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相关论文: Autoigniton of n-Butanol at Low to Intermediate Te…

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Autoignition experiments for n-butanol have been performed using a heated rapid compression machine at compressed pressures of 15 and 30 bar, in the compressed temperature range of 675-925 K, and for equivalence ratios of 0.5, 1.0, and 2.0.…

化学物理 · 物理学 2017-06-06 Bryan W. Weber , Kamal Kumar , Yu Zhang , Chih-Jen Sung

Autoignition delay experiments for the isomers of butanol, including n-, sec-, tert-, and iso-butanol, have been performed using a heated rapid compression machine. For a compressed pressure of 15 bar, the compressed temperatures have been…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Kamal Kumar , Chih-Jen Sung

Autoignition experiments of stoichiometric mixtures of s-, t-, and i-butanol in air have been performed using a heated rapid compression machine (RCM). At compressed pressures of 15 and 30 bar and for compressed temperatures in the range of…

化学物理 · 物理学 2017-06-12 Bryan W. Weber , Chih-Jen Sung

Investigation of the autoignition delay of the butanol isomers has been performed at elevated pressure of 15 bar and low to intermediate temperatures of 725-870 K. Stoichiometric mixtures made in nitrogen/oxygen air were studied. For the…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Chih-Jen Sung

The autoignition delays of iso-butanol, oxygen, and nitrogen mixtures have been measured in a heated rapid compression machine (RCM). At compressed pressures of 15 and 30 bar, over the temperature range 800-950 K, and for equivalence ratio…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Shamel Merchant , Chih-Jen Sung , William H. Green

Investigation of the autoignition delay of the butanol isomers has been performed at elevated pressures of 15 bar and 30 bar and low to intermediate temperatures of 680-860 K. The reactivity of the stoichiometric isomers of butanol, in…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Chih-Jen Sung

Butanol, an alcohol which can be produced from biomass sources, has received recent interest as an alternative to gasoline for use in spark ignition engines and as a possible blending compound with fossil diesel or biodiesel. Therefore, the…

New experimental data are collected for methyl-cyclohexane (MCH) autoignition in a heated rapid compression machine (RCM). Three mixtures of MCH/O2/N2/Ar at equivalence ratios of $\phi$=0.5, 1.0, and 1.5 are studied and the ignition delays…

化学物理 · 物理学 2017-06-12 Bryan W. Weber , WIlliam J. Pitz , Marco Mehl , Emma Silke , Alexander C. Davis , Chih-Jen Sung

Experimental and computational investigations are carried out to elucidate the influence of ethanol addition on n-heptane auto-ignition in counterflows. An axisymmetric stream of air, temperature gradually increased, is directed onto the…

化学物理 · 物理学 2024-06-14 Liang Ji , Kalyanasundaram Seshadri , Forman A. Williams

The autoignition delays of mixtures of methyl-cyclohexane (MCH), oxygen, nitrogen, and argon have been studied in a heated rapid compression machine under the conditions $P_C$ = 50 bar, $T_C$ = 690 - 910K. Three different mixture…

Methyl valerate (C$_6$H$_{12}$O$_2$, methyl pentanoate) is a methyl ester and a relevant surrogate component for biodiesel. In this work, we present ignition delays of methyl valerate measured using a rapid compression machine at a range of…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Justin Bunnell , Kamal Kumar , Chih-Jen Sung

Side-by-side comparison of detailed kinetic models using a new tool to aid recognition of species structures reveals significant discrepancies in the published rates of many reactions and thermochemistry of many species. We present a first…

化学物理 · 物理学 2017-12-27 Sai Krishna Sirumalla , Morgan A. Mayer , Kyle E. Niemeyer , Richard H. West

Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane…

To better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar)…

Autoignition delay times, ?, of methyl crotonate, methyl acrylate, ethyl butanoate, ethyl crotonate, and ethyl acrylate were studied in shock tube experiments. A series of mixtures diluted with argon, of varying fuel/oxygen equivalence…

Autoignition of n-heptane droplet/vapor/air mixtures behind an oblique shock wave are studied, through Eulerian-Lagrangian method and a skeletal chemical mechanism. The effects of gas/liquid equivalence ratio (ER), droplet diameter, flight…

流体动力学 · 物理学 2022-12-16 Hongbo Guo , Yong Xu , Ningbo Zhao , Huangwei Zhang

In this work, oblique detonation of n-heptane/air mixture in high-speed wedge flows is simulated by solving the reactive Euler equations with a two-dimensional (2D) configuration. This is a first attempt to model complicated hydrocarbon…

流体动力学 · 物理学 2022-02-11 Hongbo Guo , Yong Xu , Hongtao Zheng , Huangwei Zhang

Butanol has received significant research attention as a second-generation biofuel in the past few years. In the present study, skeletal mechanisms for four butanol isomers were generated from two widely accepted, well-validated detailed…

化学物理 · 物理学 2017-06-08 Xin Hui , Kyle E. Niemeyer , Kyle B. Brady , Chih-Jen Sung

This paper describes an experimental and modeling study of the oxidation of the three isomers of xylene (ortho-, meta- and para-xylenes). For each compound, ignition delay times of hydrocarbon-oxygen-argon mixtures with fuel equivalence…

When designing high-efficiency spark-ignition (SI) engines to operate at high compression ratios, one of the main issues that have to be addressed is detonation development from a pre-ignition front. In order to control this phenomenon, it…

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