相关论文: Methyl mercaptan (CH3SH) as a probe for $\mu$ vari…

We present results from the first molecular line survey to search for the fundamental complex organic molecule, methanol (CH$_{3}$OH), in 14 Class 0/I proto-brown dwarfs (proto-BDs). IRAM 30-m observations over the frequency range of 92-116…

We present the first astrophysical detection of methanol (CH3OH) in the torsional band near 25 um. Using high resolution mid-infrared (MIR) spectroscopy, we identified over seventy gas-phase CH3OH absorption lines between 20 and 28 um…

In this study some properties of the methanol-water mixture such as diffusivity, density, viscosity, and hydrogen bonding were calculated at different temperatures and atmospheric pressure using molecular dynamics simulations (MDS). The…

We study the effect of rotation and the consequent angular momentum fluctuations in a hadron resonance gas produced in ultra-relativistic heavy ion collisions. The rotational susceptibilities ($\chi_{\rm \omega}$, $\chi^{2}_{\rm \omega}$,…

The dramatic increase in sensitivity, spectral coverage and resolution of radio astronomical facilities in recent years has opened new possibilities for observation of chemical differentiation and isotopic fractionation in protostellar…

Methyl acetate (CH_3COOCH_3) has been recently observed by IRAM 30 m radio telescope in Orion though the presence of its deuterated isotopomers is yet to be confirmed. We therefore study the properties of various forms of methyl acetate,…

We estimate limits on non-universal coupling of hypothetical hidden fields to standard matter by evaluating the fractional changes in the electron-to-proton mass ratio, mu = m_e/m_p, based on observations of ClassI methanol masers…

We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…

We report the detection of the propargyl radical (CH2CCH) in the cold dark cloud TMC-1 in the lambda 3 mm wavelength band. We recently discovered this species in space toward the same source at a wavelength of lambda 8 mm. In those…

We propose new experiments with high sensitivity to a possible spatial or temporal variation of the electron-to-proton mass ratio $\mu \equiv m_e/m_p$. We consider a nearly-degenerate pair of molecular vibrational levels, where each state…

Densities ($\rho$), speeds of sound ($c$), relative permittivities at 1 MHz ($\varepsilon_{\text{r}}$) and refractive indices at the sodium D-line ($n_{\text{D}}$) at $T$ = (293.15 K to 303.15 K) and $p$ = 0.1 MPa are reported for binary…

3-Hydroxypropenal (HOCHCHCHO) is the lower energy tautomer of malonaldehyde which displays a complex rotation-tunneling spectrum. It was detected tentatively toward the solar-type protostar IRAS 16293$-$2422 B with ALMA in the framework of…

An extensive search for the complex molecule trans-ethyl methyl ether towards several hot core regions has been performed. Using the IRAM 30m telescope and the SEST 15m we looked at several frequencies where trans-ethyl methyl ether has…

DFT calculations performed on Si_2H_6, Si_2F_6, Si_2Cl_6, and Si_2Br_6 are reported. The evolution of the energy, the chemical potential and the molecular hardness, as a function of torsion angle, is studied. Results at the…

Resonance energy transfer between chiral molecules can be used to discriminate between different enantiomers. The transfer rate between chiral molecules consists of a non-discriminatory and discriminatory parts. We derive these two rate…

The sensitivity of rotational transitions in CH and CD to a possible variation of fundamental constants has been investigated. Largely enhanced sensitivity coefficients are found for specific transitions which are due to accidental…

Intermolecular correlations in liquid acetonitrile (CH3CN) have been revisited by calculating orientational correlation functions. In the present approach, hydrogen atoms are included, so that a concept applicable for molecules of (nearly)…

Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…

The paper presents an analysis of mechanical, structural, thermophysical and spectral properties of solid methane in temperature interval $0.5T_{tr} -T_{tr}$ ($T_{tr}$ is the triple point temperature) under equilibrium vapor pressure. It is…

We present results from calculations of the physical conditions necessary for the occurrence of 36.169 ($4_{-1}-3_{0}\, E$), 44.070 ($7_{0}-6_{1}\,A^+$), 84.521 ($5_{-1}-4_{0}\,E$), and 95.169 ($8_{0}-7_{1}\,A^+$) GHz methanol (CH$_3$OH)…