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Coulomb repulsion between the unevenly-bound bonding and nonbonding electron pairs in the O:H-O hydrogen-bond is shown to originate the anomalies of ice under compression. Consistency between experimental observations, density functional…

化学物理 · 物理学 2013-10-08 Chang Q Sun , Xi Zhang , Weitao Zheng

Coulomb repulsion between the bonding electron pair in the H-O covalent bond (denoted by "-") and the nonbonding electron pair of O (":") and the specific-heat disparity between the O:H and the H-O segments of the entire hydrogen bond…

化学物理 · 物理学 2013-10-08 Chang Q. Sun

The segmental specific heat ratio of the couple hydrogen bond defines not only the phase of Vapor, Liquid, Ice I and XI phase with a quasisolid phase that shows the negative thermal extensibility but uniquely the slope of density of water…

化学物理 · 物理学 2020-12-03 Chang Q Sun

Compression shortens the O:H nonbond and lengthens the H-O bond simultaneously via O:H-O Coulomb repulsion. The energy loss of the elongated H-O bond lowers the melting point.

软凝聚态物质 · 物理学 2015-09-22 Chang Q. Sun

We examined O:H-O bond relaxation under compression,heating,molecular undercoordination and claimed a universal resolution to the best-known mysteries of water ice such as ice foating, ice slipperiness, relegation and warm water cools…

软凝聚态物质 · 物理学 2018-09-06 Yongli Huang , Xi Zhang , Chang Q Sun

The elastic, less dense, polarized, and thermally stable supersolid skin lubricates ice. Molecular undercoordination shortens the H-O bond and lengthens the O:H nonbond through O-O repulsion, which is associated with low-frequency and…

软凝聚态物质 · 物理学 2015-02-17 Chang Q. Sun

Unlike other unusual materials whose bonds contract under compression, the O:H nonbond undergoes contraction and the H-O bond elongation towards O:H and H-O length symmetry in water and ice. The energy drop of the H-O bond dictates the…

软凝聚态物质 · 物理学 2015-01-29 Chang Q Sun

The inter oxygen repulsion opposes compression minimizing the compressibility. Polarization enlarges the bandgap and the dielectric permittivity of water ice by raising the nonbonding states above the Fermi energy. Progress evidences the…

化学物理 · 物理学 2020-08-10 Chang Q Sun

Coulomb repulsion between the unevenly-bounded bonding "-" and nonbonding ":" electron pairs in the "O2- : H+/p-O2-" hydrogen-bond is found to originate the anomalies of low-compressibility, phonon relaxation dynamics, proton symmetrization…

其他凝聚态物理 · 物理学 2011-10-13 Chang Q Sun , Xi Zhang , Weitao Zheng

Here we show that the Coulomb interaction between violations of the Bernal-Fowler rules leads to a temperature induced step-wise increase in their concentration by 6-7 orders of magnitude. This first-order phase transition is accompanied by…

统计力学 · 物理学 2016-08-24 M. I. Ryzhkin , A. V. Klyuev , V. V. Sinitsyn , I. A. Ryzhkin

Hydrogen-bond forms a pair of asymmetric, coupled, H-bridged oscillators with ultra-short-range interactions and memory. hydrogen bond cooperative relaxation and the associated binding electron entrapment and nonbonding electron…

软凝聚态物质 · 物理学 2015-01-16 Chang Q Sun

Skins of water and ice share the same attribute of supersolidity characterized by the identical H-O vibration frequency of 3450 cm-1. Molecular undercoordination and inter-electron-pair repulsion shortens the H-O bond and lengthen the O:H…

化学物理 · 物理学 2014-09-26 Xi Zhang , Yongli Huang , Zengsheng Ma , Yichun Zhou , Weitao Zheng , Ji Zhou , Chang Q. Sun

A combination of the extended Ice Rule of Pauling, Raman spectroscopy, and molecular dynamics calculations has enabled us to clarify the bonding origin of the anomalous volume expansion, Raman phonon relaxation, and the stiffness and…

其他凝聚态物理 · 物理学 2011-10-04 Xi Zhang , Xiaojian Fu , Yu Wen , Jer-lai Kuo , Zexiang Shen , Ji Zhou , Chang Q. Sun

The interplay between intra-molecular H-O covalent bond contraction, due to molecular under-coordination, and inter-molecular O:H expansion, due to inter-electron pair Coulomb repulsion, has been shown to be the source of the anomalous…

化学物理 · 物理学 2013-10-08 Chang Q. Sun

NaCl solvation turns the fS portion molecules into the hydrating supersolid phase by ionic polarization and leaves the rest fO portion ordinary. Polarization shortens and stiffens the HO bond and does the O:H nonbond contrastingly in the…

化学物理 · 物理学 2021-09-21 Yanjun Shen , Xin Wei , Yongzhi Wang , Lei Li , Yongli Huang , Chang Q Sun

The friction of a stationary moving skate on smooth ice is investigated, in particular in relation to the formation of a thin layer of water between skate and ice. It is found that the combination of ploughing and sliding gives a friction…

其他凝聚态物理 · 物理学 2018-01-22 J. M. J. van Leeuwen

The low kinetic friction between ice and numerous counterbodies is commonly attributed to an interfacial water layer, which is believed to originate from pre-existing surface water or from melt water induced by high contact pressures or…

软凝聚态物质 · 物理学 2025-09-03 Achraf Atila , Sergey V. Sukhomlinov , Martin H. Müser

We demonstrate that the Mpemba paradox arises intrinsically from the release rate of energy initially stored in the covalent H-O part of the O:H-O bond in water albeit experimental conditions. Generally, heating raises the energy of a…

化学物理 · 物理学 2015-01-29 Xi Zhang , Yongli Huang , Zengsheng Ma , Chang Q Sun

The light scattered by cold atoms induces mutual optical forces between them, which can lead to bound states. In addition to the trapping potential, this light-induced interaction generates a velocity-dependent force which damps or…

原子物理 · 物理学 2020-07-01 Angel T. Gisbert , Nicola Piovella , Romain Bachelard

Most hydrodynamical calculations used in heavy-ion physics ignore the effect of freeze-out matter carrying energy and momentum away from the expanding fluid. In a simple one-dimensional model we compare calculated energy density and…

核理论 · 物理学 2022-02-23 John J. Neumann , Boris Lavrenchuk , George Fai
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