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High pressure serves as a path finding tool towards novel structures, including those with very high Tc.The superconductivity in sulfur hydrides with record value (203 K) is caused by the phonon mechanism. However, the picture differs from…

超导电性 · 物理学 2018-02-14 Lev Gor'kov , Vladimir Kresin

The recent report of superconductivity under high pressure at the record transition temperature of Tc=203K in sulfur hydride has been identified as conventional in view of the observation of an isotope effect upon deuteration. Here it is…

The highest critical temperature of superconductivity Tc has been achieved in cuprates: 133 K at ambient pressure and 164 K at high pressures. As the nature of superconductivity in these materials is still not disclosed, the prospects for a…

超导电性 · 物理学 2014-12-02 A. P. Drozdov , M. I. Eremets , I. A. Troyan

A superconductor is a material that can conduct electricity with no resistance below its critical temperature (Tc). The highest Tc that has been achieved in cuprates1 is 133 K at ambient pressure2 and 164 K at high pressures3. As the nature…

超导电性 · 物理学 2016-03-31 A. P. Drozdov , M. I. Eremets , I. A. Troyan , V. Ksenofontov , S. I. Shylin

A maximum superconductive transition temperature $T_\textrm{C}$ = 203.5 K has recently been reported for a sample of the binary compound tri-hydrogen sulfide (H$_\textrm{3}$S) prepared at high pressure and with room temperature annealing.…

超导电性 · 物理学 2017-03-14 Dale R. Harshman , Anthony T. Fiory

Hydrogen-sulfide (H2S) was studied by x-ray synchrotron diffraction (XRD) and Raman spectroscopy up to 150 GPa at 180-295 K and by quantum-mechanical variable-composition evolutionary simulations. The experiments show that H2S becomes…

One of interesting open questions for the high transition temperature (Tc) superconductivity in sulfur hydrides is why high pressure phases of H3S have extremely high Tc's. Recently, it has been pointed out that the presence of the van Hove…

超导电性 · 物理学 2016-04-05 Wataru Sano , Takashi Koretsune , Terumasa Tadano , Ryosuke Akashi , Ryotaro Arita

Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved…

Recently, an extremely high superconducting temperature (Tc) of ~200 K has been reported in the sulfur hydride system above 100 GPa. This result is supported by theoretical predictions and verified experimentally. The crystal structure of…

The discovery of superconductivity at 203K in SH$_3$ is an important step toward higher values of $T_c$. Predictions based on state-of-the-art DFT for the electronic structure, including one preceding experimental confirmation, showed the…

超导电性 · 物理学 2019-10-09 J. P. Carbotte , E. J. Nicol , T. Timusk

We calculate superconducting transition temperatures ($T_{\rm c}$) in sulfur hydrides H$_{2}$S and H$_{3}$S from first principles using the density functional theory for superconductors. At pressures of $\lesssim$150 GPa, the high values of…

超导电性 · 物理学 2015-07-08 Ryosuke Akashi , Mitsuaki Kawamura , Shinji Tsuneyuki , Yusuke Nomura , Ryotaro Arita

A recent report that sulfur hydride under pressure is an electron-phonon superconductor with a Tc of 190 K has been met with much excitement although it is yet to be confirmed. Based on several electron-phonon spectral density functions…

超导电性 · 物理学 2015-06-30 E. J. Nicol , J. P. Carbotte

The discovery of high critical temperature T_{c} superconductivity in highly compressed H_{3}S has opened up the question of searching for strong electron-phonon coupling in the hydrides outside the transition metal series. The specific…

超导电性 · 物理学 2019-08-08 P. -H. Chang , S. Silayi , D. A. Papaconstantopoulos , M. J. Mehl

Due to the value of the isotope shift in sulfur hydrides, a phonon-mediated pairing scenario of superconductivity is generally accepted for these high-temperature superconductors which is consistent with the Bardeen-Cooper-Schrieffer (BCS)…

超导电性 · 物理学 2018-12-11 R. M. Méndez-Moreno

Motivated by the recent report of superconductivity above 200 K in ultra-dense hydrogen sulfide, we search for high-\tc\ conventional superconductivity in the phase diagram of the binary Li-S system, using {\em ab-initio} methods for…

超导电性 · 物理学 2016-08-10 Christian Kokail , Christoph Heil , Lilia Boeri

We use first principles calculations to study structural, vibrational and superconducting properties of H$_2$S at pressures $P\ge 200$ GPa. The inclusion of zero point energy leads to two different possible dissociations of H$_2$S, namely…

Hydrogen-based compounds have attracted significant attention in recent years due to the discovery of conventional superconductivity with high critical temperature under high pressure, rekindling hopes for searching room temperature…

超导电性 · 物理学 2024-11-20 Yao Ma , Mingqi Li , Wenjia Shi , Vei Wang , Pugeng Hou , Mi Pang

The recent discovery of superconductivity at 190~K in highly compressed H$_{2}$S is spectacular not only because it sets a record high critical temperature, but because it does so in a material that appears to be, and we argue here that it…

超导电性 · 物理学 2015-03-05 N. Bernstein , C. S. Hellberg , M. D. Johannes , I. I. Mazin , M. J. Mehl

Observation of high-temperature superconductivity in sulfur hydrides at megabar pressures has generated an irresistible wave on searching for new superconductors in other compressed hydrogen-rich compounds. An immediate effort is towards…

The discoveries of high-temperature superconductivity in H3S and LaH10 have excited the search for superconductivity in compressed hydrides. In contrast to rapidly expanding theoretical studies, high-pressure experiments on hydride…

超导电性 · 物理学 2021-09-15 Wuhao Chen , Dmitrii V. Semenok , Xiaoli Huang , Haiyun Shu , Xin Li , Defang Duan , Tian Cui , Artem R. Oganov
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