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A computational study of the doping of alkali halide crystals (AX: A = Na, K; X = Cl, Br) by ns2 cations (Ga+, In+ and Tl+) is presented. Active clusters of increasing size (from 33 to 177 ions) are considered in order to deal with the…

材料科学 · 物理学 2009-10-31 Andrés Aguado

Machine learning (ML) methods are becoming integral to scientific inquiry in numerous disciplines, such as material sciences. In this manuscript, we demonstrate how ML can be used to predict several properties in solid-state chemistry, in…

材料科学 · 物理学 2020-11-24 Jean-Claude Crivello , Nataliya Sokolovska , Jean-Marc Joubert

"Alchemical" interpolation paths, i.e.~coupling systems along fictitious paths that without realistic correspondence, are frequently used within materials and molecular modeling and simulation protocols for the estimation of relative…

化学物理 · 物理学 2015-03-25 K. Y. Samuel Chang , O. Anatole von Lilienfeld

This study investigates the interfacial tension, fluid mobility, and crystallization behavior of various saline and additive-modified solutions in a microfluidic chip environment, simulating pore-scale processes during CO2 injection. The…

Effects of heavy sea quarks on the low energy physics are described by an effective theory where the expansion parameter is the inverse quark mass, 1/$M$. At leading order in 1/$M$ (and neglecting light quark masses) the dependence of any…

Boosted by the relentless increase of available computational resources, high-throughput calculations based on first principles methods have become a powerful tool to screen a huge range of materials. The backbone of these studies are…

材料科学 · 物理学 2022-03-23 Holger-Dietrich Saßnick , Caterina Cocchi

Globular Clusters (GCs) are natural laboratories where stellar and chemical evolution can be studied in detail. In addition, their chemical patterns and kinematics can tell us wich Galactic structure (Disk, Bulge, Halo or extragalactic) the…

太阳与恒星天体物理 · 物理学 2018-01-10 A. Mura-Guzmán , S. Villanova , C. Muñoz , B. Tang

Existence of ferromagnetism in bulk calcium compounds is discovered theoretically. First-principles calculations of calcium phosphide, calcium arsenide and calcium antimonide in the zinc-blende structure have been performed to show the…

材料科学 · 物理学 2016-08-31 Masaaki Geshi , Koichi Kusakabe , Hidekazu Tsukamoto , Naoshi Suzuki

The Z-vector method in the relativistic coupled-cluster framework is used to calculate magnetic hyperfine structure constant ($A_J$) of alkali metals and singly charged alkaline earth metals in their ground state electronic configuration.…

原子物理 · 物理学 2017-07-18 Sudip Sasmal

We introduce a local machine-learning method for predicting the electron densities of periodic systems. The framework is based on a numerical, atom-centred auxiliary basis, which enables an accurate expansion of the all-electron density in…

化学物理 · 物理学 2021-11-10 Alan M. Lewis , Andrea Grisafi , Michele Ceriotti , Mariana Rossi

A real-space formalism for density-functional perturbation theory (DFPT) is derived and applied for the computation of harmonic vibrational properties in molecules and solids. The practical implementation using numeric atom-centered…

材料科学 · 物理学 2017-03-08 Honghui Shang , Christian Carbogno , Patrick Rinke , Matthias Scheffler

Choice of appropriate force field is one of the main concerns of any atomistic simulation that needs to be seriously considered in order to yield reliable results. Since, investigations on mechanical behavior of materials at micro/nanoscale…

计算物理 · 物理学 2016-07-12 Seyed Moein Rassoulinejad-Mousavi , Yijin Mao , Yuwen Zhang

The van der Waals coefficients for the alkali-metal atoms from Na to Fr interacting in their ground states, are calculated using relativistic ab initio methods. The accuracy of the calculations is estimated by also evaluating atomic static…

原子物理 · 物理学 2007-05-23 A. Derevianko , W. R. Johnson , M. S. Safronova , J. F. Babb

New mechanochemical preparations of three multicomponent crystals (MCCs) of the form MCl:urea.nH2O (M = Li+, Na+, and Cs+) are reported. Their structures were determined by an NMR crystallography approach, combining Rietveld refinement of…

The $\Delta$-Self-Consistent-Field ($\Delta$SCF) method has been established as an accurate and computationally efficient approach for calculating absolute core electron binding energies for light elements up to chlorine, but relatively…

材料科学 · 物理学 2022-10-12 Juhan Matthias Kahk , Johannes Lischner

Free energy calculations are widely used tools in computational chemistry, but their dependence on the assignment of partial charges during force field parametrization reduces their accuracy and reproducibility. In this work, we highlight…

High-entropy alloys (HEAs) have attracted growing attention for their exceptional mechanical and thermal properties arising from complex atomic configurations. In this paper, we propose crystal fractional graph neural network for predicting…

计算物理 · 物理学 2026-05-12 Takanori Kotama , Yang Huang

The high-pressure properties of fluorine and chlorine are not yet well understood because both are highly reactive and volatile elements, which has made conducting diamond anvil cell and x-ray diffraction experiments a challenge. Here we…

材料科学 · 物理学 2020-08-12 Mark A. Olson , Shefali Bhatia , Paul Larson , Burkhard Militzer

We determine the critical Zeeman energy splitting of a homogeneous Fermi superfluid at unitary in terms of the Fermi energy $\epsilon_{\text F}$ according to recent experimental results in LKB-Lhomond. Based on the universal equations of…

核理论 · 物理学 2011-06-08 Lianyi He , Pengfei Zhuang

Accurate quantum mechanics based predictions of property trends are so important for materials design and discovery that even inexpensive approximate methods are valuable. We use the Alchemical Integral Transform (AIT) to study…

化学物理 · 物理学 2024-09-16 Simon León Krug , O. Anatole von Lilienfeld