相关论文: Derivation of the Inverse Schulze-Hardy Rule
A theory is presented for the effective charge of colloidal particles in suspensions containing multivalent counterions. It is shown that if colloids are sufficiently strongly charged, the number of condensed multivalent counterion can…
The notion of the weighted core inverse in a ring with involution was introduced, recently [Mosic et al. Comm. Algebra, 2018; 46(6); 2332-2345]. In this paper, we explore new representation and characterization of the weighted core inverse…
We report molecular dynamics simulation of the (overall neutral) system consisting of an immobile macroion surrounded by the electrolyte of multivalent counterions and monovalent coions. As expected theoretically, counterions adsorb on the…
A theory is presented which allows us to accurately calculate the density profile of monovalent and multivalent counterions in suspensions of polarizable colloids or nano-particles. In the case of monovalent ions, we derive a weak-coupling…
This paper concerns inverse problems for strongly coupled Schr\"odinger equations. The purpose of this inverse problem is to retrieve a stationary potential in the strongly coupled Schr\"odinger equations from either boundary or internal…
In this paper, a new model is proposed for the inverse random source scattering problem of the Helmholtz equation with attenuation. The source is assumed to be driven by a fractional Gaussian field whose covariance is represented by a…
Screening of a strongly charged macroion by multivalent counterions is considered. It is shown that counterions form a strongly correlated liquid at the surface of the macroion. Cohesive energy of this liquid leads to additional attraction…
Inverse patchy colloids are nano- to micro-scale particles with a surface divided into differently charged regions. This class of colloids combines directional, selective bonding with a relatively simple particle design: owing to the…
Screening of a strongly charged macroion by oppositely charged colloidal particles, micelles, or short polyelectrolytes is considered. Due to strong lateral repulsion such multivalent counterions form a strongly correlated liquid at the…
Colloidal suspensions and polyelectrolyte solutions containing multivalent counterions can exhibit some very counter-intuitive behavior usually associated with the low temperature physics. There are two particularly striking phenomena…
We review works on screening of a macroion, such as colloidal particle or double helix DNA, by multivalent counterions. Multivalent metal ions, charged micelles, short or long polyelectrolytes can play the role of multivalent counterions.…
The inverse current, i.e., induced current is opposite to applied force, has recentlybeen found in a classical one-dimensional interacting Hamiltonian system [Phys. Rev.Lett. 124, 110607 (2020)]. In this paper, we show that inverse current…
Due to the strong correlations between multivalent counterions condensed on a macroion, the net macroion charge changes sign at some critical counterion concentration. This effect is known as the charge inversion. Near this critical…
Adsorption of multivalent counterions on the charged surface of a macroion is known to lead to inversion of the macroion charge due to the strong lateral correlations of counterions. We consider a nontrivial role of the excluded volume of…
We investigate spherical macroions in the strong Coulomb coupling regime within the primitive model in salt-free environment. Molecular dynamics (MD) simulations are used to elucidate the effect of $discrete$ macroion charge distribution on…
Most theoretical and simulation studies on charged particles suspensions are at infinite dilution conditions. Hence these studies have been focused on the electrolyte structure around an isolated central particle (or elctrode), where…
We have directly observed reversal of the polarity of charged surfaces in water upon the addition of tri- and quadrivalent ions using atomic force microscopy. The bulk concentration of multivalent ions at which charge inversion reversibly…
We generalize the inverse patchy colloid model that was originally developed for heterogeneously charged particles with two identical polar patches and an oppositely charged equator to a model that can have a considerably richer surface…
We review recent advances in the physics of strongly interacting charged systems functioning in water at room temperature. We concentrate on the phenomena which go beyond the framework of mean field theories, whether linear Debye-Huckel or…
We propose a covariant holographic conjecture for the entanglement negativity of mixed states in bipartite systems described by $d$-dimensional conformal field theories dual to bulk non static $AdS_{d+1}$ configurations. Application of our…