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Detailed magnetic studies including magneto-caloric measurements on magnetic multiferroic quadruple perovskite CaMn7O12 are presented. Based on the collective response of Arrott plots and {\Delta}SM (T), a magnetic phase diagram of CaMn7O12…

La0.4Pr0.3Ca0.1Sr0.2MnO3 has been investigated as a potential candidate for room temperature magnetic refrigeration. Results from X-ray powder diffraction reveal an orthorhombic structure with Pnma space group. The electronic and chemical…

材料科学 · 物理学 2020-11-13 Sagar Ghorai , Ridha Skini , Daniel Hedlund , Petter Strom , Peter Svedlindh

Multiferroic materials have undergone extensive research in the past two decades in an effort to produce a sizable room-temperature magneto-electric (ME) effect in either exclusive or composite materials for use in a variety of electronic…

Combining our comprehensive investigations of polarization evolution, soft-mode by Raman scattering and microstructure by TEM, and the results reported in the literatures, we show that prototypical relaxor Pb(Mg1/3Nb2/3)O3 (PMN) is…

材料科学 · 物理学 2013-01-17 Desheng Fu , Hiroki Taniguchi , Mitsuru Itoh , Shigeo Mori

The occurrence at low temperatures of an ultrasharp field-induced transition in phase separated manganites is analyzed. Experimental results show that magnetization and specific heat step-like transitions below 5 K are correlated with an…

Ferroelectric photovoltaic materials are an alternative to semiconductor-based photovoltaics and offer the advantage of above bandgap photovoltage generation. However, there are few known compounds, and photovoltaic efficiencies remain low.…

材料科学 · 物理学 2018-01-31 A. S. Makhort , F. Chevrier , D. Kundys , B. Doudin , B. Kundys

The colossal electroresistance in manganites is a concomitant of the electric field induced insulator-to-metal phase transition. A phenomenological phase transition model is proposed to study this electric field induced collapse of…

材料科学 · 物理学 2007-06-17 S. Dong , C. Zhu , Y. Wang , F. Yuan , K. F. Wang , J. -M. Liu

Low as well as high-temperature electron and x-ray diffraction studies have been carried out on a rare-earth free B-site disordered electron-doped manganite SrMn0.875.Mo0.125O3-{\delta} in the temperature range of 83K to 637K. These studies…

强关联电子 · 物理学 2015-03-23 Aga Shahee , N. P. Lalla

We report on the microwave, terahertz (THz), infrared and Raman spectroscopic studies of $BiMn_{7}O_{12}$ ceramics, shedding more light into the nature of two structural phase transitions and their possible relation with ferroelectricity in…

Short-range polar orders in the relaxor ferroelectric material PbMg$_{1/3}$Nb$_{2/3}$O$_3$-$28\%$PbTiO$_3$ (PMN-28PT) have been studied using neutron diffuse scattering. An external electric field along [110] direction can affect the…

材料科学 · 物理学 2019-08-07 Zhijun Xu , Fei Li , Shujun Zhang , Christopher Stock , Jun Luo , Peter M. Gehring , Guangyong Xu

The proton ordering model for the KH$_{2}$PO$_{4}$ type ferroelectrics is modified by taking into account the dependence of the effective dipole moments on the proton ordering parameter. Within the four-particle cluster approximation we…

材料科学 · 物理学 2015-02-10 A. S. Vdovych , A. P. Moina , R. R. Levitskii , I. R. Zachek

We have observed a sizable positive magnetocapacitance ($\sim$$5-90\%$) in perovskite Pr$_{0.55}$Ca$_{0.45}$MnO$_3$ and bilayer Pr(Sr$_{0.1}$Ca$_{0.9}$)$_2$Mn$_2$O$_7$ system under 5T magnetic field across 20-100 K below the magnetic…

We incorporate single crystal Fe$_3$O$_4$ thin films into a gated device structure and demonstrate the ability to control the Verwey transition with static electric fields. The Verwey transition temperature ($T_V$) increases for both…

强关联电子 · 物理学 2015-06-04 Jared J. I. Wong , Adrian G. Swartz , Renjing Zheng , Wei Han , Roland K. Kawakami

A monoclinic phase was recently discovered near the morphotropic phase boundary in several high-performance piezoelectric perovskite solid solutions, but its properties have not been reported. In this paper the dielectric, piezo- and…

材料科学 · 物理学 2016-08-31 A. A. Bokov , Z. -G. Ye

Magnetically-driven ferroelectric atomic displacements of the order of 10$^{-3} Angstrom have been observed in orthorhombic (perovskite like) YMnO$_3$ by a single-crystal synchrotron x-ray diffraction. The refined polar structure shows the…

Structural, magnetic and electric properties of a metal-ordered perovskite YBaMn2O6 have been studied by means of powder X-ray diffraction, DSC, magnetic susceptibility, and electric resistivity. It is found that this material undergoes a…

强关联电子 · 物理学 2009-11-07 T. Nakajima , H. Kageyama , Y. Ueda

We have investigated the magnetic and dielectric properties of orthorhombic Eu$_{1-y}$Y$_y$MnO$_3$ ($0\leq y\leq 0.6$) single crystals without the presence of the 4$f$ magnetic moments of the rare-earth ions. In $y\geq 0.2$, the…

强关联电子 · 物理学 2015-05-28 Mitsuru Akaki , Masaaki Hitomi , Mizuaki Ehara , Daisuke Akahoshi , Hideki Kuwahara

The symmetric studies on the structure-property relationship of the unpoled and poled states of 0.67BiFeO3-0.33BaTiO3 (0.67BF-0.33BT) were conducted to understand the origin of the morphotropic phase boundary (MPB) in BF-BT. A typical…

材料科学 · 物理学 2020-03-24 Yongxing Wei , Jiahao Shen , Chenxing Bai , Changqing Jin , Weitong Zhu , Ye Tian , Gang Xu

In this paper we study the size effects of the ferroelectric nanotube and nanowire phase diagrams and polar properties allowing for radial stress and depolarization field influence. The approximate analytical expression for the…

材料科学 · 物理学 2009-05-09 Anna N. Morozovska , Maya D. Glinchuk , Eugene A. Eliseev

The investigation of the structural phase transition in the vicinity of the Curie temperature $T_c$ of LiNb$_{1-x}$Ta$_x$O$_3$ crystals is motivated by the expected combination of advantageous high-temperature properties of LiNbO$_3$ and…