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Molybdenum carbide (Mo2C) nanoparticles and thin films are particularly suitable catalysts for catalytic fast pyrolysis (CFP) as they are effective for deoxygenation and can catalyze certain reactions that typically occur on noble metals.…

MoTe$_2$ is an exfoliable transition metal dichalcogenide (TMD) which crystallizes in three symmetries, the semiconducting trigonal-prismatic $2H-$phase, the semimetallic $1T^{\prime}$ monoclinic phase, and the semimetallic orthorhombic…

FoF1-ATP synthase is the enzyme that provides the 'chemical energy currency' adenosine triphosphate, ATP, for living cells. The formation of ATP is accomplished by a stepwise internal rotation of subunits within the enzyme. We monitor…

生物物理 · 物理学 2015-06-26 N. Zarrabi , M. G. Dueser , R. Reuter , S. D. Dunn , J. Wrachtrup , M. Boersch

Molybdenum dithiocarbamates (MoDTCs) are lubricant additives very efficient in reducing the friction of steel and they are employed in a number of industrial applications. The functionality of these additives is ruled by the chemical…

Aims: The production of saturated organic molecules in hot cores and corinos is not well understood. The standard approach is to assume that, as temperatures heat up during star formation, methanol and other species evaporate from grain…

天体物理学 · 物理学 2009-11-11 R. T. Garrod , E. Herbst

Interactions of two-dimensional MXene sheets and electron beam of (scanning) transmission electron microscope are studied via first-principles calculations. We simulated the knock-on displacement threshold for Ti$_3$C$_2$ MXene sheet via ab…

材料科学 · 物理学 2021-04-13 Rina Ibragimova , Zhong-Peng Lv , Hannu-Pekka Komsa

Chemical vapor deposition (CVD) is a powerful method employed for high quality monolayer crystal growth of 2D transition metal dichalcogenides with much effort invested toward improving the growth process. Here, we report a novel method for…

Methyl acetate (CH_3COOCH_3) has been recently observed by IRAM 30 m radio telescope in Orion though the presence of its deuterated isotopomers is yet to be confirmed. We therefore study the properties of various forms of methyl acetate,…

星系天体物理 · 物理学 2015-08-06 Ankan Das , Liton Majumdar , Dipen Sahu , Prasanta Gorai , B Sivaraman , Sandip K. Chakrabarti

In this paper, for the first time, a new generation of ultrafast reprogrammable multi-mission bias encoded metasurface is proposed for dynamic THz wavefront engineering by employing VO2 reversible and fast monoclinic to tetragonal phase…

应用物理 · 物理学 2019-11-01 Javad Shabanpour , Sina Beyraghi , Ahmad Cheldavi

Heterostructures are ubiquitous in many optoelectronic devices and as photocatalysts. One of the key features of a heterojunction is the proper band alignment between the two materials. Estimation of the correct relative band positions with…

介观与纳米尺度物理 · 物理学 2024-08-13 Raheel Hammad , Snehith Adabala , Soumya Ghosh

Understanding the atomic-scale interaction mechanism of CO$_2$ and H$_2$O on TiO$_2$ surface is crucial to establish a correlation between the catalytic efficiency with its exposed facet. Here, with the aid of a three-state model, nudged…

材料科学 · 物理学 2020-08-07 Shashi B. Mishra , B. R. K. Nanda

The role of layer disorder is important in establishing the topological phases of MoTe${_2}$. A rich tapestry of atomic ordering influences the structural phase transitions (SPTs), but there is little understanding of the mechanistic…

材料科学 · 物理学 2023-12-07 Sumit Khadka , Leighanne C. Gallington , Byron Freelon

The preferential formation of one solid over the other, as it precipitates out from the melt at specific temperatures, is often explained by invoking a competition between thermodynamic and kinetic control. A quantitative theory, however,…

统计力学 · 物理学 2018-09-10 Puja Banerjee , Biman Bagchi

The Sm-activated orthvanadate nanoparticles were synthesized by co-precipitation and sol-gel methods. XRD study has shown that synthesized samples are characterized by monoclinic or tetragonal structure as well as their mixture dependently…

This paper presents an end-to-end design method for the synthesis of dielectric metasurfaces with modulated thickness that are able to realize desired radiation patterns in the far-field with high precision. The method relies on integral…

应用物理 · 物理学 2022-11-28 Vasileios G. Ataloglou , George V. Eleftheriades

Earth-abundant two-dimensional (2D) pristine transition metal dichalcogenides (TMDs) have emerged as a superlative class of materials for several applications in electronic devices, energy storage devices, gas sensing, etc., and they have…

材料科学 · 物理学 2021-06-29 Joy Ekka , Shrish Nath Upadhyay , Verma Bunty Sardar , Srimanta Pakhira

Recently, new states of matter like superconducting or topological quantum states were found in transition metal dichalcogenides (TMDs) and manifested themselves in a series of exotic physical behaviors. Such phenomena have been…

The synthesis of the high-$T_c$ superhydride CaH$_6$ has stimulated significant interest in understanding synthesis pathways for metastable hydrides. However, the microscopic mechanisms governing such hydrogenation reactions remain poorly…

We develop mean-field kinetic equations for a lattice gas model of a binary alloy with vacancies (ABv model) in which diffusion takes place by a vacancy mechanism. These equations are applied to the study of phase separation of finite…

材料科学 · 物理学 2007-05-23 Mathis Plapp , Jean-Francois Gouyet

Transition-metal dichalcogenides open novel opportunities for the exploration of exciting new physics and devices. As a representative system, 2H-MoS$_2$ has been extensively investigated owing to its unique band structure with a large band…