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High-entropy alloys are made from random mixtures of principal elements on simple lattices, stabilized by a high mixing entropy. The recently discovered BCC Ta-Nb-Hf-Zr-Ti high entropy alloy superconductor appears to display properties of…

超导电性 · 物理学 2016-12-21 Fabian von Rohr , Michal J. Winiarski , Jing Tao , Tomasz Klimczuk , Robert J. Cava

The exceptional mechanical strengths of medium and high-entropy alloys have been attributed to hardening in random solid solutions. Here, we evidence non-random chemical mixings in CrCoNi alloys, resulting from short range ordering. A novel…

材料科学 · 物理学 2022-06-07 H. W. Hsiao , R. Feng , H. Ni , K. An , J. D. Poplawsky , P. K. Liaw , J. M. Zuo

The AlCrTiV high entropy alloy undergoes an order-disorder transition from body centered cubic (Strukturbericht A2) at high temperatures to the CsCl structure (B2) at intermediate temperatures. We model this transition using first…

材料科学 · 物理学 2024-07-02 Michael Widom

The high entropy alloy containing refractory metals Mo-Nb-Ta-W has a body centered cubic structure, which is not surprising given the complete mutual solubility in BCC solid solutions of all pairs of the constituent elements. However, first…

材料科学 · 物理学 2014-02-10 Michael Widom , William Paul Huhn , Soumyadipta Maiti , Walter Steurer

This study delves into bcc HfNbTaTiZr refractory high entropy alloys, focusing on the $\frac{1}{2}\langle111\rangle$ screw dislocation core structures. While traditional observations in pure elements often revealed compact dislocation…

材料科学 · 物理学 2024-05-07 Asif Iqbal Bhatti , David Tingaud , M. Seydou , Sylvain Queyreau

The quaternary alloy AlCrTiV has been proposed as both a lightweight high entropy alloy and also a functional spin filter material based on the Heusler structure. Experimental investigations to-date, based on X-ray diffraction, offer…

材料科学 · 物理学 2025-05-14 Nedjma Kalliney , Michael Widom

We introduce a simplified method to model the interatomic interactions of high entropy alloys based on a lookup table of cluster energies. These interactions are employed in replica exchange Monte Carlo simulations with histogram analysis…

材料科学 · 物理学 2022-12-06 Andrew D. Kim , Michael Widom

Impurity diffusion in Zr is potentially important for many applications of Zr alloys, and in particular for their use of nuclear reactor cladding. However, significant uncertainty presently exists about which elements are vacancy vs.…

材料科学 · 物理学 2018-05-14 Hai-Jin Lu , Henry Wu , Nan Zou , Xiao-Gang Lu , Yan-Lin He , Dane Morgan

Refractory high-entropy alloys (RHEAs) have emerged as promising candidates for extreme high-temperature applications, for example, in next-generation turbines and nuclear reactors. In such applications, atomic diffusion critically governs…

With first-principles theoretical analysis of the local structure using Bond Orientational Order parameters and Voronoi partitioning, we establish (a) HCP$\rightarrow$BCC structural transformation in high-entropy alloys (HEAs)…

材料科学 · 物理学 2023-06-21 Narendra Kumar , Umesh V. Waghmare

Refractory high-entropy alloys are under consideration for applications where materials are subjected to high temperatures and levels of radiation, such as in the fusion power sector. However, at present, their scope is limited because they…

材料科学 · 物理学 2024-04-09 Christopher D. Woodgate , Julie B. Staunton

Solid solutions occur when multiple chemical species share sites of a common crystal lattice. Although the single site occupation is random, chemical interaction preferences bias the occupation probabilities of neighboring sites, and this…

材料科学 · 物理学 2021-04-14 Nathaniel Hoffman , Michael Widom

Tracer diffusion of all constituting elements is studied at various temperatures in a series of (CoCrFeMn)$_{100-x}$Ni$_x$ alloys with compositions ranging from pure Ni to the equiatomic CoCrFeMnNi high-entropy alloy. At a given homologous…

Even if the atoms of a multicomponent alloy occupy a common lattice, their distribution is not homogeneous, and regions with different compositions can be detected. Three representative examples will be discussed: a Cantor-type system…

材料科学 · 物理学 2026-05-12 Vaclav Paidar , Pavel Lejcek , Andrea Skolakova

The alloying effect on the lattice parameters, isostructural mixing enthalpies and ductility of the ternary nitride systems Cr1-xTMxN (TM=Sc, Y; Ti, Zr, Hf; V, Nb, Ta; Mo, W) in the cubic B1 structure has been investigated using…

材料科学 · 物理学 2014-07-10 Liangcai Zhou , David Holec , Paul. H. Mayrhofer

The temperature and density of the hot diffuse medium pervading galaxy groups and clusters combine into one significant quantity, the entropy. Here we express the entropy levels and profiles in model-independent forms by joining two…

天体物理学 · 物理学 2009-11-13 A. Cavaliere , A. Lapi , Y. Rephaeli

We study order transitions and defect formation in a model high-entropy alloy (CuNiCoFe) under ion irradiation by means of molecular dynamics simulations. Using a hybrid Monte-Carlo/molecular dynamics scheme a model alloy is generated which…

Tungsten-based low-activation high-entropy alloys are possible candidates for next-generation fusion reactors due to their exceptional tolerance to irradiation, thermal loads, and stress. We develop an accurate and efficient machine-learned…

We study the thermodynamics and phase stability of the AlTiVNb and AlTiCrMo refractory high-entropy superalloys using a combination of \textit{ab initio} electronic structure theory -- namely a concentration wave analysis -- and atomistic…

Detailed neutron diffraction measurements on a single crystalline ErB$_2$C$_2$ were performed. We observed magnetic diffuse scattering which consists of three components just above the transition temperatures, which is also observed in…

强关联电子 · 物理学 2009-11-10 Kenji Ohoyama , Kentaro Indoh , Aya Tobo , Koji Kaneko , Aya Hino , Hideya Onodera
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