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Ferroelectricity at room temperature has been demonstrated in nanometer-thin quasi 2D croconic acid thin films, by the polarization hysteresis loop measurements in macroscopic capacitor geometry, along with observation and manipulation of…

The ground-state polarization of PbTiO3 thin films is studied using a microscopic effective Hamiltonian with parameters obtained from first-principles calculations. Under short-circuit electrical boundary conditions, (001) films with…

材料科学 · 物理学 2009-10-31 Ph. Ghosez , K. M. Rabe

The Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) ceramics were successfully prepared by sol-gel process, and sintered at 1420 degree. The effect of sintering times (2, 4 and 6 h) on structural, microstructural, electric properties, energy storage, and…

材料科学 · 物理学 2021-02-03 H. Mezzourh , S. Belkhadir , D. Mezzane , M. Amjoud , E. Choukri , A. Lahmar , Y. Gagou , Z. Kutnjak , M. El Marssi

We consider the polarization of thermal emission in the near-field of various materials including dielectrics and metallic systems with resonant surface modes. We find that at thermal equilibrium, the degree of polarization exhibits spatial…

光学 · 物理学 2016-05-25 Manabu Machida , Evgenii Narimanov , John C. Schotland

Using first-principles calculations, we predict a lightweight room-temperature ferroelectric carbon-boron framework in a host/guest clathrate structure. This ferroelectric clathrate, with composition ScB$_3$C$_3$, exhibits high polarization…

材料科学 · 物理学 2020-09-18 Li Zhu , Timothy A. Strobel , R. E. Cohen

The electrocaloric properties of BaTiO$_3$-based lead-free ferroelectric materials have been widely investigated. One approach to achieving a large electrocaloric response is to exploit the substantial polarization change associated with…

材料科学 · 物理学 2025-07-11 M. Karakaya , I. Gurbuz , L. Fulanovic , U. Adem

In quantum materials, degeneracies and frustrated interactions can have a profound impact on the emergence of long-range order, often driving strong fluctuations that suppress functionally relevant electronic or magnetic phases. Engineering…

We discuss the particle size driven tunability of the coexistence of ferromagnetism and ferroelectricity in Pr0.67Ca0.33MnO3(PCMO) with the help of x ray diffraction, magnetization, impedance spectroscopy, and remanent polarization…

强关联电子 · 物理学 2014-12-25 Vinay Kumar Shukla , Soumik Mukhopadhyay , Kalipada Das , A. Sarma , I. Das

The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

The thermal conductivity of polycrystalline bulk PZT (lead-zirconate-titanate) has been investigated according to electrical boundary conditions and poling. The thermal conductivity of poled PZT was measured in the poling direction for open…

In contrast to ordinary ferroelectrics where the temperature, Tm, of the permittivity maximum monotonically increases with bias field, E, in (1-x)PbMg1/3Nb2/3O3-(x)PbTiO3 (0<x<0.35) single crystals, Tm was found to remain constant or…

A wake-up free Hf0.5Zr0.5O2 (HZO) ferroelectric film with the highest remnant polarization (Pr) value to-date was achieved through tuning of the ozone pulse duration, the annealing process, and the metal/insulator interface. The ozone…

材料科学 · 物理学 2021-01-14 Alireza Kashir , Hyung Woo Kim , Seungyeol Oh , Hyunsang Hwang

The structural phase transition in hexagonal BaMnO$_3$ occurring at $T_c$=130 K was studied in ceramic samples using electron and X-ray diffraction, second harmonic generation as well as by dielectric and lattice dynamic spectroscopies. The…

We demonstrate that switching of ferroelectric thin-films sandwiched between metallic electrodes can be controlled by laser-assisted heating, reminiscent of heat-assisted magnetic recording. We employ electrical switching cycles that…

We study the phase transition behavior of the ferroelectric BaTi$_{0.8}$Zr$_{0.2}$O$_3$ in the paraelectric region. The temperature dependencies of thermal, polar, elastic and dielectric properties indicate the presence of local structures…

High-frequency dielectric studies of Bi_0.85Nd_0.15FeO_3 ceramics performed betweeen 100 and 900 K reveal hardening of most polar phonons on cooling below antiferroelectric phase transition, which occurs near 600 K. Moreover, a strong THz…

材料科学 · 物理学 2011-10-18 V. Goian , S. Kamba , S. Greicius , D. Nuzhnyy , S. Karimi , I. M. Reaney

We have measured the bending-induced polarization of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals with compositions at the relaxor-ferroelectric phase boundary. The crystals display very large flexoelectricity, with flexocoupling coefficients an…

材料科学 · 物理学 2015-06-18 Jackeline Narvaez , Gustau Catalan

We are concerned with the modification of liquid crystalline and polar order in SmC* liquids by illumination. In particular we show that non-uniformity due to absorption and also dynamics, can be complex. The variation of polarization with…

软凝聚态物质 · 物理学 2012-10-17 Milos Knezevic , Mark Warner

We report a molecular dynamics study of ab initio quality of the ferroelectric phase transition in crystalline PbTiO3. We model anharmonicity accurately in terms of potential energy and polarization surfaces trained on density functional…

材料科学 · 物理学 2025-04-02 Pinchen Xie , Yixiao Chen , Weinan E , Roberto Car

The evolution of tetragonality with thickness has been probed in epitaxial c-axis oriented PbTiO3 films with thicknesses ranging from 500 down to 24 Angstroms. High resolution x-ray pointed out a systematic decrease of the c-axis lattice…

材料科学 · 物理学 2009-11-10 Celine Lichtensteiger , Jean-Marc Triscone , Javier Junquera , Philippe Ghosez