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We report a first-principles study on the elastic, vibrational, and electronic properties of recently synthesized phosphorene. By calculating Gr\"uneisen parameters, we evaluate the frequency shift of Raman/infrared active modes via…

介观与纳米尺度物理 · 物理学 2015-03-26 Mohammad Elahi , Kaveh Khaliji , Seyed Mohammad Tabatabaei , Mahdi Pourfath , Reza Asgari

In 2D materials, the quantum confinement and van der Waals-type interlayer interactions largely govern the fundamental electronic and optical properties, and the dielectric screening plays a dominant role in the excitonic properties. This…

介观与纳米尺度物理 · 物理学 2021-02-19 Guowei Zhang , Shenyang Huang , Fanjie Wang , Hugen Yan

We investigate the spontaneous emission lifetime of a quantum emitter near a substrate coated with phosphorene under the influence of uniaxial strain. We consider both electric dipole and magnetic dipole-mediated spontaneous transitions…

介观与纳米尺度物理 · 物理学 2023-10-30 P. P. Abrantes , W. J. M. Kort-Kamp , F. S. S. Rosa , C. Farina , F. A. Pinheiro , Tarik P. Cysne

Antimonene has attracted much attention for its high carrier mobility and suitable band gap for electronic, optoelectronic, and even spintronic devices. To tailor its properties for such applications, strain engineering may be adopted.…

材料科学 · 物理学 2023-03-10 Yujia Tian , Devesh R. Kripalani , Ming Xue , Shaofan Li , Kun Zhou

One of the fascinating properties of the new families of two-dimensional crystals is their high stretchability and the possibility to use external strain to manipulate, in a controlled manner, their optical and electronic properties. Strain…

介观与纳米尺度物理 · 物理学 2015-07-24 Rafael Roldán , Andres Castellanos-Gomez , Emmanuele Cappelluti , Francisco Guinea

We demonstrate the continuous and reversible tuning of the optical band gap of suspended monolayer MoS2 membranes by as much as 500 meV by applying very large biaxial strains. By using chemical vapor deposition (CVD) to grow crystals that…

Modern electronics rely on devices whose functionality can be adjusted by the end-user with an external 'knob'. A new tuning knob to modify the band gap of black phosphorus has been experimentally demonstrated.

介观与纳米尺度物理 · 物理学 2017-11-17 Rafael Roldán , Andres Castellanos-Gomez

We show that oxidation of phosphorene can lead to the formation of a new family of planar (2D) and tubular (1D) oxides and sub-oxides, most of them insulating. This confers to black phosphorus a native oxide that can be used as barrier…

介观与纳米尺度物理 · 物理学 2015-02-09 A. Ziletti , A. Carvalho , P. E. Trevisanutto , D. K. Campbell , D. F. Coker , A. H. Castro Neto

Black phosphorus is a material with an intrinsic anisotropy in electronic and optical properties due to its puckered honeycomb lattice. Optical absorption is different for incident light with linear polarization in the armchair and zigzag…

介观与纳米尺度物理 · 物理学 2022-04-20 Leandro Seixas

Interlayer interactions in 2D materials, also known as van der Waals (vdWs) interactions, play a critical role in the physical properties of layered materials. It is fascinating to manipulate the vdWs interaction, and hence to "redefine"…

Anisotropy describes the directional dependence of a material's properties such as transport and optical response. In conventional bulk materials, anisotropy is intrinsically related to the crystal structure, and thus not tunable by the…

材料科学 · 物理学 2017-02-10 Ting Cao , Zhenglu Li , Diana Y. Qiu , Steven G. Louie

Black phosphorus has attracted interest as a material for use in optoelectronic devices due to many favorable properties such as a high carrier mobility, field-effect, and a direct bandgap that can range from 0.3 eV in its bulk crystalline…

Black phosphorus (BP) is a two-dimensional layered material composed of phosphorus atoms. Recently, it was demonstrated that external perturbations such as an electric field close the band gap in few-layer BP, and can even induce a band…

介观与纳米尺度物理 · 物理学 2019-03-11 Jiho Jang , Seongjin Ahn , Hongki Min

Light modulation is an essential operation in photonics and optoelectronics. With existing and emerging technologies increasingly demanding compact, efficient, fast and broadband optical modulators, high-performance light modulation…

光学 · 物理学 2016-05-04 Zhipei Sun , Amos Martinez , Feng Wang

Screening in reduced dimensions has strong consequences on the electronic properties in van der Waals semiconductors, impacting the quasiparticle band gap and exciton binding energy. Screening in these materials is typically treated…

Light forces induced by scattering and absorption in elastic dielectrics lead to local density modulations and deformations. These perturbations in turn modify light propagation in the medium and generate an intricate nonlinear response. We…

光学 · 物理学 2012-11-01 Matthias Sonnleitner , Monika Ritsch-Marte , Helmut Ritsch

Most recently, a brand new phosphorus allotrope called green phosphorus has been predicted, which has a direct band gap up to 2.4 eV, and its single-layer form termed green phosphorene shows high stability. Here the mechanical properties…

材料科学 · 物理学 2018-06-18 Guang Yang , Tianxing Ma , Xihong Peng

Using the Tight Binding (TB) parameters extracted from Density Functional Theory (DFT) and Recursive Green's Function method, it is shown that skewed-zigzag black phosphorous (phosphorene) nanoribbons obtain large and tuneable bandgap in…

介观与纳米尺度物理 · 物理学 2019-01-16 Sima Shekarforoush , Farhad Khoeini , Daryoush Shiri

The tunable bandgap from 0.3 eV to 2 eV of black phosphorus (BP) makes it to fill the gap in graphene. When studying the properties of BP more comprehensive, scientists have discovered that many two-dimensional materials, such as tellurene,…

光学 · 物理学 2021-03-01 Ying-Ying Li , Bo Gao , Ying Han , Bing-Kun Chen , Jia-Yu Huo

Optical and electronic properties of black phosphorus strongly depend on the number of layers and type of stacking. Using first-principles calculations within the framework of density functional theory, we investigate the electronic…

介观与纳米尺度物理 · 物理学 2017-09-07 Cem Sevik , John R. Wallbank , Oguz Gulseren , Francois M. Peeters , Deniz Cakır