相关论文: Reactions between cold methyl halide molecules and…
We present a detailed analysis of the molecular kinetics of CHCl$_3$ in a range of temperatures covering the solid and liquid phases. Using nuclear quadrupolar resonance we determine the relaxation times for the molecular rotations in solid…
The multipole response of nuclei at temperatures T=0-2 MeV is studied using a self-consistent finite-temperature RPA (random phase approximation) based on relativistic energy density functionals. Illustrative calculations are performed for…
Interfaces play a crucial role in energy transport at the nanoscale. However, direct experimental observations of interfacial thermal conductance across molecular junctions have remained challenging due to the high spatiotemporal resolution…
We explore the possible existence of light $\phi$-mesic nuclei using HAL QCD $\phi N$ interactions for the $^2S_{1/2}$ and $^4S_{3/2}$ channels. Particularly, using the Faddeev formalism in configuration space, the $\phi NN$ system, and…
In this work, we report results from our extensive spectroscopic study on AlF and AlCl molecules, keeping in mind potential laboratory as well as astrophysical applications. We carry out detailed electronic structure calculations in both…
Silicon monosulfide is an important silicon bearing molecule detected in circumstellar envelopes and star forming regions. Its formation and destruction routes are not well understood, partially due to the lack of a detailed knowledge on…
We have investigated the chemistry of ${\rm C + H_3^+}$ forming CH$^+$, CH$_2^+$, and CH$_3^+$. These reactions are believed to be some of the key gas-phase astrochemical processes initiating the formation of organic molecules in molecular…
Nuclear processes in solid environment are investigated. It is shown that if a slow, quasi-free heavy particle of positive charge interacts with a "free" electron of a metallic host, it can obtain such a great magnitude of momentum in its…
We investigate the pre-equilibrium dipole response in the charge-asymmetric reaction $^{40}$Ca+$^{152}$Sm, of recent experimental interest, at several beam energies within the range $[5, 11]$ AMeV and different collision centralities. By…
The first three electronically excited states in the alkaline-earth-metal atoms magnesium, calcium, and strontium comprise the (nsnp) triplet P^o_J (J=0,1,2) fine-structure manifold. All three states are metastable and are of interest for…
Three-charge-particle collisions with participation of ultra-slow antiprotons ($\bar{\rm{p}}$) is the subject of this work. Specifically we compute the total cross sections and corresponding thermal rates of the following three-body…
This article reviews the current state of the art in the field of cold and ultracold molecules and demonstrates that chemical reactions, inelastic collisions and dissociation of molecules at subKelvin temperatures can be manipulated with…
The reactions of carbon atoms with dihydrogen have been investigated in liquid helium droplets at $T$ = 0.37 K. A calorimetric technique was applied to monitor the energy released in the reaction. The barrierless reaction between a single…
Context: Dimethyl sulfide (DMS; CH$_3$SCH$_3$) is an organosulfur compound that has been suggested as a potential biosignature in exoplanetary atmospheres. In addition to its tentative detections toward the sub-Neptune planet K2-18b, DMS…
Chemical reactions involve the movement of charges, and this work presents a mathematical model for describing chemical reactions in electrolytes. The model is developed using an energy variational method that aligns with classical…
The physical mechanism of nuclear reactions at low energies caused by spatial extension of electron is considered. Nuclear reactions of this type represent intra-electronic processes, more precisely, the processes occurring inside the area…
Electrochemical kinetics at electrode-electrolyte interfaces limit performance of devices including fuel cells and batteries. While the importance of moving beyond Butler-Volmer kinetics and incorporating the effect of electronic density of…
We study the conversion of bulk Se and Te, consisting of intertwined a helices, to structurally very dissimilar, atomically thin two-dimensional (2D) layers of these elements. Our ab initio calculations reveal that previously unknown and…
By employing single charge injections with an atomic force microscope, we investigated redox reactions of a molecule on a multilayer insulating film. First, we charged the molecule positively by attaching a single hole. Then we neutralized…
Due to the development of efficient algorithms and the improvement of computer power it is now possible to map out potential energy surfaces (PES) of reactions at surfaces in great detail. This achievement has been accompanied by an…