , Marjolein Dijkstra

Monte Carlo simulation performed on a lattice system of biaxial molecules possessing $D_{2h}$ symmetry and interacting with a second rank anisotropic dispersion potential yields three distinct macroscopic phases depending on the biaxiality…

软凝聚态物质 · 物理学 2012-05-31 Nababrata Ghoshal , Kisor Mukhopadhyay , Soumen Kumar Roy

We study non-equilibrium phases for interacting two-dimensional self-propelled particles with isotropic pair-wise interactions using a persistent kinetic Monte Carlo (MC) approach. We establish the quantitative phase diagram, including the…

软凝聚态物质 · 物理学 2019-04-17 Juliane U. Klamser , Sebastian C. Kapfer , Werner Krauth

We perform Monte Carlo simulations of a simplified two-dimensional model for colloidal hard spheres in an external uniaxial AC electric field. Experimentally, the external field induces dipole moments in the colloidal particles, which in…

软凝聚态物质 · 物理学 2015-05-28 Ahmad M. Almudallal , Ivan Saika-Voivod

We perform Dynamic Monte Carlo simulations to investigate the equilibrium dynamics of hard colloidal cuboids in oblate and prolate nematic liquid crystals. In particular, we characterise the particles' diffusion along the nematic director…

软凝聚态物质 · 物理学 2020-05-27 Alejandro Cuetos , Alessandro Patti

Equilibrium director structures in two thin hybrid planar films of biaxial nematics are investigated through Markov chain Monte Carlo simulations based on a lattice Hamiltonian model within the London dispersion approximation. While the…

软凝聚态物质 · 物理学 2018-12-27 B. Kamala Latha , G. Sai Preeti , K. P. N. Murthy , V. S. S. Sastry

The generation of nanoscale square and stripe patterns is of major technological importance since they are compatible with industry-standard electronic circuitry. Recently, a blend of diblock copolymer interacting via hydrogen-bonding was…

软凝聚态物质 · 物理学 2009-11-13 Carlos I. Mendoza , Erasmo Batta
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