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We study the effect of isoelectronic doping and external pressure in tuning the ground state of the honeycomb iridate Na$_2$IrO$_3$ by combining optical spectroscopy with synchrotron x-ray diffraction measurements on single crystals. The…

We investigate the doping effects of magnetic and nonmagnetic impurities injected to the honeycomb iridate sample of Na2IrO3 . Both the doping result in changing the ordering temperature as well as the Curie-Weiss temperature of the parent…

强关联电子 · 物理学 2020-01-06 Sujit Das , Er Jia Guo , Krishanu Roychowdhury

We have synthesized single crystals of Na$_2$(Ir$_{1-x}$Ti$_x$)O$_3$ and polycrystals of Li$_2$(Ir$_{1-x}$Ti$_x$)O$_3$ and studied the effect of magnetic depletion on the magnetic properties by measurements of the magnetic susceptibility,…

强关联电子 · 物理学 2014-06-18 S. Manni , Y. Tokiwa , P. Gegenwart

We report the successful synthesis of single-crystals of the layered iridate, (Na$_{1-x}$Li$_{x}$)$_2$IrO$_3$, $0\leq x \leq 0.9$, and a thorough study of its structural, magnetic, thermal and transport properties. The new compound allows a…

强关联电子 · 物理学 2014-01-07 G. Cao , T. F. Qi , L. Li , J. Terzic , V. S. Cao , S. J. Yuan , M. Tovar , G. Murthy , R. K. Kaul

We report the structure, magnetic, and thermal property measurements on single crystalline and polycrystalline samples of Ru substituted honeycomb lattice iridate Na$_2$Ir$_x$Ru$_{1-x}$O$_3$ (x = 0, 0.05, 0.1, 0.15, 0.2, 0.3, 0.5). The…

强关联电子 · 物理学 2015-10-20 Kavita Mehlawat , Yogesh Singh

We demonstrate that the surface of the honeycomb lattice iridate Na$_2$IrO$_3$ is extremely tunable by plasma etching. We have succeeded in turning the surface of Na$_2$IrO$_3$ metallic by Ar plasma etching which leads to the removal of Na…

强关联电子 · 物理学 2017-05-29 Kavita Mehlawat , Yogesh Singh

Single-crystal x-ray diffraction studies with synchrotron radiation on the honeycomb iridate $\alpha$-Li$_{2}$IrO$_{3}$ reveal a pressure-induced structural phase transition with symmetry lowering from monoclinic to triclinic at a critical…

Kitaev's honeycomb spin-liquid model and its proposed realization in materials such as $\alpha$-RuCl$_3$, Li$_2$IrO$_3$ and Na$_2$IrO$_3$ continue to present open questions about how the dynamics of a spin-liquid are modified in the…

强关联电子 · 物理学 2020-02-12 R. Sarkar , Z. Mei , A. Ruiz , G. Lopez , H. -H. Klauss , J. G. Analytis , I. Kimchi , N. J. Curro

We derive and study a spin one-half Hamiltonian on a honeycomb lattice describing the exchange interactions between Ir$^{4+}$ ions in a family of layered iridates $A_2$IrO$_3$ ($A$=Li,Na). Depending on the microscopic parameters, the…

强关联电子 · 物理学 2014-11-20 Jiri Chaloupka , George Jackeli , Giniyat Khaliullin

Iridates are characterized by a fascinating interplay of spin-orbit and electron-electron interactions. The honeycomb-lattice materials A2IrO3 (A=Na,Li) have been proposed to realize pseudospin-1/2 Mott insulating states with strongly…

强关联电子 · 物理学 2014-11-11 Eric C. Andrade , Matthias Vojta

We report equilibrium and nonequilibrium optical measurements on the recently synthesized "harmonic" honeycomb iridate \gamma-Li$_2$IrO$_3$ (LIO), as well as the layered honeycomb iridate Na$_2$IrO$_3$ (NIO). Using Fourier transform…

The Kitaev model of spin-1/2 on a honeycomb lattice supports degenerate topological ground states and may be useful in topological quantum computation. Na$_{2}$IrO$_{3}$ with honeycomb lattice of Ir ions have been extensively studied as…

材料科学 · 物理学 2018-10-03 Kaige Hu , Zhimou Zhou , Yi-Wen Wei , Chao-Kai Li , Ji Feng

The low-temperature magnetic properties of \tcr{polycrystalline} Na$_2$IrO$_3$, a candidate material for the realization of a quantum spin-liquid state, were investigated by means of muon-spin relaxation and nuclear magnetic resonance…

Combining thermodynamic measurements with theoretical density functional and thermodynamic calculations we demonstrate that the honeycomb lattice iridates A2IrO3 (A = Na, Li) are magnetically ordered Mott insulators where the magnetism of…

强关联电子 · 物理学 2012-03-26 Yogesh Singh , S. Manni , J. Reuther , T. Berlijn , R. Thomale , W. Ku , S. Trebst , P. Gegenwart

We report a polarized Raman scattering study of the lattice dynamics of $\beta$-Li$_2$IrO$_3$ under hydrostatic pressures up to 7.62 GPa. At ambient pressure, $\beta$-Li$_2$IrO$_3$ exhibits the hyperhoneycomb crystal structure and a…

The structural and magnetic properties of a new series of iridium-based honeycomb lattices with the formula Na3-delta(Na1-xMgx)Ir2O6 (x = 0 to 1) are reported. As x and delta are increased, the honeycomb lattice contracts and the strength…

强关联电子 · 物理学 2014-04-18 D. C. Wallace , C. M. Brown , T. M. McQueen

$Li_{2}RuO_{3}$ with a honeycomb structure undergoes a drastic transition from a regular honeycomb lattice with the $C2/m$ space group to a valence bond solid state of the $P2_{1}/m$ space group with an extremely strong dimerization at 550…

Dielectric permittivity and infrared reflectivity spectra of Li doped KNbO3 single crystals have been studied for the first time for K1-xLixNbO3 (KLN) with x = 0.015, 0.02, 0.065. It was found that like in KTaO3, Li admixture results in…

其他凝聚态物理 · 物理学 2007-05-23 V. A. Trepakov , M. L. Savinov , V Zelezny , P. P. Syrnikov , A. G. Deyneka , L. Jastrabik

The honeycomb-lattice cobaltate Na$_3$Co$_2$SbO$_6$ has recently been proposed to be a proximate Kitaev quantum spin liquid~(QSL) candidate. However, non-Kitaev terms in the Hamiltonian lead to a zigzag-type antiferromagnetic~(AFM) order at…

A new honeycomb lattice iridate (La,Na)IrO$_3$ ($\approx$ LaNaIr$_2$O$_6$) is successfully synthesized from the spin-orbit coupled Mott insulator Na$_2$IrO$_3$ by replacing the interlayer Na$^+$ ions with La$^{3+}$ ions. (La,Na)IrO$_3$…

强关联电子 · 物理学 2024-06-06 Yuya Haraguchi , Hiroko Aruga Katori
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