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Cu3Nb2O8 is an unusual multiferroic compound that undergoes a series of magnetic ordering at low temperatures. Concurrent development of electric polarization has been reported at TN1 ~25 K corresponding to a non-collinear helicoidal…

强关联电子 · 物理学 2015-06-22 G. Sharma , J. Saha , S. D. Kaushik , V. Siruguri , S. Patnaik

We report remarkable multiferroic effects in polycrystalline Bi2Fe4O9. High-resolution X-ray diffraction shows that this compound has orthorhombic structure. Magnetic measurements confirm an antiferromagnetic transition around 260 K. A…

材料科学 · 物理学 2009-11-13 A. K. Singh , S. D. Kaushik , Brijesh Kumar , A. Venimadhav , P. K. Mishra , V. Siriguri , S. Patnaik

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

Single-crystal samples of LiCu2O2 with spin 1/2 Cu2+ chains of edge-sharing CuO4 square planes (ribbon chains), have been characterized by X-ray diffraction, thermogravimetric analysis, and magnetic measurements. Neither the atomic…

材料科学 · 物理学 2015-05-13 Yukio Yasui , Kenji Sato , Yoshiaki Kobayashi , Masatoshi Sato

The recently observed multiferroic behavior in the s=1/2 chain cuprate LiVCuO_4 (LiCuVO_4) with edge-shared CuO_4 plaquettes and helical spin ordering does not agree with the existing theories such as a spin-current scenario. We argue that…

强关联电子 · 物理学 2009-11-13 A. S. Moskvin , S. -L. Drechsler

We have carried out a detailed experimental investigation on CuO using dielectric constant, ac resistance, Raman spectroscopy and X-ray diffraction measurements at high pressures and room temperature. Both dielectric constant and dielectric…

LiCu2O2 is the first multiferroic cuprate to be reported and its ferroelectricity is induced by complex magnetic ordering in ground state, which is still in controversy today. Herein, we have grown nearly untwinned LiCu2O2 single crystals…

Motivated by the discovery of multiferroicity in the geometrically frustrated triangular antiferromagnet CuCrO$_2$ below its N\'eel temperature $T_N$, we investigate its magnetic and ferroelectric properties using ab initio calculations and…

材料科学 · 物理学 2017-10-23 Ahmed Albaalbaky , Yaroslav Kvashnin , Denis Ledue , Renaud Patte , Raymond Frésard

Different from other magnetically frustrated spinel systems, GeCu$_{2}$O$_{4}$ is a strongly tetragonal distorted spinel cuprate in which edge-sharing CuO$_{2}$ ribbons are running along alternating directions perpendicular to the $c$-axis.…

强关联电子 · 物理学 2018-05-02 L. Zhao , L. Muzica , U. Schwarz , A. C. Komarek

Multiferroic materials, in which ferroelectric and magnetic ordering coexist, are of fundamental interest for the development of multi-state memory devices that allow for electrical writing and non-destructive magnetic read-out operation.…

Ferrimagnetic spinel materials of formula AB2X4, where A and B are transition metals and X is oxygen or sulphur, hold promise for the realization of multiferroic characteristics. In this work, we report synthesis of spinel CoMn2O4 and…

材料科学 · 物理学 2026-04-07 P. Kumar , P. Das , B. K. Kuanr , S. Patnaik

X-ray scattering by multiferroic LuFe2O4 is reported. Below 320 K, superstructure reflections indicate an incommensurate charge order with propagation close to (1/3,1/3,3/2). The corresponding charge configuration, also found by electronic…

The crystal and magnetic structure of multiferroic LiFe(WO$_4$)$_2$ were investigated by temperature and magnetic-field dependent specific heat, susceptibility and neutron diffraction experiments on single crystals. Considering only the two…

Temperature measurements of dielectric permittivity are performed for nonstoichiometric ferroelectric lead germanate Pb$_{4.95}$Ge$_3$O$_{11}$ and multiferroic solid solution [N(C$_2$H$_5$)$_4$]$_2$CoClBr$_3$. Unlike the heat capacity data,…

材料科学 · 物理学 2024-01-18 I. S. Girnyk , B. I. Horon , V. B. Kapustianyk , O. S. Kushnir , R. Y. Shopa

Magnetic susceptibility, specific heat, dielectric, and electric polarization of LiCuFe2(VO4)3 have been investigated. Two sequential antiferromagnetic transitions at TN1 ~ 9.95 K and TN2 ~ 8.17 K are observed under zero magnetic field.…

Synthesis and extensive structural, pyroelectric, magnetic, dielectric and magneto-electric characterizations are reported for polycrystalline Co4Nb2O9 towards unraveling the multiferroic state especially in reference to the magnetic spin…

材料科学 · 物理学 2016-12-07 P. Srivastava , S. Chaudhary , J. Saha , S. Patnaik

We report on neutron diffraction, thermal expansion, magnetostriction, dielectric, and specific heat measurements on polycrystalline FeCr2S4 in external magnetic fields. The ferrimagnetic ordering temperatures $T_{\mathrm{C}}\approx 170$ K…

Neutron diffraction measurements on multiferroic LuFe2O4 show changes in the antiferromagnetic (AFM) structure characterized by wavevector q = (1/3 1/3 1/2) as a function of electric field cooling procedures. The increase of intensity from…

强关联电子 · 物理学 2011-11-09 A. M. Mulders , M. Bartkowiak , J. R. Hester , E. Pomjakushina , K. Conder

Measurements of ferroelectric polarization and dielectric constant were done on $R$Mn$_2$O$_5$ ($R$=Tb, Dy, and Ho) with applied hydrostatic pressures of up to 18 kbar. At ambient pressure, distinctive anomalies were observed in the…

强关联电子 · 物理学 2009-11-13 C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Wang , S. Park , S-W. Cheong , M. M. Gospodinov , C. W. Chu

We present results of an {\it ab initio} density functional theory study of three bismuth-based multiferroics, BiFeO$_{3}$, Bi$_{2}$FeCrO$_{6}$, and BiCrO$_{3}$. We disuss differences in the crystal and electronic structure of the three…

材料科学 · 物理学 2007-05-23 Pio Baettig , Claude Ederer , Nicola A. Spaldin
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