相关论文: Quantum Yields from Stationary States: Cis-Trans I…
We simulate the nonequilibrium steady state \textit{cis-trans} photoisomerization of retinal chromophore in rhodopsin based on a two-state-two-mode model coupled to a thermal environment. By analyzing the systematic trends within an…
The photoisomerization reaction of the retinal chromophore in rhodopsin was computationally studied using a two-state two-mode model coupled to thermal baths. Reaction quantum yields at the steady state (10 ps and beyond) were found to be…
Designing a model of retinal isomerization in Rhodopsin, the first step in vision, that accounts for both experimental transient and stationary state observables is challenging. Here, multi-objective Bayesian optimization is employed to…
For a detailed understanding of chemical processes in nature and industry, we need accurate models of chemical reactions in complex environments. While Eyring transition state theory is commonly used for modeling chemical reactions, it is…
We propose to control the retinal photoisomerization yield through the back-action dynamics imparted by a nonselective optical measurement of the molecular electronic state. This incoherent effect is easier to implement than comparable…
The quantum yield of synthetic eumelanin is known to be extremely low and it has recently been reported to be dependent on excitation wavelength. In this paper, we present quantum yield as a function of excitation wavelength between 250 and…
Modern potential energy surfaces have shifted attention to molecular simulations of chemical reactions. While various methods can estimate rate constants for conformational transitions in molecular dynamics simulations, their applicability…
The thermal cis-trans isomerization around the C$_{13}$=C$_{14}$ double bond of retinal is a prototypical high-barrier reaction whose mechanism hinges on subtle out-of-plane bending motions. We apply Artificial Intelligence for Molecular…
Characterization of the primary events involved in the $cis-trans$ photoisomerization of the rhodopsin retinal chromophore was approximated by a minimum one-dimensional quantum-classical model. The developed mathematical model is identical…
We study laser-driven isomerization reactions through an excited electronic state using the recently developed Geometrical Optimization procedure [J. Phys. Chem. Lett. 6, 1724 (2015)]. The goal is to analyze whether an initial wave packet…
We show that optomechanical systems in the quantum regime can be used to demonstrate EPR-type quantum entanglement between the optical field and the mechanical oscillator, via quantum-state steering. Namely, the conditional quantum state of…
In this work, we study the quantum dynamics of a photoisomerization reaction employing a two-electronic-state three-vibrational-mode model of the 2-cis-penta-2,4-dieniminium cation (cis-PSB3). In particular, we address two main issues: the…
Under certain conditions, focused laser excitation in semiconductor quantum well structures can lead to charge separation and a circular reaction front, which is visible as a ring-shaped photoluminescence pattern. The diffusion-reaction…
Isomeric yield ratios for the odd-$A$ isotopes of $^{119-127}$Cd and $^{119-127}$In from 25-MeV proton-induced fission on natural uranium have been measured at the JYFLTRAP double Penning trap, by employing the Phase-Imaging…
We investigate the nature of quantum jumps occurring between macroscopic metastable states of light in the open driven Jaynes-Cummings model. We find that, in the limit of zero spontaneous emission considered in [H. J. Carmichael, Phys.…
We present an approach for state and parameter estimation in retinal laser treatment by a novel setup where both measurement and heating is performed by a single laser. In this medical application, the temperature that is induced by the…
Light-induced chemical processes are ubiquitous in nature and have widespread technological applications. For example, photoisomerization can allow a drug with a photo-switchable scaffold such as azobenzene to be activated with light. In…
Accurate characterization of quantum yield is crucial to the reconstruction of energy depositions in silicon at the eV scale. This work presents a new method for experimentally calculating quantum yield using vacuum UV-sensitive silicon…
In this work we present numerical results for physical quantities in the steady-state obtained after a variety of product-states initial conditions are evolved unitarily, driven by the dynamics of quantum integrable models of the rational…
The influence of the collimating conditions of the incident beam on diffraction patterns produced by grazing scattering of fast atoms off crystal surfaces is studied within a semi-quantum approach, named Surface Initial Value Representation…