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A microscopic approach to the investigation of the behaviour of a symmetrical binary fluid mixture in the vicinity of the vapour-liquid critical point is proposed. It is shown that the problem can be reduced to the calculation of the…

凝聚态物理 · 物理学 2009-10-31 O. V. Patsahan , M. P. Kozlovskii , R. S. Melnyk

A binary fluid mixture of non-additive hard spheres characterized by a size ratio $\gamma=\sigma_2/\sigma_1<1$ and a non-additivity parameter $\Delta=2\sigma_{12}/(\sigma_1+\sigma_2)-1$ is considered in infinitely many dimensions. From the…

统计力学 · 物理学 2007-05-23 A. Santos , M. Lopez de Haro

Acrylic (poly(methyl methacrylate) or PMMA) is commonly used as a vessel to hold scintillating liquids in rare-event searches. Certain types of PMMA can fluoresce with a low efficiency at room temperature. We have investigated the…

仪器与探测器 · 物理学 2020-04-22 J. M. Corning , G. R. Araujo , P. C. F. Di Stefano , V. Pereymak , T. Pollmann , P. Skensved

We have measured the coexistence curve of the binary liquid mixture n-heptane+nitrobenzene near its consolute point using an optical method. In particular, the critical exponent beta describing the coexistence curve was measured for this…

无序系统与神经网络 · 物理学 2007-05-23 Nicola Fameli , David A. Balzarini

Coexistence curves in mixtures of limited miscibility with the lower critical consolute temperature (LCT), of 3-picoline with deuterium oxide (D$_2$O), and D2O/H2O have been determined. They were tested with respect to the order parameter,…

软凝聚态物质 · 物理学 2022-07-06 Jakub Kalabinski , Aleksandra Drozd-Rzoska , Sylwester J. Rzoska

2,6-lutidine molecules mix with water at high and low temperatures but in a wide intermediate temperature range a 2,6-lutidine/water mixture exhibits a miscibility gap. We constructed and validated an atomistic model for 2,6-lutidine and…

统计力学 · 物理学 2016-07-27 Faezeh Pousaneh , Olle Edholm , Anna Maciołek

The critical behavior of the Widom-Rowlinson mixture [J. Chem. Phys. 52, 1670 (1970)] is studied in d=3 dimensions by means of grand canonical Monte Carlo simulations. The finite size scaling approach of Kim, Fisher, and Luijten [Phys. Rev.…

软凝聚态物质 · 物理学 2007-05-23 R. L. C. Vink

Composites comprising Poly(Methyl Methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) via melt mixing followed by hot pressing were fabricated. These were characterized using X-ray diffraction (XRD), thermo gravimetric (TGA), scanning electron…

材料科学 · 物理学 2013-01-18 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

Optical detection of magnetic resonance enables spin-based quantum sensing with high spatial resolution and sensitivity-even at room temperature-as exemplified by solid-state defects. Molecular systems provide a complementary, chemically…

We use a two-level simulation method to analyse the critical point associated with demixing of binary hard sphere mixtures. The method exploits an accurate coarse-grained model with two-body and three-body effective interactions. Using this…

Poly(Methyl Methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) composites were fabricated via melt mixing followed by hot pressing technique. These were characterized using X-ray diffraction (XRD), thermo gravimetric (TGA), Thermo Mechanical…

材料科学 · 物理学 2013-01-21 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

The coexistence curves of the liquid-liquid equilibria (LLE) for systems of -caprolactam with heptane, octane, nonane, decane or 2,2,4-trimethylpentane have been determined by the method of the critical opalescence using a laser scattering…

A binary liquid near its consolute point exhibits critical fluctuations of the local composition; the diverging correlation length has always challenged simulations. The method of choice for the calculation of critical points in the phase…

统计力学 · 物理学 2021-04-29 Yogyata Pathania , Dipanjan Chakraborty , Felix Höfling

Structural, vibrational and dielectric properties of (Pb1-xBix)(Ti1-xMnx)O3 (PBTM) (0 x 0.50) polycrystalline ceramics have been examined as a function of temperature. Synchrotron-based powder x-ray diffraction was employed to confirm phase…

Relative permittivities, $\varepsilon_{r}$, and refractive indixes, $n_{D}$, have been measured at (288.15-308.15) K and (293.15-303.15) K, respectively, for the mixtures 1-pentanol + octane, or + dibutyl ether and dibutyl ether + octane.…

We have discovered unusual behavior of polymer coils in a binary solvent (nitroethane+isooctane) near the critical temperature of demixing. The exceptionally close refractive indices of the solvent components make the critical opalescence…

软凝聚态物质 · 物理学 2018-11-21 Xiong Zheng , Mikhail A. Anisimov , Jan V. Sengers , Maogang He

The dynamic and static critical behavior of five binary Lennard-Jones liquid mixtures, close to their continuous demixing points (belonging to the so-called model H' dynamic universality class), are studied computationally by combining…

统计力学 · 物理学 2018-03-09 Sutapa Roy , S. Dietrich , Felix Höfling

A semi-grand-canonical Monte Carlo algorithm is employed in conjunction with the bond fluctuation model to investigate the critical properties of an asymmetric binary (AB) polymer mixture. By applying the equal peak-weight criterion to the…

凝聚态物理 · 物理学 2009-10-22 M. Mueller , N. B. Wilding

Membranes containing a wide variety of ternary mixtures of high chain-melting temperature lipids, low chain-melting temperature lipids, and cholesterol undergo lateral phase separartion into coexisting liquid phases at a miscibility…

Critical opalescence is a characteristic experimental signature of a second order phase transition in solid state physics. A new, experimentally accessible measure of opacity and of attenuation length in heavy ion reactions is suggested, as…

核理论 · 物理学 2010-02-09 T. Csorgo
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