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We investigate relative stability, structural properties and electronic structure of various modulated martensites of the magnetic shape memory alloy Mn$_{2}$NiGa by means of density functional theory. We observe that the instability in the…

材料科学 · 物理学 2017-08-23 Ashis Kundu , Markus E. Gruner , Mario Siewert , Alfred Hucht , Peter Entel , Subhradip Ghosh

The impact of shear deformation in $(1\,0\,1)[1\,0\,\bar{1}]$ system of non-modulated (NM) martensite in Ni$_2$MnGa ferromagnetic shape memory alloy is investigated by means of ab initio atomistic simulations. The shear system is associated…

材料科学 · 物理学 2024-11-11 Martin Heczko , Petr Šesták , Hanuš Seiner , Martin Zelený

Structural modulation is a key ingredient behind the extraordinary (magneto)elastic response of Ni-Mn-Ga martensite, yet its link to fine twinned microstructure and twin-boundary supermobility remains unresolved. Here we analyse martensitic…

Understanding the crystal structure of magnetic shape memory alloys is crucial for insights into their unique properties, such as the high mobility of twin boundaries and magnetic field functionality. The complex neutron diffraction…

材料科学 · 物理学 2024-06-25 P. Veřtát , M. Klicpera , O. Fabelo , O. Heczko , L. Straka

The temperature dependent crystal structure analysis in martensitic phase of Ni_2Mn_(1+x)Sn_(1-x) (x = 0.40 and 0.44) magnetic shape memory alloy is performed using X-ray diffraction. The martensitic phase consists of 4-Layered and…

材料科学 · 物理学 2017-01-31 Soumyadipta Pal , Sandeep Singh , Chhayabrita Maji

Influence of disorder, antisite defects, martensite transition and compositional variation on the magnetic properties and electronic structure of Mn$_2$NiGa and Mn$_{1+x}$Ni$_{2-x}$Ga magnetic shape memory alloys have been studied by using…

材料科学 · 物理学 2015-06-17 Sunil Wilfred D'Souza , Tufan Roy , Sudipta Roy Barman , Aparna Chakrabarti

7M orthorhombic modulated structure in the martensite phase of Ni1.8Pt0.2MnGa is reported by powder neutron diffraction study, which indicates that it is likely to exhibit magnetic field induced strain. The change in the unit cell volume is…

材料科学 · 物理学 2012-11-02 Sanjay Singh , K. R. A. Ziebeck , E. Suard , P. Rajput , S. Bhardwaj , A. M. Awasthi , S. R. Barman

The electronic structure of Mn_2NiGa has been studied using density functional theory and photoemission spectroscopy. The lower temperature tetragonal martensitic phase with c/a= 1.25 is more stable compared to the higher temperature…

其他凝聚态物理 · 物理学 2009-11-13 S. R. Barman , S. Banik , A. K. Shukla , C. Kamal , Aparna Chakrabarti

We investigate the effects of Fe and Co substitutions on the phase stability of the martensitic phase, mechanical, electronic and magnetic properties of magnetic shape memory system Mn$_{2}$NiGa by first-principles Density functional…

材料科学 · 物理学 2017-11-15 Ashis Kundu , Sheuly Ghosh , Subhradip Ghosh

Heusler alloys exhibiting magnetic and martensitic transitions enable applications like magnetocaloric refrigeration and actuation based on the magnetic shape memory effect. Their outstanding functional properties depend on low hysteresis…

The magnetic and structural properties of MnAs are studied with ab initio methods, and by mapping total energies onto a Heisenberg model. The stability of the different phases is found to depend mainly on the volume and on the amount of…

材料科学 · 物理学 2009-11-11 Ivan Rungger , Stefano Sanvito

In search for the origins of the extraordinary low twinning stress of Ni-Mn-Ga magnetic shape memory alloys we studied the thermally induced changes of structure in Ni$_{50}$Mn$_{25+x}$Ga$_{25-x}$ ($x$=2.7--3.9) single crystal samples and…

The different crystal structures of ferromagnetic Ni$_2$MnGa have been calculated using density functional theory (DFT) with special emphasis on the modulated structures 10M and 14M. These are important for understanding the stability of…

材料科学 · 物理学 2007-05-23 A. Zayak , W. A. Adeagbo , P. Entel , V. D. Buchelnikov

Magnetic, transport, and x-ray diffraction measurements of ferromagnetic shape memory alloy Ni$_{2.16}$Mn$_{0.84}$Ga revealed that this alloy undergoes an intermartensitic transition upon cooling, whereas no such a transition is observed…

材料科学 · 物理学 2009-11-10 V. V. Khovailo , K. Oikawa , C. Wedel , T. Takagi , T. Abe , K. Sugiyama

High mobility of twin boundaries in modulated martensites of Ni-Mn-Ga-based ferromagnetic shape memory alloys holds a promise for unique magnetomechanical applications. This feature has not been fully understood so far, and in particular it…

In the present work, the aspects of magnetic and structural properties of Ni-Mn-Ga alloys are described in the framework of fist-principles approach and mapped into ternary composition diagrams. The stable atomic arrangement and magnetic…

材料科学 · 物理学 2020-03-23 Yu. Sokolovskaya , O. Miroshkina , V. Sokolovskiy , M. Zagrebin , V. Buchelnikov , A. Zayak

A series of first principles calculations have been carried out in order to discuss electronic structure, phonon dynamics, structural instabilities and the nature of martensitic transformations of the Heusler alloys Ni$_2$Mn(Ga, Ge, Al) and…

材料科学 · 物理学 2009-11-10 A. T. Zayak , P. Entel

The local atomic structure of Ni$_{2+x}$Mn$_{1-x}$Ga with 0 $\le$ $x$ $\le$ 0.16 alloys was explored using Mn and Ga K-edge Extended X-ray Absorption Fine Structure (EXAFS) measurement. Inorder to study the atomic re-arrangements that occur…

材料科学 · 物理学 2009-11-11 P. A. Bhobe , K. R. Priolkar , P. R. Sarode

The local atomic structure of Ni-Mn-Ga alloys was explored using Mn and Ga K-edge extended X-ray fine structure (EXAFS) measurement. The changes occuring in the L1$_0$ sub-cell of the martensitic unit cell and the bond lengths obtained from…

材料科学 · 物理学 2007-05-23 P. A. Bhobe , K. R. Priolkar , P. R. Sarode

In this work, we perform first principles DFT calculations to investigate the interplay between magnetic and structural properties in Ni2MnGa. We demonstrate that the relative stability of austenite (cubic) and non-modulated martensite…

材料科学 · 物理学 2012-04-09 Burak Himmetoglu , Vamshi M. Katukuri , Matteo Cococcioni
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