相关论文: The Theory of SERS on Dielectrics and Semiconducto…
The paper presents briefly some general points of the theory of Surface Enhanced Raman Scattering on metals, semiconductors, dielectrics and graphene. It is pointed out that the reason of SERS on graphene and some other 2D materials is not…
The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of the strongly irregular surface roughness. The main SERS…
The long-range action of surface-enhanced Raman scattering (SERS) is probed via distance-dependent measurements of molecular Raman spectra. To this end, identical SERS substrates composed of irregular silver nanoisland arrays were covered…
The SERS spectrum of hydroquinone, adsorbed on nanoparticles of titanium dioxide is analyzed. It is pointed out that the enhancement is stronger for larger mean size of nanoparticles that is in an agreement with the electrostatic…
The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…
We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…
We suggest a new type of substrates for the Surface Enhanced Raman Scattering measurements with the geometry based on self-similar fractal space filling curves. As an example, we have studied theoretically the dielectric response properties…
Semiconductor-based surface-enhanced Raman spectroscopy (SERS) substrates, as a new frontier in the field of SERS, are hindered by their poor electromagnetic field confinement, and weak light-matter interaction. Metasurfaces, a class of 2D…
A mechanism for additional enhancement of SERS in the nanoparticle-on-mirror scheme is proposed. This new mechanism is based on the use of a substrate made of material with a near-minus-one permittivity. The setup involves a plasmonic…
Giant field enhancement and field singularities are a natural consequence of the commonly employed local-response framework. We show that a more general nonlocal treatment of the plasmonic response leads to new and possibly fundamental…
The paper briefly describes main statements of the theory of the SERS spectra with regards to the single molecule regime, when the enhancement achieves the values . Analysis of the spectra of 4,4-bypyridine, obtained on the dimer lattice of…
Photo-Induced Enhanced Raman Spectroscopy (PIERS) is a new surface enhanced Raman spectroscopy (SERS) modality with an order-of-magnitude Raman signal enhancement of adsorbed analytes over that of typical SERS substrates. Despite the…
Surface-enhanced Raman spectroscopy (SERS) allows single-molecule detection due to the strong field localization occurring at sharp bends or kinks of the metal-vacuum interface. An important question concerns the limits of the signal…
The electromagnetic interaction between Ag nanoparticles on the top of the Si substrate and the incident light has been studied by numerical simulations. It is found that the presence of a dielectric layer with different thickness leads to…
We provide the theoretical framework to understand the phenomenology and statistics of single-molecule (SM) signals arising in Surface-Enhanced Raman Scattering (SERS) under the presence of so-called electromagnetic hot-spots (HS's). We…
The dependence of surface-enhanced Raman scattering (SERS) spectra on the precise axial position of the laser focus relative to a solid nanostructured substrate has received little to no attention in the literature. Here we show this…
The electromagnetic enhancement for surface enhanced Raman spectroscopy (SERS) of graphene is studied by inserting a layer of Al2O3 between epitaxial graphene and Au nanoparticles. Different excitation lasers are utilized to study the…
We discuss the mechanism responsible for the observed improvement in the structural properties of In doped GaSe, a layered material of great current interest. Formation energy calculations show that by tuning the Fermi energy, In can…
The SERS spectra of the phthalocianine molecule, adsorbed on the gallium phosphide substrate are investigated. It is demonstrated that there appear strong lines, which are forbidden in usual Raman scattering. Analysis of the spectra…
Dielectric metasurfaces have introduced a new paradigm for substance detection by exploiting their resonant properties to enhance light-matter interaction. This enhancement can be used for sensing either through refractive index changes or…