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In the search for novel organic charge transfer salts with variable charge transfer degree we study the effects of two modifications to the recently synthesized donor-acceptor Tetramethoxypyrene (TMP)-Tetracyanoquinodimethane (TCNQ). One is…

Using first-principles calculations we analyze the electronic transport properties of a recently proposed anthraquinone based electrochemical switch. Robust conductance on/off ratios of several orders of magnitude are observed due to…

介观与纳米尺度物理 · 物理学 2015-05-18 Troels Markussen , Jakob Schiøtz , Kristian S. Thygesen

Interfaces formed by two different organic semiconductors often exhibit a large conductivity, originating from transfer of charge between the constituent materials. The precise mechanisms driving charge transfer and determining its…

材料科学 · 物理学 2016-03-01 Yulia Krupskaya , Ignacio Gutiérrez Lezama , Alberto F. Morpurgo

We have measured a graphene double quantum dot device with multiple electrostatic gates that are used to enhance control to investigate it. At low temperatures the transport measurements reveal honeycomb charge stability diagrams which can…

介观与纳米尺度物理 · 物理学 2015-05-20 L. J. Wang , H. O. Li , Z. Su , T. Tu , G. Cao , C. Zhou , X. J. Hao , G. C. Guo , G. P. Guo

Azophenine has previously been identified as a controllable molecular switch when deposited on a Cu(110) surface, where it can be in two symmetry-equivalent states. Each of the two states can be set as well as read by means of a scanning…

原子与分子团簇 · 物理学 2018-01-04 Herbert Fruchtl , Tanja van Mourik

Precise control of spin states and spin-spin interactions in atomic-scale magnetic structures is crucial for spin-based quantum technologies. A promising architecture is molecular spin systems, which offer chemical tunability and…

The current work investigates candidate building blocks based on molecular junctions from hydrogen transfer tautomerization in the benzoquinone-like core of an azophenine molecule with QTAIM and the recently-introduced stress tensor…

The spatial arrangement of adsorbates deposited onto a clean surface in vacuum typically cannot be reversibly tuned. Here we use scanning tunneling microscopy to demonstrate that molecules deposited onto graphene field-effect transistors…

Combined diverse two-dimensional (2D) materials for semiconductor interfaces are attractive for electrically controllable carrier confinement to enable excellent electrostatic control. We investigated the transport characteristic in…

介观与纳米尺度物理 · 物理学 2021-03-22 Rahul Tripathi , Pritam Bhattacharyya , Sukanta Nandi , Alok Shukla , Abha Misra

We report the electronic transport properties of a new photo-addressable molecular switch. The switching process relies on a new concept based on linear {\pi}-conjugated dynamic systems, in which the geometry and hence the electronic…

介观与纳米尺度物理 · 物理学 2017-06-13 S. Lenfant , Y. Viero , C. Krzeminski , D. Vuillaume , D. Demeter , I. Dobra , M. Ocafrain , P. Blanchard , J. Roncali , C. van Dyck , J. Cornil

We study the model of a molecular switch comprised of a molecule with a soft vibrational degree of freedom coupled to metallic leads. In the presence of strong electron-ion interaction, different charge states of the molecule correspond to…

介观与纳米尺度物理 · 物理学 2008-12-18 Fabio Pistolesi , Yaroslav M. Blanter , Ivar Martin

Charge carriers in the quantum Hall regime propagate via one-dimensional conducting channels that form along the edges of a two-dimensional electron gas. Controlling their transmission through a gate-tunable constriction, also called…

Graphene double quantum open the possibility to use charge or spin degrees of freedom for storing and manipulating quantum information in this new electronic material. However, impurities and edge disorders in etched graphene…

介观与纳米尺度物理 · 物理学 2014-06-18 Da Wei , Hai-Ou Li , Gang Cao , Gang Luo , Zhi-Xiong Zheng , Tao Tu , Ming Xiao , Guang-Can Guo , Hong-Wen Jiang , Guo-Ping Guo

We apply a first-principles computational approach to study a light-sensitive molecular switch. The molecule that comprises the switch can convert between a trans and a cis configuration upon photo-excitation. We find that the conductance…

介观与纳米尺度物理 · 物理学 2015-06-18 Chun Zhang , M. -H. Du , H. -P. Cheng , X. -G. Zhang , A. E. Roitberg , J. L. Krause

We study numerically cross conductances in a four-terminal all-graphene setup. We show that far away from the Dirac point current flows along zigzag directions, giving the possibility to guide the current between terminals using a tunable…

介观与纳米尺度物理 · 物理学 2009-11-01 Kimmo Sääskilahti , Ari Harju , Pirjo Pasanen

The ability to control the conductance of single molecules will have a major impact in nanoscale electronics. Azobenzene, a molecule that changes conformation as a result of a trans/cis transition when exposed to radiation, could form the…

介观与纳米尺度物理 · 物理学 2008-11-26 Miriam del Valle , Rafael Gutierrez , Carlos Tejedor , Gianaurelio Cuniberti

Electrically stimulated switching of a charge injection barrier at the interface between an organic semiconductor and an electrode modified with a disordered monolayer (DM) is studied by using various benzenethiol derivatives as DM…

材料科学 · 物理学 2016-08-04 Ryo Nouchi , Takaaki Tanimoto

As a methodology for controlling the carrier transport of topological insulators (TI's), a flexible tuning in carrier number on the surface states (SS's) of three dimensional TI's by surface modifications using organic molecules is…

Semiconductor quantum dot molecules are considered as promising candidates for quantum technological applications due to their wide tunability of optical properties and coverage of different energy scales associated with charge and spin…

The influence of an intramolecular proton transfer reaction on the conductance of a molecular junction is investigated employing a generic model, which includes the effects of the electric field of the gate and leads electrodes and the…

介观与纳米尺度物理 · 物理学 2017-03-08 Chriszandro Hofmeister , Pedro B. Coto , Michael Thoss
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