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A general variational approach for computing the rovibrational dynamics of polyatomic molecules in the presence of external electric fields is presented. Highly accurate, full-dimensional variational calculations provide a basis of…

化学物理 · 物理学 2018-04-18 Alec Owens , Andrey Yachmenev

The electric-field-dependent $g$ factor and the electron electric dipole moment (eEDM)-induced Stark splittings for the lowest rotational levels of $^{207,208}$PbF are calculated. Observed and calculated Zeeman shifts for $^{207}$PbF are…

原子物理 · 物理学 2021-08-04 V. V. Baturo , P. M. Rupasinghe , T. J. Sears , R. J. Mawhorter , J. -U. Grabow , A. N. Petrov

Experiments with paramagnetic ground or metastable excited states of molecules (ThO, HfF$^+$, YbF, YbOH, BaF, PbO, etc.) provide strong constraints on electron electric dipole moment (EDM) and coupling constant $C_{SP}$ of contact…

高能物理 - 唯象学 · 物理学 2020-10-28 V. V. Flambaum , I. B. Samsonov , H. B. Tran Tan

The rovibrational electric dipole transitions in the ground electronic state of the HD molecule are studied. A simple, yet rigorous formula is derived for the transition rates in terms of the electric dipole moment function $D(R)$, which is…

化学物理 · 物理学 2009-11-13 Krzysztof Pachucki , Jacek Komasa

We perform laser induced fluorescence(LIF) spectroscopy on a pulsed supersonic beam of tungsten carbide(WC) molecules, which has been proposed as a candidate molecular system for a permanent Electric Dipole Moment(EDM) search of the…

原子物理 · 物理学 2015-06-12 J. Lee , J. Chen , L. V. Skripnikov , A. N. Petrov , A. V. Titov , N. S. Mosyagin , A. E. Leanhardt

We establish a correspondence between the electric dipole matrix elements of a polyatomic symmetric top molecule in a state with nonzero projection of the total angular momentum on the symmetry axis of the molecule and the magnetic dipole…

量子气体 · 物理学 2015-03-20 Michael L Wall , Kenji Maeda , Lincoln D Carr

The order dependent mapping method, its convergence has recently been proven for the energy eigenvalue of the anharmonic oscillator, is applied to re-sum the standard perturbation series for Stark effect of the hydrogen atom. We perform a…

高能物理 - 理论 · 物理学 2009-10-28 Ken-ichi Hiraizumi , Yoshihisa Ohshima , Hiroshi Suzuki

We present a microscopic study of the low-lying states of five odd-mass nuclei of particular interest for experimental searches of atomic electric dipole moments (EDMs): $^{129}$Xe, $^{199}$Hg, $^{225}$Ra, $^{229}$Th, and $^{229}$Pa. The…

核理论 · 物理学 2025-11-11 E. F. Zhou , J. M. Yao

We report the theoretical investigation of the suppression of magnetic systematic effects in HfF$^+$ cation for the experiment to search for the electron electric dipole moment. The g-factors for $J = 1$, $F=3/2$, $|M_F|=3/2$ hyperfine…

原子物理 · 物理学 2017-08-09 A. N. Petrov , L. V. Skripnikov , A. V. Titov

Recently the Eu$_{0.5}$Ba$_{0.5}$TiO$_{3}$ solid was suggested as a promising candidate for experimental search of the electron electric dipole moment. To interpret the results of this experiment one should calculate the effective electric…

原子物理 · 物理学 2015-01-13 L V Skripnikov , A V Titov , A N Petrov , N S Mosyagin , O P Sushkov

The T-odd phenomenon of induction of the magnetic field by a static electric field provides to study the electron EDM and constants of T-odd, P-odd interaction of an electron with a nucleus. Measurement of this magnetic field for…

高能物理 - 唯象学 · 物理学 2007-05-23 V. G. Baryshevsky

We present a unified variational treatment of the electric quadrupole (E2) matrix elements, Einstein coefficients, and line strengths for general open-shell diatomic molecules in the general purpose diatomic code \Duo. Transformation…

原子与分子团簇 · 物理学 2021-11-11 Wilfrid Somogyi , Sergey N. Yurchenko , Andrey Yachmenev

We are pursuing an experiment to measure the electric dipole moment of the electron using the molecule PbO. This measurement requires the ability to prepare quantum states with orientation of the molecular axis and, simultaneously,…

原子物理 · 物理学 2013-05-29 S. Bickman , P. Hamilton , Y. Jiang , D. DeMille

The possibility to measure an electric dipole moment (EDM) of nuclei in the range $10^{-27} \div 10^{-32}$ $e \cdot cm$ in experiments for search of time-reversal violating generation of magnetic and electric fields is discussed.

高能物理 - 唯象学 · 物理学 2007-05-23 Vladimir Baryshevsky

In this work, the electromagnetic and gravitational form factors of a spin-$3/2$ particle, $\Delta$ resonance, are simultaneously calculated with the help of a relativistic covariant quark-diquark approach. The two kinds of form factors are…

高能物理 - 唯象学 · 物理学 2022-01-24 Dongyan Fu , Bao-Dong Sun , Yubing Dong

We have studied the Stark effect in the soft x-ray region for various small molecules by calculating the field-dependent x-ray absorption spectra. This effect is explained in terms of the response of molecular orbitals (core and valence),…

化学物理 · 物理学 2025-03-26 Avdhoot Datar , Catherine Wright , Devin A. Matthews

We set up the framework for the calculation of electric dipole moments (EDMs) of light nuclei using the systematic expansion provided by chiral effective field theory (EFT). We take into account parity (P) and time-reversal (T) violation…

高能物理 - 唯象学 · 物理学 2011-12-12 J. de Vries , R. Higa , C. -P. Liu , E. Mereghetti , I. Stetcu , R. G. E. Timmermans , U. van Kolck

We investigate the electronic structure and properties of atoms exposed to a magnetic quadrupole field. The spin-spatial as well as generalized time reversal symmetries are established and shown to lead to a two-fold degeneracy of the…

原子物理 · 物理学 2007-05-23 Igor Lesanovsky , Joerg Schmiedmayer , Peter Schmelcher

A particle, which moves in a crystal, experiences weak interactions with electrons and nuclei alongside with electromagnetic interaction. Measuring the polarization vector and the angular distribution of charged and neutral particles…

高能物理 - 唯象学 · 物理学 2019-05-17 V. G. Baryshevsky

The electric dipole moment of the electron (eEDM) and the Scalar-PseudoScalar (S-PS) interaction are probes of new physics beyond the standard model of elementary particles, but experiments to observe them using atoms and molecules are…

原子物理 · 物理学 2019-06-19 A. Sunaga , M. Abe , M. Hada , B. P. Das