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Metal halide perovskites exhibit a materials physics that is distinct from traditional inorganic and organic semiconductors. While materials such as CH3NH3PbI3 are non-magnetic, the presence of heavy elements (Pb and I) in a…

The extended carrier lifetime in hybrid halide perovskites was attributed to a quasi-indirect band gap that arises due to Rashba splitting in both conduction and valence band edges. In this paper, we present results for an effective…

材料科学 · 物理学 2018-12-04 Chao Zheng , Shidong Yu , Oleg Rubel

Doping organic metal-halide perovskites with cesium could be the best solution to stabilize highly-efficient perovskite solar cells. The understanding of the respective roles of the organic molecule, on one hand, and the inorganic lattice,…

Rashba-Dresselhaus effects, which originate from spin-orbit coupling and allow for spin manipulations, are actively explored in materials following the pursuit of spintronics and quantum computing. However, materials that possess…

材料科学 · 物理学 2024-07-22 Abduljelili Popoola , Nikhilesh Maity , Ravi Kashikar , S. Lisenkov , I. Ponomareva

The strong spin-orbit interaction in the organic-inorganic perovskites tied to the incorporation of heavy elements (\textit{e.g.} Pb, I) makes these materials interesting for applications in spintronics. Due to a lack of inversion symmetry…

Large Rashba effect efficiently tuned by an external electric field is highly desired for spintronic devices. Using first-principles calculations, we demonstrate that large Rashba splitting is locked at conduction band minimum in…

材料科学 · 物理学 2019-09-10 Yan Song , Dong Zhang , Ben Xu , Kai Chang , Ce-Wen Nan

We show that the Rashba effect at the polar perovskite surfaces and interfaces can be tuned by manipulating the two-dimensional electron gas (2DEG) by an applied electric field, using it to draw the 2DEG out to the surface or push it deeper…

介观与纳米尺度物理 · 物理学 2014-03-21 K. V. Shanavas , S. Satpathy

The dynamical and static Rashba effects in hybrid methylammonium (MA) lead halide perovskites have recently been theoretically predicted. However, only the static effect was experimentally confirmed so far. Here we report on the dynamical…

应用物理 · 物理学 2020-03-11 Yuri D. Glinka , Rui Cai , Junzi Li , Xiaodong Lin , Bing Xu , Kai Wang , Rui Chen , Tingchao He , Xiao Wei Sun

Recently, halide perovskites have gained significant attention from the perspective of efficient spintronics owing to Rashba effect. This effect occurs as a consequence of strong spin-orbit coupling under noncentrosymmetric environment,…

Inorganic-organic lead halide perovskites, particularly methylammonium lead halide (MAPbI$_3$) perovskite, is perceived to be a promising material for optoelectronics and spintronics. However, lead toxicity and instability under air and…

材料科学 · 物理学 2022-12-07 Megha Arya , Preeti Bhumla , Sajjan Sheoran , Suraj , S Bhattacharya

In this letter, we investigated the Rashba effect of the CsPbBr$_3$ bilayers under the external electric field (EEF), with the first-principles calculations. For the PbBr$_2$ terminated bilayer, we found that only electrons experience the…

材料科学 · 物理学 2018-07-04 Xue-Jiao Chen , Lei Liu , De-Zhen Shen

The organic-inorganic hybrid perovskite CH3NH3PbI3 has attracted significant interest for its high performance in converting solar light into electrical power with an efficiency exceeding 20%. Unfortunately, chemical stability is one major…

材料科学 · 物理学 2018-03-02 Yue-Yu Zhang , Shiyou Chen , Peng Xu , Hongjun Xiang , Xin-Gao Gong , Aron Walsh , Su-Huai Wei

Bulk hybride halide perovskites are governed by significant Rashba and Dresselhaus splitting. This indicates that such effects will not only affect their optoelectronic properties but also those of their two dimensional layered relatives.…

材料科学 · 物理学 2022-05-04 Benedikt Maurer , Christian Vorwerk , Claudia Draxl

Spin-orbit coupling (SOC) in conjunction with broken inversion symmetry acts as a key ingredient for several intriguing quantum phenomena viz. persistent spin textures, topological surface states and Rashba-Dresselhaus (RD) effects. The…

材料科学 · 物理学 2021-09-28 Preeti Bhumla , Deepika Gill , Sajjan Sheoran , Saswata Bhattacharya

All-inorganic halide perovskites have received a lot of attention as attractive alternatives to overcome the stability issues of hybrid halide perovskites that are commonly associated with organic cations. To find a compromise between the…

材料科学 · 物理学 2026-04-28 Mike Pols , Adri C. T. van Duin , Sofía Calero , Shuxia Tao

Environmental effects and intrinsic energy-loss processes lead to fluctuations in the operational temperature of solar cells, which can profoundly influence their power conversion efficiency. Here we determine from first principles the…

材料科学 · 物理学 2016-12-16 Wissam A. Saidi , Samuel Poncé , Bartomeu Monserrat

Two-dimensional (2D) hybrid organic-inorganic perovskites (HOIPs) are introducing new directions in the 2D materials landscape. The coexistence of ferroelectricity and spin-orbit interactions play a key role in their optoelectronic…

材料科学 · 物理学 2021-04-08 Fei Wang , Heng Gao , Coen de Graaf , Josep M. Poblet , Branton J. Campbell , Alessandro Stroppa

One of the most fundamental phenomena and a reminder of the electron's relativistic nature is the Rashba spin splitting for broken inversion symmetry. Usually this splitting is a tiny relativistic correction, hardly discernible in…

材料科学 · 物理学 2015-02-23 Zhicheng Zhong , Liang Si , Qinfang Zhang , Wei-Guo Yin , Seiji Yunoki , Karsten Held

The anisotropic Rashba effect allows for the manipulation of electron spins in a more precise and tunable manner since the magnitude of the Rashba splitting and orientation of the spin textures can be simply controlled by tuning the…

材料科学 · 物理学 2023-10-30 Arif Lukmantoro , Moh. Adhib Ulil Absor

One of the exciting features of two-dimensional (2D) materials is their electronic and optical tunability through strain engineering. Previously, we found a class of 2D ferroelectric Rashba semiconductors PbX (X = S, Se, Te) with tunable…

材料科学 · 物理学 2018-06-29 Paul Z. Hanakata , A. S. Rodin , Harold S. Park , David K. Campbell , A. H. Castro Neto
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