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A method is presented that allows to combine the effective potential between two nano crystals, the potential of mean force (PMF), as obtained from all-atomistic Molecular Dynamics simulations with perturbation theory. In this way, a…

软凝聚态物质 · 物理学 2015-12-31 G. Bauer , A. Lange , N. Gribova , C. Holm , J. Groß

We study the potential of mean force (PMF) between atomistic silica and gold nanoparticles in the vacuum by using molecular dynamics simulations. Such an investigation is devised in order to fully characterize the effective interactions…

软凝聚态物质 · 物理学 2018-03-08 Gianmarco Munaò , Andrea Correa , Antonio Pizzirusso , Giuseppe Milano

We perform a systematic application of the hybrid particle-field molecular dynamics technique [Milano et al, J. Chem. Phys. 2009, 130, 214106] to study interfacial properties and potential of mean force (PMF) for separating nanoparticles…

Ligand coated nanoparticles are complex objects consisting of a metallic or semiconductor core with organic ligands grafted on their surface. These organic ligands provide stability to a nanoparticle suspension. In solutions, the effective…

软凝聚态物质 · 物理学 2022-03-01 Dinesh Chintha , Shivanand Kumar Veesam , Emanuele Boattini , Laura Filion , Sudeep N Punnathanam

Predicting the adsorption affinity of a small molecule to a target surface is of importance to a range of fields, from catalysis to drug delivery and human safety, but a complex task to perform computationally when taking into account the…

化学物理 · 物理学 2022-11-16 Ian Rouse , Vladimir Lobaskin

We consider a system where a spherical particle is suspended in a nematic liquid crystal confined between two walls. We calculate the liquid-crystal mediated potential of mean force between the sphere and a substrate by means of Monte Carlo…

软凝聚态物质 · 物理学 2009-11-07 Evelina B. Kim , Roland Faller , Qiliang Yan , Nicholas L. Abbott , Juan J. de Pablo

We have performed fully atomistic classical molecular dynamics (MD) simulations to calculate the effective interaction between two polyamidoamine (PAMAM) dendrimers. Using the umbrella sampling (US) technique, we have obtained the potential…

计算物理 · 物理学 2015-06-23 Taraknath Mandal , Chandan Dasgupta , Prabal K Maiti

Hydrostatic pressure is a common perturbation to probe the conformations of proteins. There are two common forms of pressure dependent potentials of mean force (PMFs) derived from hydrophobic molecules available for the coarse grained…

生物大分子 · 定量生物学 2020-11-17 Andrei G. Gasic , Margaret S. Cheung

Understanding protein structure is of crucial importance in science, medicine and biotechnology. For about two decades, knowledge based potentials based on pairwise distances -- so-called "potentials of mean force" (PMFs) -- have been…

Molecular dynamic (MD) simulations are applied to investigate the dependency of the kinetic friction coefficient on the temperature at the nano-scale. The system is comprised of an aluminum spherical particle consisting of 32000 atoms in an…

数据分析、统计与概率 · 物理学 2023-11-08 Rasoul Kheiri , Alexey A Tsukanov

Computer simulations can provide mechanistic insight into ionic liquids (ILs) and predict the properties of experimentally unrealized ion combinations. However, ILs suffer from a particularly large disparity in the time scales of atomistic…

This article presents a new force model for performing quantitative simulations of dense granular materials. Interactions between multiple contacts (MC) on the same grain are explicitly taken into account. Our readily applicable method…

软凝聚态物质 · 物理学 2018-10-22 Nicolas Brodu , Joshua A. Dijksman , Robert P. Behringer

We study the heat transfer between two nanoparticles held at different temperatures that interact through nonreciprocal forces, by combining molecular dynamics simulations with stochastic thermodynamics. Our simulations reveal that it is…

统计力学 · 物理学 2022-12-16 Sarah A. M. Loos , Saeed Arabha , Ali Rajabpour , Ali Hassanali , Edgar Roldan

The extent of ion pairing in solution is an important phenomenon to rationalise transport and thermodynamic properties of electrolytes. A fundamental measure of this pairing is the potential of mean force (PMF) between solvated ions. The…

化学物理 · 物理学 2024-04-11 Niamh O'Neill , Benjamin X. Shi , Kara Fong , Angelos Michaelides , Christoph Schran

Molecular dynamics (MD) simulation, which is considered an important tool for studying physical and chemical processes at the atomic scale, requires accurate calculations of energies and forces. Although reliable energies and forces can be…

材料科学 · 物理学 2021-12-06 Van-Quyen Nguyen , Viet-Cuong Nguyen , Tien-Cuong Nguyen , Tien-Lam Pham

We use analytical calculations and event-driven molecular dynamics simulations to study a small number of hard sphere particles in a spherical cavity. The cavity is taken also as the thermal bath so that the system thermalizes by collisions…

软凝聚态物质 · 物理学 2014-09-30 Ignacio Urrutia , Claudio Pastorino

We use functional, Fr\'echet, derivatives to quantify how thermodynamic outputs of a molecular dynamics (MD) simulation depend on the potential used to compute atomic interactions. Our approach quantifies the sensitivity of the quantities…

计算物理 · 物理学 2020-04-08 Samuel Temple Reeve , Alejandro Strachan

Ions are critical to the structure and stability of polyelectrolytes such as nucleic acids. In this work, we systematically calculated the potentials of mean force between two like-charged nanoparticles in salt solutions by Monte Carlo…

生物物理 · 物理学 2015-06-15 Yuan-Yan Wu , Feng-Hua Wang , Zhi-Jie Tan

A new potential of mean force is proposed for colloidal dispersions, which is obtained from coarse grained, pair interactions between colloidal particles formed by the explicit grouping of particles that are themselves groups of atoms and…

软凝聚态物质 · 物理学 2015-10-06 K. A. Terrón-Mejía , R. López-Rendón , A. Gama Goicochea

Molecular dynamics (MD) simulations allow atomistic insights into chemical and biological processes. Accurate MD simulations require computationally demanding quantum-mechanical calculations, being practically limited to short timescales…

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