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This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

超导电性 · 物理学 2016-06-06 Sahana Rößler , Cevriye Koz , Steffen Wirth , Ulrich Schwarz

We investigate the high-pressure phase of the iron-based superconductor FeSe$_{0.89}$S$_{0.11}$ using transport and tunnel diode oscillator studies. We construct detailed pressure-temperature phase diagrams that indicate that outside of the…

超导电性 · 物理学 2022-12-14 Pascal Reiss , Alix McCollam , Zachary Zajicek , Amir A. Haghighirad , Amalia I. Coldea

Superconducting iron chalcogenide FeSe has the simplest crystal structure among all the Fe-based superconductors. Unlike other iron pnictides, FeSe exhibits no long range magnetic order accompanying the tetragonal-to-orthorhombic structural…

We investigated the evolution of the temperature-composition phase diagram of Fe$_{1+y}$Te upon Se substitution. In particular, the effect of Se substitution on the two-step, coupled magneto-structural transition in Fe$_{1+y}$Te single…

超导电性 · 物理学 2015-05-12 Dona Cherian , S. Rößler , S. Wirth , Suja Elizabeth

Among the Fe-based superconductors, Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ is unique in that its crystal structure is the simplest and the electron correlation level is the strongest, and thus it is important to investigate the…

We have synthesized tetragonal iron selenide and telluride superconductors through solid state reaction at 450deg.C and 550deg.C respectively. These synthesis temperatures have been established by optimization. Electrical resistivity and…

Iron chalcogenide Fe(Te,Se) attracted much attention due to its simple structure, which is favorable for probing the superconducting mechanism. Its less toxic nature compared with iron arsenides is also advantageous for applications of…

Knowledge of the doping (x)-temperature (T) phase diagram of Fe-based superconductors is crucial in understanding the mechanism of high transition temperature superconductivity. Here, we measured the Se doping dependence of the magnetic…

超导电性 · 物理学 2023-06-21 Takenori Fujii , Yu Uezono , Takumi Otsuka , Shotaro Hagisawa , Takao Watanabe

Here we establish a combined electronic phase diagram of isoelectronic FeSe1-xSx (0.19 > x > 0.0) and FeSe1-yTey (0.04 < y < 1.0) single crystals. The FeSe1-yTey crystals with y = 0.04 - 0.30 are grown by a hydrothermal ion-deintercalation…

A fundamental issue concerning iron-based superconductivity is the roles of electronic nematicity and magnetism in realising high transition temperature ($T_{\rm c}$). To address this issue, FeSe is a key material, as it exhibits a unique…

A series of (Li$_{0.8}$Fe$_{0.2}$)OHFeSe$_{1-x}$S$_x$ (0 $\leq$ x $\leq$ 1) samples were successfully synthesized via hydrothermal reaction method and the phase diagram is established. Magnetic susceptibility suggests that an…

超导电性 · 物理学 2015-01-07 X. F. Lu , N. Z. Wang , X. G. Luo , G. H. Zhang , X. L. Gong , F. Q. Huang , X. H. Chen

We present the first review of the current state of the literature on electronic properties and phase transitions in TlX and TlMX2 (M = Ga, In; X = Se, S, Te) compounds. These chalcogenides belong to a family of the low-dimensional…

其他凝聚态物理 · 物理学 2008-07-21 A. M. Panich

We have investigated the elastoresistance of two FeSe${}_{1-x}$Te${}_{x}$ (x about 0.4 - 0.5) compounds that have a close chemical composition but differ significantly in electronic properties. The first compound has a negative temperature…

We have investigated the influence of Fe-excess on the electrical transport and magnetism of Fe1+yTe0.5Se0.5 (y=0.04 and 0.09) single crystals. Both compositions exhibit resistively determined superconducting transitions (Tc) with an onset…

We measured the resistivity and magnetic susceptibility to map out the phase diagram of single crystalline NaFe$_{1-x}$Co$_x$As. Replacement of Fe by Co suppresses both the structural and magnetic transition, while enhances the…

超导电性 · 物理学 2012-06-21 A. F. Wang , X. G. Luo , Y. J. Yan , J. J. Ying , Z. J. Xiang , G. J. Ye , P. Cheng , Z. Y. Li , W. J. Hu , X. H. Chen

We report synthesis of under doped non-superconducting parent compound of iron chalcogenide, i.e FeTe1-xSex (x=0.0, 0.01, 0.03, 0.05) single crystals by flux free method. These FeTe1-xSex (x=0.0, 0.01, 0.03, 0.05) single crystals are…

超导电性 · 物理学 2016-06-17 P. K. Maheshwari , Rajveer Jha , Bhasker Gahtori , V. P. S. Awana

Transition metal dichalcogenides provide a versatile platform for tunable ferroic phenomena at the atomic scale owing to their reduced dimensionality. Here we investigate the structural, magnetic, and ferroelectric properties of bulk solid…

In this study, we conducted various magnetotransport measurements on Fe$_{1+y}$Te$_{1-x}$Se$_{x}$ single crystals from which excess iron was sufficiently removed. Our results revealed that crossover from the incoherent to the coherent…

We report the successful synthesis of FeSe$_{1-x}$S$_{x}$ single crystals with $x$ ranging from 0 to 1 via a hydrothermal method. A complete phase diagram of FeSe$_{1-x}$S$_{x}$ has been obtained based on resistivity and magnetization…

Iron-based chalcogenides are complex superconducting systems in which orbitally-dependent electronic correlations play an important role. Here, using high-resolution angle-resolved photoemission spectroscopy, we investigate the effect of…

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