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Optical birefringence and light absorption measurements reveal four regimes for the thermotropic behavior of a nematogen liquid (7CB) upon sequential filling of parallel-aligned capillaries of 12 nm diameter in a monolithic, mesoporous…

软凝聚态物质 · 物理学 2013-04-08 Patrick Huber , Mark Busch , Sylwia Calus , Andriy V. Kityk

We report dielectric relaxation spectroscopy experiments on two rod-like liquid crystals of the cyanobiphenyl family (5CB and 6CB) confined in tubular nanochannels with 7 nm radius and 340 micrometer length in a monolithic, mesoporous…

介观与纳米尺度物理 · 物理学 2015-08-18 Sylwia Calus , Lech Borowik , Andriy V. Kityk , Manfred Eich , Mark Busch , Patrick Huber

The optical birefringence of rod-like nematogens (7CB, 8CB), imbibed in parallel silica channels with 10 nm diameter and 300 micrometer length, is measured and compared to the thermotropic bulk behavior. The orientational order of the…

软凝聚态物质 · 物理学 2016-09-08 Andriy V. Kityk , Matthias Wolff , Klaus Knorr , Denis Morineau , Ronan Lefort , Patrick Huber

We explore the nematic ordering of the rod-like liquid crystals 5CB and 6CB, embedded into parallel-aligned nanochannels in mesoporous silicon and silica membranes as a function of mean channel radius (4.7<=R <=8.3 nm), and thus geometrical…

软凝聚态物质 · 物理学 2012-08-15 Sylwia Calus , Daniel Rau , Patrick Huber , Andriy V. Kityk

Landau - de Gennes mean field model predicts the discontinuous transition for the Isotropic - Nematic transition, associated with uniaxial and quadrupolar order parameter in three dimensions. This report shows pressure-related dielectric…

Optical birefringence measurements on a rod-like liquid crystal (8OCB), imbibed in silica channels (7 nm diameter), are presented and compared to the thermotropic bulk behavior. The orientational and positional order of the confined liquid…

软凝聚态物质 · 物理学 2015-05-20 Andriy V. Kityk , Patrick Huber

Nanoconfined liquid crystals (LCs) and their nanocomposites are driving the next generation of photonic applications. Consequently, deepening our understanding of mesophase stability, defect topology, and the dynamic response of LCs at the…

Confinement in the nanochannels of porous silicon strongly affects the phase behavior of the archetype liquid-crystal 4-n-octyl-4-cyanobiphenyl (8CB). A very striking phenom- enon is the development of a short-range smectic order, which…

软凝聚态物质 · 物理学 2011-06-08 Régis Guégan , Ronan Lefort , Wilfried Béziel , Denis Morineau , Mohammed Guendouz , Bernhard Frick

We use numerical simulations to investigate the hydrodynamic behavior of the interface between nematic (N) and isotropic (I) phases of a confined active liquid crystal. At low activities, a stable interface with constant shape and velocity…

软凝聚态物质 · 物理学 2021-02-25 Rodrigo C. V. Coelho , Nuno A. M. Araújo , Margarida M. Telo da Gama

We present a combined x-ray diffraction and infrared spectroscopy study on the phase behavior and molecular dynamics of n-hexadecanol in its bulk state and confined in an array of aligned nanochannels of 8 nm diameter in mesoporous silicon.…

材料科学 · 物理学 2009-05-11 R. Berwanger , A. Henschel , K. Knorr , P. Huber , R. Pelster

In this work, we study the nematic-isotropic phase transition based on the dynamics of the Landau--De Gennes theory of liquid crystals. At the critical temperature, the Landau--De Gennes bulk potential favors the isotropic phase and nematic…

偏微分方程分析 · 数学 2021-07-28 Tim Laux , Yuning Liu

We report combined optical birefringence and neutron scattering measurements on the liquid crystal 12CB nanoconfined in mesoporous silicon layers. This liquid crystal exhibits strong nematic-smectic coupling responsible for a discontinuous…

介观与纳米尺度物理 · 物理学 2010-05-04 Gilbert Chahine , Andriy V. Kityk , Klaus Knorr , Ronan Lefort , Mohammed Guendouz , Denis Morineau , Patrick Huber

The yet virtually unexplored class of soft colloidal rods with small aspect ratio is investigated and shown to exhibit a very rich phase and dynamic behavior, spanning from liquid to nearly melt state. Instead of nematic order, these short…

We explore the optical birefringence of the nematic binary mixtures 6CB$_{1-x}$7CB$_x$ ($0~\le~x~\le~1$) imbibed into parallel-aligned nanochannels of mesoporous alumina and silica membranes for channel radii of $3.4~\le~R~\le 21.0$ nm. The…

软凝聚态物质 · 物理学 2014-06-20 Sylwia Calus , Beata Jablonska , Mark Busch , Daniel Rau , Patrick Huber , Andriy V. Kityk

The nematic twist-bend (TB) phase, exhibited by certain achiral thermotropic liquid crystalline (LC) dimers, features a nanometer-scale, heliconical rotation of the average molecular long axis (director) with equally probable left- and…

Structural order parameters of a smectic liquid crystal confined into the columnar form of porous silicon are studied using neutron scattering and optical spectroscopic techniques. It is shown that both the translational and orientational…

软凝聚态物质 · 物理学 2011-06-08 Ronan Lefort , Denis Morineau , Régis Guégan , Moréac Alain , Claude Ecolivet , Mohammed Guendouz

We investigate orientational relaxation of a model discotic liquid crystal, consists of disc-like molecules, by molecular dynamics simulations along two isobars starting from the high temperature isotropic phase. The two isobars have been…

软凝聚态物质 · 物理学 2009-11-13 Dwaipayan Chakrabarti , Biman Jana , Biman Bagchi

We report a dynamic light scattering study of the fluctuation modes in a thermotropic liquid crystalline mixture of monomer and dimer compounds that exhibits the twist-bend nematic ($\mathrm{N_{TB}}$) phase. The results reveal a spectrum of…

Using density-functional theory in the restricted-orientation approximation, we analyse the liquid-crystal patterns and phase behaviour of a fluid of hard rectangular particles confined in a two-dimensional square nanocavity of side length…

软凝聚态物质 · 物理学 2015-06-16 Miguel Gonzalez-Pinto , Yuri Martinez-Raton , Enrique Velasco

Motivated by the search for quantum liquid crystal phases in a gas of ultracold atoms and molecules, we study the density wave and nematic instabilities of dipolar fermions on the two-dimensional square lattice (in the $x-y$ plane) with…

量子气体 · 物理学 2015-03-13 Chungwei Lin , Erhai Zhao , W. Vincent Liu
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