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Full control of molecular interactions, including reactive losses, would open new frontiers in quantum science. Here, we demonstrate extreme tunability of chemical reaction rates by using an external electric field to shift excited…

Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have…

原子物理 · 物理学 2015-05-18 K. -K. Ni , S. Ospelkaus , D. Wang , G. Quemener , B. Neyenhuis , M. H. G. de Miranda , J. L. Bohn , J. Ye , D. S. Jin

We report the investigation on dipolar collisions in rotational state mixtures of ultracold bosonic $^{23}$Na$^{87}$Rb molecules. The large resonant dipole-dipole interaction between molecules in rotational states of opposite parities…

原子物理 · 物理学 2021-01-13 Junyu He , Xin Ye , Junyu Lin , Mingyang Guo , Goulven Quéméner , Dajun Wang

The dipolar collision between ultracold polar molecules is an important topic both by its own right from the fundamental point of view and for the successful exploration of many-body physics with strong and long-range dipolar interactions.…

Microscopic control over polar molecules with tunable interactions would enable realization of novel quantum phenomena. Using an applied electric field gradient, we demonstrate layer-resolved state preparation and imaging of ultracold…

Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well…

By leveraging the hyperfine interaction between the rotational and nuclear spin degrees of freedom, we demonstrate extensive magnetic control over the electric dipole moments, electric dipolar interactions, and ac Stark shifts of…

原子物理 · 物理学 2024-01-11 Rebekah Hermsmeier , Ana Maria Rey , Timur V. Tscherbul

Chemical reaction rates often depend strongly on stereodynamics, namely the orientation and movement of molecules in three-dimensional space. An ultracold molecular gas, with a temperature below 1 uK, provides a highly unusual regime for…

量子物理 · 物理学 2016-11-25 M. H. G. de Miranda , A. Chotia , B. Neyenhuis , D. Wang , G. Quemener , S. Ospelkaus , J. L. Bohn , J. Ye , D. S. Jin

Ultracold polar molecules possess long-range, anisotropic, and tunable dipolar interactions, providing the opportunities to probe quantum phenomena inaccessible with existing cold gas platforms. However, experimental progress has been…

Understanding the sources of losses and chemical reactions of ultracold alkali-metal molecules is among the critical elements needed for their application in precision measurements and quantum technologies. Recent experiments with…

量子气体 · 物理学 2022-11-11 Krzysztof Jachymski , Marcin Gronowski , Michał Tomza

Ultracold dipolar molecules hold great promise for the creation of novel quantum states of matter, but the realization of long-lived molecular bulk samples with strong dipole-dipole interactions has remained elusive. Here, we realize a…

Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the…

We develop a collisional formalism adapted for the dynamics of ultracold dipolar particles in a confined geometry and in fields tilted relative to the confinement axis. Using tesseral harmonics instead of the usual spherical harmonics to…

原子物理 · 物理学 2015-10-21 Goulven Quéméner , Maxence Lepers , Olivier Dulieu

We prepare mixtures of ultracold CaF molecules and Rb atoms in a magnetic trap and study their inelastic collisions. When the atoms are prepared in the spin-stretched state and the molecules in the spin-stretched component of the first…

Recent experimental developments in the loading of ultracold KRb molecules into quasi-two-dimensional traps, combined with the ability to tune the ratio between elastic and loss (inelastic/reactive) collisions through application of an…

量子物理 · 物理学 2013-12-18 Bihui Zhu , Goulven Quéméner , Ana M. Rey , Murray J. Holland

We show that the precise preparation of a quantum superposition between three rotational states of an ultracold dipolar molecule generates controllable interferences in their two-body scattering dynamics and collisional rate coefficients,…

量子气体 · 物理学 2024-06-21 Thibault Delarue , Goulven Quéméner

Collisions of polar $^{1}\Sigma$ state molecules at ultralow energies are considered, within a model that accounts for long-range dipole-dipole interactions, plus rotation of the molecules. We predict a substantial suppression of…

原子物理 · 物理学 2016-09-08 Alexander V. Avdeenkov , Masatoshi Kajita , John L. Bohn

We propose a one-channel, simple model to describe the dynamics of ultracold dipolar molecules around a F\"orster resonance. Slightly above a specific electric field, a collisional shielding can take place, suppressing the molecular losses…

量子气体 · 物理学 2024-06-21 Lucas Lassablière , Goulven Quéméner

We theoretically study collisions between ultracold polar molecules that are polarized by microwave or static electric fields. We systematically study the dependence on field strength, microwave polarization, and detuning from rotational…

原子物理 · 物理学 2022-02-09 Tijs Karman , Zoe Z. Yan , Martin Zwierlein

Understanding collisions between ultracold molecules is crucial for making stable molecular quantum gases and harnessing their rich internal degrees of freedom for quantum engineering. Transient complexes can strongly influence collisional…

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