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Bulk FeSe becomes superconducting below 9\,K, but the critical temperature (T$_{c}$) is enhanced almost universally by a factor of $\sim$4-5 when it is intercalated with alkali elements. How intercalation modifies the structure is known…

超导电性 · 物理学 2023-03-07 Swagata Acharya , Mikhail I. Katsnelson , Mark van Schilfgaarde

We report the superconductivity at enhanced temperature of 5.2 K in the polycrystalline sample of ZrTe3 and Ni intercalated ZrTe3. ZrTe3 is a Charge Density Wave (T = 63K) compound, which is known to superconduct only below 2K in single…

超导电性 · 物理学 2015-06-05 C. S. Yadav , P. L. Paulose

The superconductivity and intercalation statein the lithium-and hexamethylenediamine (HMDA)-intercalated superconductor Li$_x$(C$_6$H$_{16}$N$_2$)$_y$Fe$_{2-z}$Se$_2$ have been investigated from powder x-ray diffraction, thermogravimetric…

The superconducting critical temperature, $T_{\rm c}$, of FeSe can be dramatically enhanced by intercalation of a molecular spacer layer. Here we report on a $^{77}$Se, $^7$Li and $^1$H nuclear magnetic resonance (NMR) study of the powdered…

We report here that a new superconducting phase with much higher Tc has been found in K intercalated FeSe compound with excess Fe. We successfully grew crystals by precisely controlling the starting amount of Fe. Besides the superconducting…

超导电性 · 物理学 2013-02-08 A. M. Zhang , T. L. Xia , K. Liu , W. Tong , Z. R. Yang , Q. M. Zhang

Potassium intercalated FeSe has been reported as a superconductor with superconducting transition temperatures ($T_{\rm c}$'s) of 30-48 K. However, there is no clear answer to identify the relationship between the surface morphology,…

超导电性 · 物理学 2017-01-06 Masashi Tanaka , Hiroyuki Takeya , Yoshihiko Takano

The discovery of ThCr2Si2-type AxFe2-ySe2 (A = K, Rb, Cs and Tl) with Tc ~ 30K make much progress in iron-based superconducting field, but their multiple-phase separations are disadvantageous for understanding the origin. On the other hand,…

超导电性 · 物理学 2014-10-24 Jiangang Guo , Hechang Lei , Fumitaka Hayashi , Hideo hosono

New FeSe-based intercalation superconductors, $A_x$(C$_8$H$_{11}$N)$_y$Fe$_{1-z}$Se ($A$ = Li, Na), with $T_\mathrm{c}$ = 39-44 K have been successfully synthesized via the intercalation of alkali metals and 2-phenethylamine into FeSe. The…

超导电性 · 物理学 2016-09-21 Takehiro Hatakeda , Takashi Noji , Kazuki Sato , Takayuki Kawamata , Masatsune Kato , Yoji Koike

Intercalation of polyatomic molecules into a superconductor can drastically affect the properties of the compound. A mechanism leading to a large increase in Tc for such systems is proposed. It explains the recent remarkable observation of…

超导电性 · 物理学 2009-11-07 A. Bill , V. Z. Kresin

Superconductivity with transition temperature Tc above 40 K was observed in protonated FeSe (Hy-FeSe) previously with the ionic liquid of EMIM-BF4 used in the electrochemical process. However, the real superconducting phase is not clear…

超导电性 · 物理学 2021-11-23 Jinhua Wang , Qing Li , Wei Xie , Guanyu Chen , Xiyu Zhu , Hai-Hu Wen

Following a recent proposal by Burrard-Lucas et al. [unpublished, arXiv: 1203.5046] we intercalated FeSe by Li in liquid ammonia. We report on the synthesis of new LixFe2Se2(NH3)y phases as well as on their magnetic and superconducting…

超导电性 · 物理学 2012-09-28 E. -W. Scheidt , V. R. Hathwar , D. Schmitz , A. Dunbar , W. Scherer , V. Tsurkan , J. Deisenhofer , A. Loidl

Realizing topological superconductivity by integrating high-transition-temperature ($T_C$) superconductors with topological insulators can open new paths for quantum computing applications. Here, we report a new approach for increasing the…

The dream of room temperature superconductors has inspired intense research effort to find routes for enhancing the superconducting transition temperature (Tc). Therefore, single-layer FeSe on a SrTiO3 substrate, with its extraordinarily…

超导电性 · 物理学 2019-03-12 Q. Song , T. L. Yu , X. Lou , B. P. Xie , H. C. Xu , C. H. P. Wen , Q. Yao , S. Y. Zhang , X. T. Zhu , J. D. Guo , R. Peng , D. L. Feng

The superconducting critical temperature $T_{\mathrm{c}}$ of intercalated iron-selenide superconductor (Li,Fe)OHFeSe (FeSe11111) can be increased to 42 K from 8 K of bulk FeSe. It shows remarkably similar electronic properties as the…

With the advent of Fe-As based superconductivity it has become important to study how superconductivity manifests itself in details of 57Fe Mossbauer spectroscopy of conventional, Fe - bearing superconductors. To this end, the iron-based…

材料科学 · 物理学 2015-08-07 Xiaoming Ma , Sheng Ran , Hua Pang , Fashen Li , Paul C. Canfield , Sergey L. Bud'ko

Two-dimensional iron-chalcogenide intercalates display a remarkable correlation of the interlayer spacing with the enhancement of the superconducting critical temperature ($T_c$). In this work, synchrotron x-ray absorption ($XAS$, at Fe and…

A new iron-based superconductor, Lix(C6H16N2)yFe2-zSe2, with Tc = 38 K has successfully been synthesized via the intercalation of lithium and hexamethylenediamine into FeSe. The superconducting transition has been confirmed not only by…

超导电性 · 物理学 2016-01-14 S. Hosono , T. Noji , T. Hatakeda , T. Kawamata , M. Kato , Y. Koike

The FeSe superconductor and its related systems have attracted much attention in the iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a…

超导电性 · 物理学 2015-06-24 Xu Liu , Lin Zhao , Shaolong He , Junfeng He , Defa Liu , Daixiang Mou , Bing Shen , Yong Hu , Jianwei Huang , X. J. Zhou

In the recently synthesized Li$_x$(NH$_2$)$_y$(NH$_3$)$_z$Fe$_2$Se$_2$ family of iron chalcogenides a molecular spacer consisting of lithium ions, lithium amide and ammonia separates layers of FeSe. It has been shown that upon variation of…

超导电性 · 物理学 2015-01-16 Daniel Guterding , Harald O. Jeschke , P. J. Hirschfeld , Roser Valenti

We have performed transverse- and zero-field muon spin rotation/relaxation experiments, as well as magnetometry measurements, on samples of Fe1-xVxSe and their Li+NH3 intercalates Li0.6(NH2)0.2(NH3)0.8 Fe1-x Vx Se. We examine the low…

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