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Density functional calculations are performed to study the effect of epitaxial strain on PbZrO3. We find a remarkably small energy difference between the epitaxially strained polar R3c and nonpolar Pbam structures over the full range of…

材料科学 · 物理学 2014-05-15 Sebastian E. Reyes-Lillo , Karin M. Rabe

The centrosymmetric halide perovskites undergo a continuous phase transition from a normal insulator to a topological insulator at the critical value of strain. Contrarily, in noncentrosymmetric halide perovskites, this phase transition is…

材料科学 · 物理学 2023-02-28 Ankita Phutela , Sajjan Shoeran , Saswata Bhattacharya

Rashba spin-orbit coupling (RSOC) facilitates spin manipulation without relying on an external magnetic field, opening up exciting possibilities for advanced spintronic devices. In this work, we examine the effects of crystal momentum ($k$)…

材料科学 · 物理学 2024-09-06 Arjyama Bordoloi , Sobhit Singh

We show here theoretically and experimentally that a Rashba-split electron state inside a ferromagnet can efficiently convert a dynamical spin accumulation into an electrical voltage. The effect is understood to stem from the Rashba…

Near-surface two-dimensional electron gases on the topological insulator Bi$_2$Te$_2$Se are induced by electron doping and studied by angle-resolved photoemission spectroscopy. A pronounced spin-orbit splitting is observed for these states.…

Organometallic lead halide perovskites are highly efficient materials for solar cells and other optoelectronic applications due to their high quantum efficiency and exceptional semiconducting properties. A peculiarity of these perovskites…

Although the structural phase transitions in single-crystal hybrid methyl-ammonium (MA) lead halide perovskites (MAPbX3, X = Cl, Br, I) are common phenomena, they have never been observed in the corresponding nanocrystals. Here we…

应用物理 · 物理学 2020-04-08 Yuri D. Glinka , Rui Cai , Xian Gao , Dan Wu , Rui Chen , Xiao Wei Sun

Hybrid halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them, MAPbI$_3$ where MA stands for the methylammonium cation, exhibits ideal properties for…

材料科学 · 物理学 2017-07-10 A. Koliogiorgos , S. Baskoutas , I. Galanakis

Perovskite solar cells with record power conversion efficiency are fabricated by alloying both hybrid and fully inorganic compounds. While the basic electronic properties of the hybrid perovskites are now well understood, key electronic…

Halide perovskites, such as methylammonium lead bromide (MAPbBr$_3$), host tightly bound three-dimensional excitons which are robust at room temperature. Excellent optical properties of MAPbBr$_3$ allow for designing of optical single-mode…

Hybrid lead halide perovskites exhibit a delicate interplay between average crystallographic symmetry, local structural disorder and A-site orientational dynamics, giving rise to unusual vibrational and electronic behaviour. Here, we…

材料科学 · 物理学 2026-05-13 Xia Liang , Milos Dubajic , Zezhu Zeng , Yang Lu , Johan Klarbring , Samuel D. Stranks , Aron Walsh

Spin splitting of energy bands can be induced by relativistic spin-orbit interactions in materials without inversion symmetry. Whereas polar space group symmetries permit Rashba (R-1) spin splitting with helical spin textures in momentum…

Halide perovskites have emerged as a promising class of materials for photovoltaic applications. A challenge in these applications is how to prevent the crystal structure from degradation to photovoltaically inactive phases, which requires…

材料科学 · 物理学 2024-03-22 Erik Fransson , J. Magnus Rahm , Julia Wiktor , Paul Erhart

The goal of this work is to show how the thermospin polarization current in a quantum ring changes in the presence of Rashba spin-orbit coupling and a quantized single photon mode of a cavity the ring is placed in. Employing the reduced…

介观与纳米尺度物理 · 物理学 2018-04-10 Nzar Rauf Abdullah , Thorsten Arnold , Chi-Shung Tang , Andrei Manolescu , Vidar Gudmundsson

We predict the structural, electronic and optic properties of the inorganic Ge-based halide perovskites AGeX3 (A = Cs, Rb; X = I, Br, Cl) by using first-principles method. In particular, absolute electronic energy band levels are calculated…

材料科学 · 物理学 2018-10-08 Un-Gi Jonga , Chol-Jun Yu , Yun-Hyok Kye , Yong-Guk Choe , Hao Wei , Shuzhou Li

In the quest for exotic superconducting pairing states, the Rashba effect, which lifts the electron-spin degeneracy as a consequence of strong spin-orbit interaction (SOI) under broken inversion symmetry, has attracted considerable…

A nonequilibrium Green's function approach is employed to investigate the spin-Hall effect in diffusive two-dimensional electron systems with Rashba spin-orbit interaction. Considering a long-range electron-impurity scattering potential in…

材料科学 · 物理学 2009-11-11 S. Y. Liu , X. L. Lei

The upper critical field in type II superconductors is limited by the Pauli paramagnetic limit. In superconductors with strong Rashba spin-orbit coupling this limit can be overcome by forming a helical state. Here we quantitatively study…

超导电性 · 物理学 2021-01-27 L. A. B. Olde Olthof , J. R. Weggemans , G. Kimbell , J. W. A. Robinson , X. Montiel

The interaction between the electrons and the lattice vibrations in a solid is responsible for various important effects, such as formation of polarons, temperature dependent bandgaps, phonon-limited carrier transport, and conventional…

The occurrence of ferroelectricity in inorganic germanium-based halide perovskites has provided an alternative to oxide counterparts. Using first-principles methods, we have studied CsGeX$_3$ materials with heterohalogen substitution at the…

材料科学 · 物理学 2026-03-13 Sourabh Vairat , Balachandra G. Hegde , Brajesh Tiwari , Ravi Kashikar