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A detailed spectroscopic and structural characterization of ultrathin cobalt oxide films grown by O-assisted molecular beam epitaxy on a-Al2O3(0001) single crystals is reported. The experimental results show that the cobalt oxide films…

材料科学 · 物理学 2010-03-09 C. A. F. Vaz , D. Prabhakaran , E. I. Altman , V. E. Henrich

Colloidal photonic crystals display peculiar optical properties which make them particularly suitable for application in different fields. However, the low packing fraction of the targeted structures usually poses a real challenge in the…

软凝聚态物质 · 物理学 2017-09-28 Guido Avvisati , Tonnishtha Dasgupta , Marjolein Dijkstra

Adsorption of CO$_2$ on a semiconductor surface is a prerequisite for its photocatalytic reduction. Owing to superior photocorrosion resistance, nontoxicity and suitable band edge positions, TiO$_2$ is considered to be the most efficient…

材料科学 · 物理学 2018-12-05 Shashi B. Mishra , Aditya Choudhary , Somnath C. Roy , B. R. K. Nanda

The compressive mechanical behavior of a dual phase cobalt alloy (Al$_{14}$Co$_{41}$Cr$_{16}$Fe$_{11}$Ni$_{18}$) is reported in this communication. An uncommon triple yielding phenomenon is observed in the as-cast condition. Microstructural…

材料科学 · 物理学 2020-01-22 Ali Shafiei

High-entropy materials have emerged as a promising class of catalysts, driven by their high configurational entropy originating from structural disorder in single-phase multicomponent systems. Despite their potential, the catalytic…

材料科学 · 物理学 2025-12-23 Anjali Varshney , Aishwery J. Verma , Ritesh Dubey , Sushil Kumar , Tapas Goswami , Samar Layek

Polymeric methyltrioxorhenium, {(CH_{3})_{0.92}ReO_{3}}_{\infty} (poly-MTO), is the first member of a new class of organometallic hybrids which adopts the structural pattern and physical properties of classical perovskites in two dimensions…

Here results of a systematic study on oxygen stoichiometry are reported for the first three members of the novel CoSr2(Y,Ce)sCu2O5+2s or Co-12s2 homologous series, i.e. Co-1212, Co-1222 and Co-1232 phases with a…

超导电性 · 物理学 2007-05-23 Y. Morita , V. P. S. Awana , H. Yamauchi , M. Karppinen

In this work, we report an ab initio investigation based on density functional theory of the structural, energetic and electronic properties of 2D layered chalcogenides compounds based in the combination of the transition-metals (Ti, Zr,…

材料科学 · 物理学 2019-04-17 Carlos M. O. Bastos , Rafael Besse , Juarez L. F. Da Silva , Guilherme M. Sipahi

The phase separation behaviors from the single B2 ordered phase into the two separate B2 and L2$_1$ ordered phases in the X-Al-Ti (X: Fe, Co, and Ni) alloys are analyzed using the cluster variation method (CVM) with the interaction energies…

材料科学 · 物理学 2019-10-23 Ryo Yamada , Tetsuo Mohri

A fully ab initio scheme based on quantum chemical wavefunction methods is used to investigate the correlated multiorbital electronic structure of a 3d-metal compound, LaCoO3. The strong short-range electron correlations, involving both Co…

强关联电子 · 物理学 2009-11-13 L. Hozoi , U. Birkenheuer , H. Stoll , P. Fulde

High-entropy oxides (HEOs) are a promising class of multicomponent ceramics with tunable structural and electronic properties. In this study, we investigate the local electronic structure of rare-earth HEOs in the (Ce, Sm, Pr, La, Y)O2…

Thermoelectric (TE) materials can directly convert heat into electrical energy. However, they sustain costly production procedures and batch-to-batch performance variations. Therefore, developing scalable synthetic techniques for…

To enhance the activity of photocatalysts for hydrogen production and CO2 conversion, noble metal cocatalysts as electron traps and/or acceptors such as platinum or gold are usually utilized. This study hypothesizes that mixing elements…

We report giant resistive switching of an order of 104, long-time charge retention characteristics up to 104 s, non-overlapping SET and RESET voltages, ohmic in low resistance state (LRS) and space charge limited current (SCLC) mechanism in…

材料科学 · 物理学 2017-04-26 Atul Thakre , A. K. Shukla , R. S. Katiyar , Ashok Kumar

The cobalt-intercalated transition metal dichalcogenide Co$_x$TaS$_2$ hosts a rich landscape of magnetic phases that depend sensitively on $x$. While the stoichiometric compound with $x=1/3$ exhibits a single magnetic transition, samples…

Here we report on a novel chemical route to synthesize homogenous cobalt doped titanate nanotubes (CoTNT), using an amorphous Co-doped precursor. The influence of the synthesis temperature, autoclave dwell time and metal doping on the…

材料科学 · 物理学 2013-08-27 V. C. Ferreira , M. R. Nunes , A. J. Silvestre , O. C. Monteiro

We have investigated a set of sodium cobaltates (NaxCoO2) samples with various sodium content (0.67 \le x \le 0.75) using Nuclear Quadrupole Resonance (NQR). The four different stable phases and an intermediate one have been recognized. The…

强关联电子 · 物理学 2014-07-07 T. A. Platova , I. R. Mukhamedshin , A. V. Dooglav , H. Alloul

Redox and catalytic performance in total methane oxidation of a nonostructured ceria-terbia catalyst supported on magnesia is presented and compared to that of a pure ceria catalyst supported on MgO. The investigated material, Ce0.5Tb0.5Ox…

Li2WO4 (LWO) is recognized for its potential as a solid-state electrolyte and it has demonstrated the ability to enhance the electrochemical performance of LiCoO2 (LCO) cathodes in Li-ion batteries. However, prior investigations into LWO…

Monolayer MoTe2 exhibits a variety of derivative structural phases and associated novel electronic properties that enable a wealth of potential applications in future electronic and optoelectronic devices. However, a comprehensive study…