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Black phosphorus is a layered semiconductor that is intensely researched in view of applications in optoelectronics. In this Letter, we investigate a multi-layer black phosphorus photo-detector that is capable of acquiring high-contrast…

材料科学 · 物理学 2016-01-12 Michael Engel , Mathias Steiner , Phaedon Avouris

Thousands of tons of isotopic mixtures are processed annually for heavy-water production and tritium decontamination. The existing technologies remain extremely energy intensive and require large capital investments. New approaches are…

材料科学 · 物理学 2017-05-18 M. Lozada-Hidalgo , S. Zhang , S. Hu , A. Esfandiar , I. V. Grigorieva , A. K. Geim

Phosphorene is a two-dimensional (2D) material exhibiting strong in-plane structural anisotropy. In this work, we investigate the influence of structural anisotropy on the optics, dynamics, and transport of excitons in phosphorene by…

介观与纳米尺度物理 · 物理学 2025-09-04 Kai-Wei Chang , Joshua J. P. Thompson , Bartomeu Monserrat

We propose an energy-stable parametric finite element method (ES-PFEM) to discretize the motion of a closed curve under surface diffusion with an anisotropic surface energy $\gamma(\theta)$ -- anisotropic surface diffusion -- in two…

数值分析 · 数学 2021-10-26 Yifei Li , Weizhu Bao

The engineering of the optical response of materials is a paradigm that demands microscopic-level accuracy and reliable predictive theoretical tools. Here we compare and contrast the dispersive permittivity tensor, using both a low-energy…

材料科学 · 物理学 2021-09-29 Mohammad Alidoust , Erlend E. Isachsen , Klaus Halterman , Jaakko Akola

We report a scalable approach to synthesize a large-area (up to 4 mm) thin black phosphorus (BP) film on a flexible substrate. We first deposited a red phosphorus (RP) thin-film on a flexible polyester substrate, followed by its conversion…

Recent reports on the fabrication of phosphorene, i.e., mono- or few-layer black phosphorus, have raised exciting prospects of an outstanding two-dimensional (2D) material that exhibits excellent properties for nanodevice applications. Here…

材料科学 · 物理学 2014-06-11 Liangzhi Kou , Thomas Frauenheim , Changfeng Chen

Black phosphorus (BP) is a layered material with anisotropic properties. We study interfaces formed by a pentacene monolayer adsorbed on monolayer BP, a prototypical system for BP surface passivation. We place the pentacene monolayer along…

材料科学 · 物理学 2022-12-09 Naseem Ud Din , Zhen-Fei Liu

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Though highly desirable, a…

介观与纳米尺度物理 · 物理学 2017-02-07 Guowei Zhang , Shenyang Huang , Andrey Chaves , Chaoyu Song , V. Ongun Özçelik , Tony Low , Hugen Yan

The adoption of graphene in electronics, optoelectronics and photonics is hindered by the difficulty in obtaining high quality material on technologically-relevant substrates, over wafer-scale sizes and with metal contamination levels…

Elemental phosphorous is believed to have several stable allotropes that are energetically nearly degenerate, but chemically reactive. To prevent chemical degradation under ambient conditions, these structures may be capped by monolayers of…

介观与纳米尺度物理 · 物理学 2015-03-24 Pablo Rivero , Cedric M. Horvath , Zhen Zhu , Jie Guan , David Tománek , Salvador Barraza-Lopez

The exciton dynamics in monolayer black phosphorus is investigated over a very wide range of photoexcited exciton densities using time resolved photoluminescence. At low excitation densities, the exciton dynamics is successfully described…

介观与纳米尺度物理 · 物理学 2016-08-30 A. Surrente , A. A. Mitioglu , K. Galkowski , L. Klopotowski , W. Tabis , B. Vignolle , D. K. Maude , P. Plochocka

Liquid-phase exfoliation is one of the most promising routes for large scale production of multilayer graphene dispersions. These dispersions, which may be used in coatings, composites or paints, are believed to contain disorder-free…

介观与纳米尺度物理 · 物理学 2014-09-05 M. V. Bracamonte , G. I. Lacconi , S. Urreta , L. E. F. Foa Torres

In this work we briefly review the studies of the optical constants of monolayer transition metal dichalcogenides and few layer black phosphorus, with particular emphasis to the complex dielectric function and refractive index.…

介观与纳米尺度物理 · 物理学 2021-02-03 Aaron M. Ross , Giuseppe M. Paternò , Stefano Dal Conte , Francesco Scotognella , Eugenio Cinquanta

We systematically evaluate the prospects of a novel 2D nanomaterial, phosphorene, as anode for Na-ion batteries. Using first-principles calculations, we determine the Na adsorption energy, specific capacity and Na diffusion barriers on…

材料科学 · 物理学 2015-06-24 Vadym V. Kulish , Oleksandr I. Malyi , Clas Persson , Ping Wu

Single layer (SL) phosphorus (phosphorene) has drawn considerable research attention recently as a two-dimensional (2D) material for application promises. It is a semiconductor showing superior transport and optical properties. Few-layer or…

介观与纳米尺度物理 · 物理学 2017-11-22 Jin-Peng Xu , Jun-Qiu Zhang , Hao Tian , Hu Xu , Wingkin Ho , Maohai Xie

We study the environmental instability of mechanically exfoliated few-layer black phosphorus (BP). From continuous measurements of flake topography over several days, we observe an increase of over 200% in volume due to the condensation of…

High surface area graphene sheets were obtained by electrochemical exfoliation of graphite in an acid media under constant potential conditions. Filtration and centrifugation processes played an important role in order to obtain stable…

材料科学 · 物理学 2016-06-22 M. Hurtado-Morales , M. Ortiz , C. Acuna , H. C. Nerl , V. Nicolosi , Y. Hernandez

Black Phosphorus (BP) is an excellent material for post graphene era due to its layer dependent band gap, high mobility and high Ion/Ioff. However, its poor stability in ambient poses a great challenge in its practical and long-term usage.…

The electronic structure and functionality of 2D materials is highly sensitive to structural morphology, opening the possibility for manipulating material properties, but also making predictable and reproducible functionality challenging.…

介观与纳米尺度物理 · 物理学 2022-10-26 Prakriti P. Joshi , Ruiyu Li , Joseph L. Spellberg , Liangbo Liang , Sarah B. King