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We present a theoretical model to describe the double-resonant scattering process in arbitrary carbon nanotubes. We use this approach to investigate the defect-induced $D$ mode in CNTs and unravel the dependence of the $D$-mode frequency on…

材料科学 · 物理学 2016-01-20 Felix Herziger , Asmus Vierck , Jan Laudenbach , Janina Maultzsch

We present an analysis of deep-UV Raman measurements of graphite, graphene and carbon nanotubes. For excitation energies above the strong optical absorption peak at the $M$ point in the Brillouin zone ($\approx 4.7\,\text{eV}$), we…

材料科学 · 物理学 2015-08-03 Christoph Tyborski , Felix Herziger , Roland Gillen , Janina Maultzsch

We calculate the double resonant (DR) Raman spectrum of graphene, and determine the lines associated to both phonon-defect processes, and two-phonons ones. Phonon and electronic dispersions reproduce calculations based on density functional…

介观与纳米尺度物理 · 物理学 2011-07-26 Pedro Venezuela , Michele Lazzeri , Francesco Mauri

Second-order Raman scattering has been extensively studied in carbon-based nanomaterials, \emph{e.g.} nanotube and graphene, because it activates normally forbidden Raman modes that are sensitive to crystal disorder, such as defects,…

It has been long accepted that the second-order Raman bands in carbon nanotubes are enhanced through the double-resonance mechanism. Although separate aspects of this mechanism have been studied for a few second-order Raman bands, including…

介观与纳米尺度物理 · 物理学 2018-08-15 Valentin N. Popov

Resonance Raman scattering, which probes electrons, phonons and their interplay in crystals, is extensively used in two-dimensional materials. Here we investigate Raman modes in MoSe$_2$ at different laser excitation energies from 2.33 eV…

An analytical study is presented of the double resonant Raman scattering process in graphene, responsible for the D and D$^{\prime}$ features in the Raman spectra. This work yields analytical expressions for the D and D$^{\prime}$…

介观与纳米尺度物理 · 物理学 2015-01-29 J. F. Rodriguez-Nieva , E. B. Barros , R. Saito , M. S. Dresselhaus

We report a comprehensive micro-Raman scattering study of electrochemically-gated graphene field-effect transistors. The geometrical capacitance of the electrochemical top-gates is accurately determined from dual-gated Raman measurements,…

介观与纳米尺度物理 · 物理学 2016-08-08 Guillaume Froehlicher , Stéphane Berciaud

Phonon softening phenomena of the $\Gamma$ point optical modes including the longitudinal optical mode, transverse optical mode and radial breathing mode in "metallic" single wall carbon nanotubes are reviewed from a theoretical point of…

介观与纳米尺度物理 · 物理学 2010-05-13 K. Sasaki , H. Farhat , R. Saito , M. S. Dresselhaus

We present low-temperature Raman measurements on gate tunable graphene encapsulated in hexagonal boron nitride, which allows to study in detail the Raman G and 2D mode frequencies and line widths as function of the charge carrier density.…

介观与纳米尺度物理 · 物理学 2023-02-15 Jens Sonntag , Kenji Watanabe , Takashi Taniguchi , Bernd Beschoten , Christoph Stampfer

Magneto Raman scattering study of the E$_{2g}$ optical phonons in multi-layer epitaxial graphene grown on a carbon face of SiC are presented. At 4.2K in magnetic field up to 33 T, we observe a series of well pronounced avoided crossings…

材料科学 · 物理学 2015-05-13 C. Faugeras , M. Amado , P. Kossacki , M. Orlita , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

We demonstrate enhancements of Raman scattering from graphene on two-dimensional photonic crystals using double resonances, which originate from simultaneous enhancements by a localized guided mode and a cavity mode. By adjusting the…

介观与纳米尺度物理 · 物理学 2018-08-24 W. Gomulya , H. Machiya , K. Kashiwa , T. Inoue , S. Chiashi , S. Maruyama , Y. K. Kato

The line shape of the double-resonant $2D$ Raman mode in bilayer graphene is often considered to be characteristic for a certain laser excitation energy. Here, in a joint experimental and theoretical study, we analyze the dependence of the…

介观与纳米尺度物理 · 物理学 2018-12-19 Felix Herziger , Christoph Tyborski , Oliver Ochedowski , Marika Schleberger , Janina Maultzsch

Polarized Raman scattering has been performed on CaC6 superconductor. We identify two of the three Raman active Eg phonon modes at 440 and 1508 cm-1 expected for the R-3m space group of CaC6. These first order scattering modes appear along…

材料科学 · 物理学 2009-11-13 A. Mialitsin , J. S. Kim , R. K. Kremer , G. Blumberg

We present a systematic experimental and theoretical study of the two-phonon (2D) Raman scattering in graphene under uniaxial tension. The external perturbation unveils that the 2D mode excited with 785nm has a complex line-shape mainly due…

By computing the double-resonant Raman scattering cross-section completely from first principles and including electron-electron interaction at the $GW$ level, we unravel the dominant contributions for the double-resonant 2D-mode in bilayer…

介观与纳米尺度物理 · 物理学 2014-11-04 Felix Herziger , Matteo Calandra , Paola Gava , Patrick May , Michele Lazzeri , Francesco Mauri , Janina Maultzsch

We have revisited the still unresolved puzzle of the dispersion of the Raman disordered-induced D band as a function of laser excitation photon energy E$_L$ in graphite-like materials. We propose that the D-mode is a combination of an optic…

无序系统与神经网络 · 物理学 2009-11-07 A. K. Sood , Rajeev Gupta , S. A. Asher

We present a resonance Raman study of the disorder-induced D mode in a sample highly enriched with semiconducting (9,7) single-walled carbon nanotubes in the excitation energy range of 1.49 - 2.05 eV. The intensity of the D mode shows a…

材料科学 · 物理学 2015-06-12 Jan Laudenbach , Frank Hennrich , Hagen Telg , Manfred Kappes , Janina Maultzsch

Broadening of the Raman scattering (RS) spectra was studied in monolayer graphene samples irradiated with various dose of ions followed by annealing of radiation damage at different temperatures. It is shown that the width {\Gamma} (full…

介观与纳米尺度物理 · 物理学 2019-12-13 I. Shlimak , A. Butenko , E. Kogan , M. Kaveh

We present a computational study of the two-phonon Raman spectra of silicene and graphene within a density-functional non-orthogonal tight-binding model. Due to the presence of linear bands close to the Fermi energy in the electronic…

介观与纳米尺度物理 · 物理学 2016-04-29 Valentin N. Popov , Philippe Lambin
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