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We report the first observation of trions (charged excitons), three-particle bound states consisting of one electron and two holes, in hole-doped carbon nanotubes at room temperature. When p-type dopants are added to carbon nanotube…

介观与纳米尺度物理 · 物理学 2013-08-26 Ryusuke Matsunaga , Kazunari Matsuda , Yoshihiko Kanemitsu

We demonstrate exciton and charged exciton (trion) electroluminescence from frozen p-n junctions in networks of polymer-sorted, semiconducting (6,5) single-walled carbon nanotubes. Electrolyte-gating with an ionic liquid was employed to…

Photoluminescence spectroscopy measurements are performed on suspended carbon nanotubes in a field-effect configuration, and the gate voltage dependence of photoluminescence spectra are compared for the pristine and the molecularly adsorbed…

介观与纳米尺度物理 · 物理学 2018-09-21 T. Uda , S. Tanaka , Y. K. Kato

Trions are charged excitons that form upon optical or electrical excitation of low-dimensional semiconductors in the presence of charge carriers (holes or electrons). Trion emission from semiconducting single-walled carbon nanotubes…

材料科学 · 物理学 2023-02-17 Sonja Wieland , Abdurrahman Ali El Yumin , Jan M. Gotthardt , Jana Zaumseil

We present a study of free carrier photo-generation and multi-carrier bound states, such as biexcitons and trions (ionized excitons), in semiconducting single-walled carbon nanotubes. Pump-and-probe measurements performed with fs pulses…

We report the first observation of an optical transition from a ground trion state T to excited trion state T* in (6,5) single-wall carbon nanotubes non-covalently doped with hydrochloric acid. The position of such an excited trion level T*…

介观与纳米尺度物理 · 物理学 2018-05-07 T. V. Eremin , P. A. Obraztsov , V. A. Velikanov , T. V. Shubina , E. D. Obraztsova

We investigate adsorption effects of copper phthalocyanine molecules on excitons and trions in air-suspended carbon nanotubes. Using photoluminescence excitation spectroscopy, we observe that exciton energy redshifts gradually with the…

介观与纳米尺度物理 · 物理学 2019-06-12 S. Tanaka , K. Otsuka , K. Kimura , A. Ishii , H. Imada , Y. Kim , Y. K. Kato

Trion states of three correlated particles (e.g., two electrons and one hole) are essential to understand the optical spectra of doped or gated nanostructures, like carbon nanotubes or transition-metal dichalcogenides. We develop a…

介观与纳米尺度物理 · 物理学 2016-06-22 Thorsten Deilmann , Matthias Drüppel , Michael Rohlfing

The stability of trionic excitations in zigzag carbon nanotubes has been estimated. A trion is shown to be unstable with respect to the ground excitonic state and stable with respect to the excited one. So, trions in nanotubes of this type…

介观与纳米尺度物理 · 物理学 2012-11-27 Sergey Marchenko

We present evidence of all optical trion generation and emission in undoped single walled carbon nanotubes (SWCNTs). Luminescence spectra, recorded on individual SWCNTs over a large CW excitation intensity range, show trion emission peaks…

介观与纳米尺度物理 · 物理学 2015-05-28 Silvia Santos , Bertrand Yuma , Stéphane Berciaud , Jonah Shaver , Mathieu Gallart , Pierre Gilliot , Laurent Cognet , Brahim Lounis

Resonant Raman spectroscopy of single carbon nanotubes suspended across trenches displays red shifts of up to 30 meV of the electronic transition energies as a function of the surrounding dielectric environment. We develop a simple scaling…

We study the binding energies of singlet trions, i.e. charged excitons, in carbon nanotubes. The problem is modeled, through the effective-mass model, as a three-particle complex on the surface of a cylinder, which we investigate using both…

量子物理 · 物理学 2010-07-27 Troels F. Rønnow , Thomas G. Pedersen , Horia D. Cornean

Doping substantially influences the electronic and photophysical properties of semiconducting single-wall carbon nanotubes (s-SWNTs). Although prior studies have noted that surplus charge carriers modify optical spectra and accelerate…

Charged excitons, or X$^{\pm}$-trions, in monolayer transition metal dichalcogenides have binding energies of several tens of meV. Together with the neutral exciton X$^0$ they dominate the emission spectrum at low and elevated temperatures.…

The optoelectronic properties of metal chalcogenide colloidal nanoplatelets are often interpreted in terms of excitonic states. However, recent spectroscopic experiments evidence the presence of trion states, enabled by the slow Auger…

介观与纳米尺度物理 · 物理学 2021-05-06 David F. Macías-Pinilla , Josep Planelles , Iván Mora-Seró , Juan I. Climente

We show that the energy differences between the lowest optical singlet exciton and the lowest triplet exciton in semiconducting single-walled carbon nanotubes with diameter $\sim 1$ nm and graphene nanoribbons with widths $\sim 2$ nm are an…

介观与纳米尺度物理 · 物理学 2015-05-30 K. Aryanpour , Sumit Mazumdar , Hongbo Zhao

Optical emission from carbon nanotube transistors (CNTFETs) has recently attracted significant attention due to its potential applications. In this paper, we use a self-consistent numerical solution of the Boltzmann transport equation in…

介观与纳米尺度物理 · 物理学 2008-06-12 Siyuranga O. Koswatta , Vasili Perebeinos , Mark S. Lundstrom , Phaedon Avouris

Exciton spectroscopy serves as a sensitive probe of electronic states in two-dimensional semiconductors. A prominent feature in optical spectra is the trion peak arising from the binding of a charge carrier to an exciton. The splitting…

介观与纳米尺度物理 · 物理学 2025-07-23 Arthur Christianen , Atac Imamoglu

Charged excitons, or trions, offering unique spin and charge degrees of freedom, have primarily been investigated in doped systems where charges are long considered indispensable. Here, we present an alternative route to ultra-efficient…

介观与纳米尺度物理 · 物理学 2026-02-17 N. Fang , U. Erkilic , Y. R. Chang , S. Fujii , D. Yamashita , C. F. Fong , S. Morito , K. Kanahashi , T. Taniguchi , K. Watanabe , K. Ueno , K. Nagashio , Y. K. Kato

Single walled carbon nanotubes as emerging quantum-light sources may fill a technological gap in silicon photonics due to their potential use as near infrared, electrically driven, classical or non-classical emitters. Unlike in…

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