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Type-I clathrates with a cage structure are known to be of importance for thermoelectric applications as the cage can be filled with a guest atom which leads to reduced thermal conductivity. Among the type-I clathrates, Si-based alloys are…

材料科学 · 物理学 2015-09-29 Kalpna Rajput , Satish Vitta

We study the thermopower of a junction between a metal and a strongly correlated semiconductor. Both in the electronic ferroelectric regime and in the Kondo insulator regime the thermoelectric figures of merit, ZT, of these junctions are…

强关联电子 · 物理学 2009-07-20 Massimo Rontani , L. J. Sham

Crystalline solids are generally known as excellent heat conductors, amorphous materials or glasses as thermal insulators. It has thus come as a surprise that certain crystal structures defy this paradigm. A prominent example are type-I…

Thermoelectric device is a promising next-generation energy solution owing to its capability to transform waste heat into useful electric energy, which can be realized in materials with high elec- tric conductivities and low thermal…

材料科学 · 物理学 2018-07-10 Kisung Chae , Seoung-Hun Kang , Seon-Myeong Choi , Duck Young Kim , Young-Woo Son

Substitution of Cu for Ni in the Kondo lattice system CeNi$_2$Al$_3$ results in a simultaneous optimization of the three interdependent thermoelectric parameters: thermoelectric power, electrical and thermal conductivities, where the…

强关联电子 · 物理学 2015-05-14 Peijie Sun , Tusyoshi Ikeno , Toshio Mizushima , Yosikazu Isikawa

Type-I clathrate compounds have attracted a great deal of interest in connection with the search for efficient thermoelectric materials. These compounds constitute networked cages consisting of nano-scale tetrakaidecahedrons (14 hedrons)…

材料科学 · 物理学 2014-06-06 Toshiro Takabatake , Koichiro Suekuni , Tsuneyoshi Nakayama , Eiji Kaneshita

Intermetallic clathrates are candidate materials for thermoelectric applications above room temperature. Here we explore whether their intrinsically low lattice thermal conductivities can be further reduced by nanostructuring and whether…

We study thermoelectric transport at low temperatures in correlated Kondo insulators, motivated by the recent observation of a high thermoelectric figure of merit(ZT) in $FeSb_2$ at $T \sim 10 K$. Even at room temperature, correlations have…

材料科学 · 物理学 2013-08-14 Seungmin Hong , Pouyan Ghaemi , Joel E. Moore , Philip W. Phillips

Ferroelectrics with spontaneous electric polarization play an essential role in today's device engineering, such as capacitors and memories. Their physical properties are further enriched by suppressing the long-range polar order, as is…

材料科学 · 物理学 2017-03-14 H. Sakai , K. Ikeura , M. S. Bahramy , N. Ogawa , D. Hashizume , J. Fujioka , Y. Tokura , S. Ishiwata

Temperature dependence S(T) of the thermoelectric power of metallic systems with cerium and ytterbium ions exhibits some characteristic features, which can be used to classify these systems into distinct categories. The experimental data…

强关联电子 · 物理学 2007-05-23 V. Zlatic , I. Milat , B. Coqblin , G. Czycholl

Thermoelectric devices convert temperature gradients into electrical power and vice versa, thus enabling energy scavenging from waste heat, sensing and cooling. Yet, many of these attractive applications are hindered by the limited…

材料科学 · 物理学 2019-02-14 Davide Donadio

Crystallographic data, Seebeck coefficient, electrical resistance and thermal conductivity are reported for a large number of rare-earth compounds, manifestations of the Kondo effect being discussed. In more detail, thermoelectric…

材料科学 · 物理学 2013-08-02 V. N. Nikiforov , V. Yu. Irkhin , A. V. Morozkin

Thermoelectric effects enable the direct conversion between thermal and electrical energy and provide an alternative route for power generation and refrigeration. The clathrate Ba8Ga16Ge30 has the highest figure of merit (ZT ~ 1) among…

材料科学 · 物理学 2011-11-16 Deepa Kasinathan , Vicente Pacheco-Espejel , Helge Rosner

Semiconductors with very low lattice thermal conductivities are highly desired for applications relevant to thermal energy conversion and management, such as thermoelectrics and thermal barrier coatings. Although the crystal structure and…

材料科学 · 物理学 2021-07-13 Jiangang He , Yi Xia , Wenwen Lin , Koushik Pal , Yizhou Zhu , Mercouri G. Kanatzidis , Chris Wolverton

We propose a junction of metal and rare-earth compound semiconductor as the basis for a possible efficient low-temperature thermoelectric device. If an overlayer of rare earth atoms differing from the bulk is placed at the interface, very…

强关联电子 · 物理学 2009-10-31 Massimo Rontani , L. J. Sham

There is evidence that magnetism can potentially increase the thermopower of materials, most likely due to magnon scattering, suggesting the incorporation of intrinsic magnetic semiconductors in non-magnetic thermoelectric materials. Here,…

Heavy fermion materials have been a rich playground for strongly correlated physics for decades. However, engineering tunable and synthesizable heavy fermion materials remains a challenge. We strive to integrate heavy fermion properties…

材料科学 · 物理学 2023-11-21 Rishi Rao , Li Zhu

Confined electrons in low dimensions host desirable material functions for downscaled electronics as well as advanced energy technologies. Thermoelectricity is a most fascinating example, since the dimensionality modifies the electron…

材料科学 · 物理学 2022-10-24 Naoki Kouda , Kyohei Eguchi , Ryuji Okazaki , Masafumi Tamura

Thermoelectric materials can be used to convert heat to electric power through the Seebeck effect. We study magneto-thermoelectric figure of merit (ZT) in three-dimensional Dirac semimetal Cd$_3$As$_2$ crystal. It is found that enhancement…

材料科学 · 物理学 2018-02-23 H. H. Wang , X. G. Luo , W. W. Chen , N. Z. Wang , B. Lei , F. B. Meng , C. Shang , L. K. Ma , T. Wu , X. Dai , Z. F. Wang , X. H. Chen

The sodium cobaltate system Na$_{x}$CoO$_2$ is a prominent representant of strongly correlated materials with promising thermoelectric response. In a combined theoretical and experimental study we show that by doping the Co site of the…

材料科学 · 物理学 2018-04-25 Raphael Richter , Denitsa Shopova , Wenjie Xie , Anke Weidenkaff , Frank Lechermann
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