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For a single enzyme or molecular motor operating in an aqueous solution of non-equilibrated solute concentrations, a thermodynamic description is developed on the level of an individual trajectory of transitions between states. The concept…

统计力学 · 物理学 2012-05-21 Udo Seifert

The moist-air entropy is defined in Marquet (QJRMS 2011, arXiv:1401.1097) by $\boxed{s = s_{ref} + c_{pd} \: \ln(\theta_{s})}$ in terms of two constant values ($s_{ref}$, $c_{pd}$) and a potential entropy temperature denoted by $\theta_s$.…

大气与海洋物理 · 物理学 2015-03-10 Pascal Marquet

This chapter concerns "control volume analysis", the standard engineering tool for the analysis of flow systems, and its application to entropy balance calculations. Firstly, the principles of control volume analysis are enunciated and…

流体动力学 · 物理学 2014-07-22 Robert K. Niven , Bernd R. Noack

The impact of ion pressure anisotropy on the energy cascade rate of Hall-MHD turbulence with biadiabatic ions and isothermal electrons is evaluated in three-dimensional direct numerical simulations, using the exact (or third-order) law…

Entropic Dynamics is a framework in which dynamical laws are derived as an application of entropic methods of inference. No underlying action principle is postulated. Instead, the dynamics is driven by entropy subject to the constraints…

量子物理 · 物理学 2015-09-11 Ariel Caticha

A statistical physical model of the two basic properties of clusters within a hurricane--their convectivity and rotation--reveals a relationship for the time evolution of a hurricane. Non-doppler data from NEXRAD surface radar imagery, of…

大气与海洋物理 · 物理学 2023-11-28 Bryan Kerman

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

数学物理 · 物理学 2007-05-23 Elliott H. Lieb , Jakob Yngvason

Atmospheric systems incorporating thermal dynamics must be stable with respect to both energy and entropy. While energy conservation can be enforced via the preservation of the skew-symmetric structure of the Hamiltonian form of the…

数值分析 · 数学 2023-10-31 Kieran Ricardo , David Lee , Kenneth Duru

Irreversible processes play a major role in the description and prediction of atmospheric dynamics. In this paper, we present a variational derivation of the evolution equations for a moist atmosphere with rain process and subject to the…

数学物理 · 物理学 2018-04-27 François Gay-Balmaz

The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…

统计力学 · 物理学 2015-12-03 Ian J. Ford

Entropy is a central concept in physics, but can be challenging to calculate even for systems that are easily simulated. This is exacerbated out of equilibrium, where generally little is known about the distribution characterizing simulated…

统计力学 · 物理学 2024-05-09 Samuel D. Gelman , Guy Cohen

In solar wind turbulence, the energy transfer/dissipation rate is typically estimated using MHD third-order structure functions calculated using spacecraft observations. However, the inherent anisotropy of solar wind turbulence leads to…

Uncertainty exists concerning the proper formulation of surface heat fluxes, namely the sum of "sensible" and "latent" heat fluxes, and in fact concerning these two fluxes if they are considered as separate fluxes. In fact, eddy flux of…

大气与海洋物理 · 物理学 2015-03-09 Pascal Marquet

Thermodynamic phase transitions, a central concept in physics and chemistry, are typically controlled by an interplay of enthalpic and entropic contributions. In most cases, the estimation of the enthalpy in simulations is straightforward…

软凝聚态物质 · 物理学 2025-10-30 Yamin Ben-Shimon , Barak Hirshberg , Yohai Bar-Sinai

The aim of this second part of the article is to study the absolute definition of the seawater entropy described in Part I with several concrete cases. Observed vertical profiles and polar transects, as well as analysed surface data, show…

大气与海洋物理 · 物理学 2026-03-27 Pascal Marquet

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

统计力学 · 物理学 2011-06-13 P. D. Gujrati

The theory of thermal macroeconomics (TM) analyses economic phenomena within the mathematical framework of classical thermodynamics, using a set of axioms that apply to the purely macroscopic aspects of an economy [CM]. The theory shows…

综合经济学 · 经济学 2026-03-12 Yihang Luo , Robert S. MacKay , Nick Chater

Many theoretical expressions of dissipation along non-equilibrium processes have been proposed. However, they have not been fully verified by experiments. Especially for systems strongly interacting with environments the connection between…

统计力学 · 物理学 2019-12-03 Ketan Goyal , Xian He , Ryoichi Kawai

Controversy exists regarding the possible existence of a transition between the liquid and glassy states of water. Here we use experimental measurements of the entropy, specific heat, and enthalpy of both liquid and glassy water to…

凝聚态物理 · 物理学 2007-05-23 Francis W. Starr , C. Austen Angell , Robin J. Speedy , H. Eugene Stanley

Tropical cyclones cause significant inland hazards, including wind damage and freshwater flooding, that depend strongly on how storm intensity evolves at and after landfall. Existing theoretical predictions for the time-dependent and…

大气与海洋物理 · 物理学 2021-10-27 Jie Chen , Daniel R. Chavas