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We calculate superconducting transition temperatures ($T_{\rm c}$) in sulfur hydrides H$_{2}$S and H$_{3}$S from first principles using the density functional theory for superconductors. At pressures of $\lesssim$150 GPa, the high values of…

超导电性 · 物理学 2015-07-08 Ryosuke Akashi , Mitsuaki Kawamura , Shinji Tsuneyuki , Yusuke Nomura , Ryotaro Arita

The discovery of high critical temperature T_{c} superconductivity in highly compressed H_{3}S has opened up the question of searching for strong electron-phonon coupling in the hydrides outside the transition metal series. The specific…

超导电性 · 物理学 2019-08-08 P. -H. Chang , S. Silayi , D. A. Papaconstantopoulos , M. J. Mehl

The recent report of superconductivity under high pressure at the record transition temperature of Tc=203K in sulfur hydride has been identified as conventional in view of the observation of an isotope effect upon deuteration. Here it is…

Hydrogen-rich compounds are extensively explored as candidates for a high-temperature superconductors. Currently, the measured critical temperature of $203$ K in hydrogen sulfide (H$_3$S) is among the highest over all-known superconductors.…

超导电性 · 物理学 2016-05-05 A. P. Durajski , R. Szczesniak , L. Pietronero

The rapid variation of the superconductivity Tc in hydride sulfur (H3S) under high pressure [A. Drozdov et al, Nature 525, 73 (2015); M. Einaga et al, arXiv: 1509.03156] in a vicinity Pcr=123GPa is interpreted in terms of the 1st order…

超导电性 · 物理学 2016-01-01 Lev P. Gor'kov , V. Z. Kresin

The maximum value of the superconducting transition temperature Tc due to a phonon-mediated interaction was estimated by Cohen and Anderson in 1972 from ab initio considerations, and found to be about 10 K. McMillan's semi empirical…

超导电性 · 物理学 2007-05-23 M. Weger , J. I. Birman

The discovery of a superconducting phase in sulfur hydride under high pressure with a critical temperature above 200 K has provided a new impetus to the search for even higher $T_c$. Theory predicted and experiment confirmed that the phase…

Recently superconductivity has been discovered at around 200~K in a hydrogen sulfide system and around 260~K in a lanthanum hydride system, both under pressures of about 200 GPa. These record-breaking transition temperatures bring within…

超导电性 · 物理学 2020-07-15 Sabri Elatresh , T. Timusk , E. J. Nicol

Upon thermal annealing at or above room temperature (RT) and high pressure $\it P$ $\sim$ 155 GPa, H$_3$S exhibits superconductivity at $\it T_C$ $\sim$ 200 K. Various theoretical frameworks with strong electron-phonon coupling and Coulomb…

超导电性 · 物理学 2018-08-03 Dale R. Harshman , Anthony T. Fiory

The highest critical temperature of superconductivity Tc has been achieved in cuprates: 133 K at ambient pressure and 164 K at high pressures. As the nature of superconductivity in these materials is still not disclosed, the prospects for a…

超导电性 · 物理学 2014-12-02 A. P. Drozdov , M. I. Eremets , I. A. Troyan

This article updates version 1 by restricting consideration to only the resistive data and excluding the questioned 287.7-K datum reported for carbonaceous sulfur hydride in Snider et al., Nature $\textbf{585}$, 373 (2020). The…

超导电性 · 物理学 2023-07-18 Dale R. Harshman , Anthony T. Fiory

Recently, the discovery of room-temperature superconductivity (SC) was experimentally realized in the fcc phase of LaH$_{10}$ under megabar pressure. Specifically, the isotope effect of $T_{\rm c}$ was measured by the replacement of…

超导电性 · 物理学 2020-06-03 Artur P. Durajski , Radoslaw Szczesniak , Yinwei Li , Chongze Wang , Jun-Hyung Cho

The recent discovery of superconductivity at 190~K in highly compressed H$_{2}$S is spectacular not only because it sets a record high critical temperature, but because it does so in a material that appears to be, and we argue here that it…

超导电性 · 物理学 2015-03-05 N. Bernstein , C. S. Hellberg , M. D. Johannes , I. I. Mazin , M. J. Mehl

The recent discovery of superconductivity at ~39 K in MgB2, by Nagamatsu et al. establishes this simple binary compound as having the highest bulk superconducting transition temperature, Tc, of any non-copper-oxide material. Much of the…

超导电性 · 物理学 2009-11-07 D. G. Hinks , H. Claus , J. D. Jorgensen

The discovery of high-temperature superconductivity in compressed H3S by Drozdov and co-workers (A. Drozdov, et. al., Nature 525, 73 (2015)) heralded a new era in superconductivity. To date, the record transition temperature of Tc = 260 K…

超导电性 · 物理学 2019-06-05 E. F. Talantsev

The superconducting transition temperatures, $T_{\mathrm{c}}$, of La$_{4}$Ni$_{3}$O$_{10+\delta}$($\delta$ = 0.04 and -0.01) were determined under various pressures up to 124.9 GPa by electrical resistance measurements with a diamond anvil…

H$_3$S is believed to the most possible high-temperature superconducting ($T_{\text{c}}$) phase of hydrogen sulfide at $\sim$200 GPa. It's isotope substitution of hydrogen (H) by deuterium (D), however, shows an anomalous $T_{\text{c}}$…

超导电性 · 物理学 2016-07-11 Ying Yuan , Yexin Feng , Lifeng Bian , Dong-Bo Zhang , Xin-Zheng Li

A superconductor is a material that can conduct electricity with no resistance below its critical temperature (Tc). The highest Tc that has been achieved in cuprates1 is 133 K at ambient pressure2 and 164 K at high pressures3. As the nature…

超导电性 · 物理学 2016-03-31 A. P. Drozdov , M. I. Eremets , I. A. Troyan , V. Ksenofontov , S. I. Shylin

Recently BCS superconductivity at 203 K has been discovery in a highly compressed hydrogen sulfide. We use first-principles calculations to systematically examine the effects of partially substituting the chalcogen atoms on the…

超导电性 · 物理学 2016-06-29 Yanfeng Ge , Fan Zhang , Yugui Yao

Due to its low atomic mass hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of a…

超导电性 · 物理学 2016-03-23 José A. Flores-Livas , Antonio Sanna , E. K. U. Gross
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