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We examine the role of spin-orbit coupling in the electronic structure of $\alpha$-RuCl3, in which Ru ions in 4d5 configuration form a honeycomb lattice. The measured optical spectra exhibit a clear optical gap and excitations within the…

Mott insulators with strong spin-orbit coupling have been proposed to host unconventional magnetic states, including the Kitaev quantum spin liquid. The 4$d$ system $\alpha$-RuCl$_3$ has recently come into view as a candidate Kitaev system,…

A quantum spin-liquid might be realized in $\alpha$-RuCl$_{3}$, a honeycomb-lattice magnetic material with substantial spin-orbit coupling. Moreover, $\alpha$-RuCl$_{3}$ is a Mott insulator, which implies the possibility that novel exotic…

The honeycomb Mott insulator $\alpha$-RuCl$_3$ loses its low-temperature magnetic order by pressure. We report clear evidence for a dimerized structure at $P>1$ GPa and observe the breakdown of the relativistic $j_{\rm eff}$ picture in this…

$\alpha$-RuCl$_3$ has been proposed recently as an excellent playground for exploring Kitaev physics on a two-dimensional (2D) honeycomb lattice. However, structural clarification of the compound has not been completed, which is crucial in…

材料科学 · 物理学 2016-04-27 Heung-Sik Kim , Hae-Young Kee

We investigate the role of electron correlation in the electronic structure of honeycomb lattice Li$_2$RuO$_3$ using photoemission spectroscopy and band structure calculations. Monoclinic Li$_2$RuO$_3$ having Ru network as honeycomb lattice…

强关联电子 · 物理学 2023-01-24 Sakshi Bansal , Asif Ali , B. H. Reddy , Ravi Shankar Singh

The material $\alpha$-RuCl$_3$, with a two-dimensional Ru-honeycomb sublattice, has attracted considerable attention because it may be a realization of the Kitaev quantum spin liquid (QSL). Recently, a new honeycomb material,…

强关联电子 · 物理学 2022-02-08 Yang Zhang , Ling-Fang Lin , Adriana Moreo , Elbio Dagotto

The honeycomb compound $\alpha$-RuCl$_3$ is widely discussed as a proximate Kitaev spin-liquid material. This scenario builds on spin-orbit entangled $j = 1/2$ moments arising for a $t_{2g}^5$ electron configuration with strong spin-orbit…

Using quantum chemistry calculations we shed fresh light on the electronic structure and magnetic properties of RuCl3, a proposed realization of the honeycomb Kitaev spin model. It is found that the nearest-neighbor Kitaev exchange K is…

The combination of electronic correlation and spin-orbit coupling is thought to precipitate a variety of highly unusual electronic phases in solids, including topological and quantum spin liquid states. We report a Raman scattering study…

强关联电子 · 物理学 2015-04-22 Luke J. Sandilands , Yao Tian , Kemp W. Plumb , Young-June Kim , Kenneth S. Burch

Recently, $\alpha$-$\textrm{RuCl}_3$ has attracted much attention as a possible material realization of the honeycomb Kitaev model, which may stabilize a quantum-spin-liquid state. Compared to extensive studies on its magnetic properties,…

The Kitaev model predicts that quantum spin liquids (QSLs) will form at low temperatures under certain special conditions, and materials hosting the QSL state are frequently sought. The layered honeycomb lattice material {\alpha}-RuCl3 has…

材料科学 · 物理学 2022-01-24 Danrui Ni , Xin Gui , Kelly M. Powderly , R. J. Cava

The Mott insulator $\alpha$-RuCl$_3$ has generated great interest in the community due to its possible field-induced Kitaev quantum spin liquid state. Despite enormous effort spent trying to obtain the form of the low energy Hamiltonian,…

We report magnetic and thermodynamic properties of single crystal $\alpha$-RuCl$_3$, in which the Ru$^{3+}$ ($4d^5$) ion is in its low spin state and forms a honeycomb lattice. Two features are observed in both magnetic susceptibility and…

强关联电子 · 物理学 2015-04-27 J. A. Sears , M. Songvilay , K. W. Plumb , J. P. Clancy , Y. Qiu , Y. Zhao , D. Parshall , Young-June Kim

Motivated by the rich interplay among electronic correlation, spin-orbit coupling (SOC), crystal-field splitting, and geometric frustrations in the honeycomb-like lattice, we systematically investigated the electronic and magnetic…

The layered compound $\alpha$-RuCl$_3$ is composed of a honeycomb lattice of magnetic Ru$^{3+}$ ions with the $4d^5$ electronic state. We have investigated the magnetic properties of $\alpha$-RuCl$_3$ via magnetization and specific heat…

强关联电子 · 物理学 2015-06-24 Yumi Kubota , Hidekazu Tanaka , Toshio Ono , Yasuo Narumi , Koichi Kindo

Intensive studies of the interplay between spin-orbit coupling (SOC) and electronic correlations in transition metal compounds have recently been undertaken. In particular, $j_{\rm eff}$ = 1/2 bands on a honeycomb lattice provide a pathway…

强关联电子 · 物理学 2015-06-24 Heung-Sik Kim , V. Vijay Shankar , Andrei Catuneanu , Hae-Young Kee

We report magnetization and neutron diffraction studies on crystal and magnetic structures of Ir- and Rh-substituted honeycomb lattice $\alpha$-RuCl$_3$. The iridium or rhodium atoms are distributed at the Ru site with little structural…

材料科学 · 物理学 2023-10-05 Zachary Morgan , Iris Ye , Colin L. Sarkis , Xiaoping Wang , Stephen Nagler , Jiaqiang Yan

Magnetic insulators in the regime of strong spin-orbit coupling exhibit intriguing behaviors in external magnetic fields, reflecting the frustrated nature of their effective interactions. We review the recent advances in understanding the…

强关联电子 · 物理学 2019-07-30 Lukas Janssen , Matthias Vojta

The layered RuBr3-RuI3 honeycomb system was synthesized at high-pressures. The crystal structures are centrosymmetric (space group R-3), and based on honeycomb layers of Ru$^{3+}$ (S=1/2). Their basic physical properties are surveyed. The…

材料科学 · 物理学 2023-11-27 Danrui Ni , Xianghan Xu , Robert J. Cava
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