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We demonstrate a novel technique of coherent Raman spectroscopy with a femtosecond laser. We apply to a molecular sample a sequence of pairs of ultrashort excitation and probe pulses, with a linearly increasing time delay between the two…

Single-shot time resolved Coherent Anti-Stokes Raman Scattering (CARS) is presented as a viable method for fast measurements of molecular spectra. The method is based on the short spatial extension of femtosecond pulses and maps time delays…

光学 · 物理学 2009-11-13 Yuri Paskover , I. Sh. Averbukh , Yehiam Prior

Three-color coherent anti-Stokes Raman scattering represents non-degenerate four wave mixing process that includes both a non-resonant and resonant processes, the contributions of which depend on how the molecular vibrational modes are…

光学 · 物理学 2020-10-14 Supriya Nagpal , Bryan Semon , Gombojav O. Ariunbold

Ultrafast lasers have become one of the most powerful tools in coherent nonlinear optical spectroscopy. Short pulses enable direct observation of fast molecular dynamics, whereas broad spectral bandwidth offers ways of controlling nonlinear…

化学物理 · 物理学 2015-05-13 X. G. Xu , S. O. Konorov , J. W. Hepburn , V. Milner

Early theoretical works on coherent anti-Stokes Raman scattering in optically active medium consider only heterodyne signal and subsequently, fourth- and fifth-rank tensor averages have been used. In this work, we presented a full signal…

量子物理 · 物理学 2019-01-03 Tuguldur Kh. Begzjav , Marlan O. Scully , Girish S. Agarwal

Coherent Raman scattering provides highly sensitive vibrational analysis through nonlinear light-matter interactions. However, its application to metal interfaces has remained challenging because the intrinsically large non-resonant…

Coherent anti-Stokes Raman scattering is a widely used imaging technique that provides chemical contrast without the need for labels, making it an extremely valuable tool in physics, chemistry, and biology. In this work, we explore its…

量子物理 · 物理学 2025-08-05 Giacomo Sorelli , Manuel Gessner , Frank Schlawin

We show that coherent anti-Stokes Raman lineshapes do not follow known spectral profiles if the time asymmetry of realistic laser pulses is taken into account. Examples are given for nanosecond and picosecond laser pulses commonly employed…

光学 · 物理学 2015-06-22 Michele Marrocco , Emil Nordström , Per-Erik Bengtsson

We propose a new technique for comparing two Raman active samples. The method employs optical interference of the signals generated via coherent anti-Stokes Raman scattering (CARS) of broadband laser pulses with noisy spectra. It does not…

量子物理 · 物理学 2015-05-27 Evgeny A. Shapiro , Stanislav O. Konorov , Valery Milner

Raman spectroscopy is an appealing technique that probes molecular vibrations in a wide variety of materials with virtually no sample preparation. However, accurate and reliable Raman measurements are still a challenge and require more…

光学 · 物理学 2020-02-14 Hugo Kerdoncuff , Mikael Lassen , Jan C. Petersen

We propose a Bayesian statistical model for analyzing coherent anti-Stokes Raman scattering (CARS) spectra. Our quantitative analysis includes statistical estimation of constituent line-shape parameters, underlying Raman signal,…

应用统计 · 统计学 2020-05-15 Teemu Härkönen , Lassi Roininen , Matthew T. Moores , Erik M. Vartiainen

Raman scattering spectroscopy is widely used as an analytical technique in various fields, but its measurement process tends to be slow due to the low scattering cross-section. In the last decade, various broadband coherent Raman scattering…

光学 · 物理学 2025-05-06 Takuma Nakamura , Kazuki Hashimoto , Takuro Ideguchi

We have developed an interferometric implementation of coherent anti-Stokes Raman scattering (CARS) which enables broadband coherent Raman spectroscopy free from non-resonant background (NRB), with a signal strength proportional to…

光学 · 物理学 2014-02-25 Brad Littleton , Thomas Kavanagh , Frederic Festy , David Richards

Since its first demonstration in the sixties, coherent anti-Stokes Raman scattering (CARS) has become a powerful spectroscopic sensing tool with broad applications in biology and chemistry. However, it is a complex nonlinear optical process…

光学 · 物理学 2020-07-15 Gombojav O. Ariunbold , Supriya Nagpal , Bryan Semon

Broadband coherent anti-Stokes Raman scattering (CARS) spectroscopy plays a vital role in chemical sensing and label-free vibrational imaging, yet conventional methods suffer from limited acquisition speeds and complex detection schemes.…

光学 · 物理学 2025-07-23 Jing Hu , Tianjian Lv , Zhaoyang Wen , Wending Huang , Ming Yan , Heping Zeng

Spontaneous vibrational Raman scattering is a ubiquitous form of light-matter interaction whose description necessitates quantization of the electromagnetic field. It is usually considered as an incoherent process because the scattered…

量子物理 · 物理学 2023-07-18 Valeria Vento , Santiago Tarrago Velez , Anna Pogrebna , Christophe Galland

Coherent Raman scattering (CRS) spectroscopy techniques have been widely developed and optimized for different applications in biomedicine and fundamental science. The most utilized CRS technique has been coherent anti-Stokes Raman…

光学 · 物理学 2020-03-05 Pavel Kolesnichenko , Jonathan O. Tollerud , Jeffrey A. Davis

We have developed a coherent Raman imaging platform using broadband coherent anti-Stokes Raman scattering (BCARS) that provides an unprecedented combination of speed, sensitivity, and spectral breadth. The system utilizes a unique…

Coherent anti-Stokes Raman scattering (CARS) microspectroscopy has demonstrated significant potential for biological and materials imaging. To date, however, the primary mechanism of disseminating CARS spectroscopic information is through…

光学 · 物理学 2015-10-08 Charles H. Camp , Young Jong Lee , Marcus T. Cicerone

The process in which Raman scattering produces correlated Stokes and anti-Stokes radiation is known as Stokes--anti-Stokes (SaS) scattering. It has been shown recently that this process can generate entangled photon pairs, making it a…

量子物理 · 物理学 2025-09-30 Raul Corrêa , Marcelo F. Santos , Carlos H. Monken , Ado Jorio
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