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Understanding the fundamental properties that dictate photoexcited polarons in materials is critical to tuning their properties. Theoretical models of polarons have only recently been extended to the excited state. Experimental measurements…

材料科学 · 物理学 2025-12-22 Jocelyn L. Mendes , Scott K. Cushing

A combination of Scanning Tunneling Microscopy/Spectroscopy and Density Functional Theory (DFT+U) is used to characterize excess electrons in TiO$_2$ rutile and anatase, two prototypical materials with identical chemical composition but…

Layered two-dimensional (2D) materials MoTe2 have been paid special attention due to the rich optoelectronic properties with various phases. The nonequilibrium carrier dynamics as well as its temperature dependence in MoTe2 are of prime…

强关联电子 · 物理学 2022-01-11 Jiaming Chen , Peng Suo , Wenjie Zhang , Hong Ma , Jibo Fu , Di Li , Xian Lin , Xiaona Yan , Guohong Ma , Jianquan Yao

The evolution of the properties of a finite density electronic system as the electron-phonon coupling is increased are investigated in the Holstein model using the Dynamical Mean-Field Theory (DMFT). We compare the spinless fermion case, in…

强关联电子 · 物理学 2025-12-12 M. Capone , P. Carta , S. Ciuchi

Researchers pursuing advanced photoelectric devices have discovered near room-temperature metal-insulator transitions (MIT) in non-volatile VO2. Despite theoretical investigations suggesting that polaron dynamics mediate the MIT, direct…

Elucidating the details of the electron-phonon coupling in semiconductors and insulators is a topic of pivotal interest, as it governs the transport mechanisms and is responsible for various phenomena such as spectral-weight transfers to…

Electrodynamic properties of La-doped SrTiO3 thin films with controlled elemental vacancies have been investigated using optical spectroscopy and thermopower measurement. In particular, we observed a correlation between the polaron…

材料科学 · 物理学 2015-05-13 Woo Seok Choi , Hyang Keun Yoo , Hiromichi Ohta

The optical properties of quasi-one-dimensional metallic LaTiO$_{3.41}$ are studied for the polarization along the $a$ and $b$ axes. With decreasing temperature modes appear along both directions suggestive for a phase transition. The…

凝聚态物理 · 物理学 2009-11-07 C. A. Kuntscher , M. Dressel , F. Lichtenberg , J. Mannhart , D. van der Marel

We explore polaronic quantum transport in three-dimensional models of disordered organic crystals with strong coupling between electronic and vibrational degrees of freedom. By studying the polaron dynamics in a static disorder environment,…

材料科学 · 物理学 2015-06-03 Frank Ortmann , Stephan Roche

We present a comparative Raman scattering study of metallic rutile oxides (RuO$_2$ and IrO$_2$) and insulating rutiles (TiO$_2$ and SnO$_2$). Temperature-dependent Raman spectra reveal that the metallic compounds exhibit pronounced phonon…

材料科学 · 物理学 2026-05-25 Reshma Kumawat , Shubham Farswan , Simranjeet Kaur , Kaushik Sen

Rare-earth orthoferrites are a promising platform for antiferromagnetic spintronics with a rich variety of terahertz spin and lattice dynamics phenomena. For instance, it has been experimentally demonstrated that the light-driven optical…

We investigate phonon lifetimes in VO2 single crystals. We do so in the metallic state above the metal-insulator transition (MIT), where strong structural fluctuations are known to take place. By combining inelastic X-ray scattering and…

Light-matter interaction allows to achieve non-equilibrium states that are otherwise inaccessible. Motivated by recent experiments that report ferroelectricity -- and even multiferroicity -- in the prototypical diamagnetic band insulator…

材料科学 · 物理学 2026-02-25 Andri Darmawan , Markus E. Gruner , Rossitza Pentcheva

In a solid, electrons can be scattered both by phonons and other electrons. First proposed by Landau, scattering by phonons can lead to a composite entity called a polaron, in which a lattice distortion traps an itinerant electron (or hole)…

材料科学 · 物理学 2023-01-18 Yunfan Liang , Min Cai , Lang Peng , Zeyu Jiang , Damien West , Ying-Shuang Fu , Shengbai Zhang

Oxygen vacancies created in anatase TiO2 by UV photons (80 - 130 eV) provide an effective electron-doping mechanism and induce a hitherto unobserved dispersive metallic state. Angle resolved photoemission (ARPES) reveals that the…

A comprehensive picture of polaron and bipolaron physics is essential to understand the optical absorption spectrum in many materials with electron-phonon interactions. In particular, the finite-temperature properties are of interest since…

强关联电子 · 物理学 2022-10-27 David Jansen , Janez Bonča , Fabian Heidrich-Meisner

We investigate ultrafast dynamics from photoinduced reflectivity of Sr2RhO4 by using femtosecond near-infrared pulses. We observe a clear temperature-dependent anomaly in its electronic dynamics which slows down below 160 K. In addition,…

Exact diagonalization calculations show a continuous transition from delocalized to small polaron behavior as a function of intersite electron-lattice coupling. A transition, found previously at Hartree-Fock level [Yonemitsu et al., Phys.…

凝聚态物理 · 物理学 2008-06-16 J. Lorenzana , A. Dobry

We measured the temperature dependent infrared reflectivity spectra of MnF2 between 4 K and room temperature. We show that the phonon spectrum undergoes a strong renormalization at TN. The ab-initio calculation we performed on this compound…

材料科学 · 物理学 2010-10-20 R. Schleck , Y. Nahas , R. P. S. M. Lobo , J. Varignon , M. B. Lepetit , C. S. Nelson , R. L. Moreira

We study how polaronic states form as a function of time due to strong electron-phonon coupling, starting from a hot electron distribution which is representative of a photo-induced metallic state immediately after laser excitation. For…

强关联电子 · 物理学 2015-03-11 Sharareh Sayyad , Martin Eckstein