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We present an x-ray study of freely suspended hexatic films of the liquid crystal 3(10)OBC. Our results reveal spatial inhomogeneities of the bond-orientational (BO) order in the vicinity of the hexatic-smectic phase transition and the…

We present an x-ray study of liquid crystal membranes in the vicinity of hexatic-smectic phase transition by means of angular x-ray cross-correlation analysis (XCCA). By applying two-point angular intensity cross-correlation functions to…

Experimental and theoretical studies of a smectic-hexatic transition in freely suspended films of 54COOBC compound are presented. X-ray investigations revealed a discontinuous first-order transition into the hexatic phase. Moreover, the…

X-ray diffraction studies of the bond-orientational order in the hexatic-B phase of 75OBC and 3(10)OBC compounds are presented. The temperature evolution of an angular profile of a single diffraction peak is analyzed. Close to the…

软凝聚态物质 · 物理学 2016-10-07 I. A. Zaluzhnyy , R. P. Kurta , A. P. Menushenkov , B. I. Ostrovskii , I. A. Vartanyants

The hexatic phase predicted by the theories of two-dimensional melting is characterised by the power law decay of the orientational correlations whereas the in-layer bond orientational order in all the hexatic smectic phases observed so far…

软凝聚态物质 · 物理学 2018-05-16 Lorenzo Agosta , Alfredo Metere , Mikhail Dzugutov

We report results from X-ray scattering studies of the angular structure factor of liquid crystal hexatic-B films. According to the sixfold rotational symmetry of the hexatic-B phase, its characteristic scattering splits into six…

软凝聚态物质 · 物理学 2021-10-25 Ivan A. Zaluzhnyy , Ruslan P. Kurta , Michael Sprung , Ivan A. Vartanyants , Boris I. Ostrovskii

Addressing the nature of an unexpected smectic-A' phase in liquid crystal 54COOBC films, we perform large scale Monte Carlo simulations of a coupled hexatic-nematic XY model. The resulting finite-temperature phase diagram reveals a small…

Simple symmetry considerations would suggest that the transition from the smectic-A phase to the long-range bond orientationally ordered hexatic smectic-B phase should belong to the XY universality class. However, a number of experimental…

无序系统与神经网络 · 物理学 2009-11-07 Mohammad Kohandel , Michel J. P. Gingras , Josh P. Kemp

Comprehensive x-ray scattering studies have characterized the smectic ordering of octylcyanobiphenyl (8CB) confined in the hydrogen-bonded silica gels formed by aerosil dispersions. For all densities of aerosil and all measurement…

软凝聚态物质 · 物理学 2009-11-07 R. L. Leheny , S. Park , R. J. Birgeneau , J. -L. Gallani , C. W. Garland , G. S. Iannacchione

Using a high resolution Monte Carlo simulation technique based on multi-histogram method and cluster-algorithm, we have investigated critical properties of a coupled XY model, consists of a six-fold symmetric hexatic and a three-fold…

软凝聚态物质 · 物理学 2016-08-31 Farhad Shahbazi , rasool Ghanbari

X-ray scattering and polarized microscopic studies of the structure and order parameters in the nematic (N) and heliconical, or the twist-bend nematic (Ntb), phase have been performed as a function of temperature. The nematic orientational…

Molecular arrangement in the chiral smectic phases of the glassforming (S)-4'-(1-methylheptylcarbonyl)biphenyl-4-yl 4-[7-(2,2,3,3,4,4,4-heptafluorobutoxy) heptyl-1-oxy]benzoate is investigated by X-ray diffraction. An increased correlation…

软凝聚态物质 · 物理学 2025-01-15 Aleksandra Deptuch , Natalia Górska , Stanisław Baran , Magdalena Urbańska

We resolve the old riddle related to the critical behavior of the heat capacity near the smectic A -- hexatic second order phase transition. Experiment suggests a "large" positive specific heat critical exponent inconsistent with the…

软凝聚态物质 · 物理学 2016-03-18 E. I. Kats , V. V. Lebedev , A. R. Muratov

An x-ray scattering approach to determine the two-dimensional (2D) pair distribution function (PDF) in partially ordered 2D systems is proposed. We derive relations between the structure factor and PDF that enable quantitative studies of…

软凝聚态物质 · 物理学 2016-09-21 I. A. Zaluzhnyy , R. P. Kurta , A. P. Menushenkov , B. I. Ostrovskii , I. A. Vartanyants

We explain theoretically peculiarities of the smectic A -- hexatic B equilibrium phase coexistence in a finite temperature range recently observed experimentally in free standing smectic films [I.A.Zaluzhnyy et al., Physical Review E,…

软凝聚态物质 · 物理学 2019-09-04 E. I. Kats , V. V. Lebedev , E. S. Pikina

Thermotropic liquid crystals are versatile optical materials that exhibit a state of matter intermediate between liquids and solids. Their properties can change significantly with temperature, pressure, or other external factors, leading to…

Molecular Dynamics simulations have been performed on the orientationally disordered crystal chloroadamantane: a model system where dynamics are almost completely controlled by rotations. A critical temperature T_c = 225 K as predicted by…

材料科学 · 物理学 2009-10-31 F. Affouard , M. Descamps

We study the kinetics of the nematic-isotropic transition in a two-dimensional liquid crystal by using a lattice Boltzmann scheme that couples the tensor order parameter and the flow consistently. Unlike in previous studies, we find the…

软凝聚态物质 · 物理学 2009-11-07 Colin Denniston , Enzo Orlandini , J. M. Yeomans

Recent advances in cold atom experimentation suggest that studies of quantum two-dimensional melting of dipolar molecules, with dipoles aligned perpendicular to ordering plane, may be on the horizon. An intriguing aspect of this problem is…

量子气体 · 物理学 2014-04-02 Georg M. Bruun , David R. Nelson

Using video-microscopy data of a two-dimensional colloidal system the bond-order correlation function G6 is calculated and used to determine the temperature-dependence of both the orientational correlation length xi6 in the isotropic liquid…

软凝聚态物质 · 物理学 2012-10-26 P. Keim , G. Maret , H. H. von Gruenberg
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