相关论文: Methyl mercaptan (CH3SH) as a probe for $\mu$ vari…
Quantum mechanical tunneling inversion transition in ammonia NH3 is actively used as a sensitive tool to study possible variations of the electron-to-proton mass ratio, mu = m_e/m_p. The molecule H3O+ has the inversion barrier significantly…
Microwave and submillimeter molecular transition frequencies between nearly degenerated rotational levels, tunneling transitions, and mixed tunneling-rotational transitions show an extremely high sensitivity to the values of the…
We calculate the sensitivity of the inversion spectrum of ammonia to possible time-variation of the ratio of the proton mass to the electron mass, mu=m_p/m_e. For the inversion transition (lambda= 1.25 cm^{-1}) the relative frequency shift…
Observations of the frequencies of different rotational transitions of the methanol molecule have provided the most sensitive probe to date for changes in the proton-to-electron mass ratio, over space and time. Using methanol absorption…
Methanol is observed in a wide range of astrophysical sources throughout the universe, and comprehensive databases of the millimeter and THz spectra of CH3OH and its principal isotopologues represent important tools for the astronomical…
We estimate sensitivity coefficients Q_\mu to variation of the electron-to-proton mass ratio \mu for microwave transitions in partly deuterated ammonia NH2D and ND2H. Because of the mixing between rotational and inversion degrees of freedom…
The mass sensitivity of the vibration-rotation-inversion transitions of H$_3{}^{16}$O$^+$, H$_3{}^{18}$O$^+$, and D$_3{}^{16}$O$^+$ is investigated variationally using the nuclear motion program TROVE~\citep{TROVE:2007}. The calculations…
Using the Haystack Observatory 37-m radio telescope we have undertaken a search for emission in the 2(0)-3(1)E rotational transition of methanol in its first torsionally excited state (v_t=1) at 44.9 GHz. We examined seven galactic sources…
Near (~100 pc) and far (~8.7 kpc) relative to the Galactic center, the molecular clouds SgrB2(N) and Orion-KL exhibit different values of the fundamental physical constant mu=m_e/m_p - the electron-to-proton mass ratio. Measured frequency…
We have used the Australia Telescope Compact Array to measure the absorption from the 2(0) - 3(-1}E 12.2 GHz transition of methanol towards the z=0.89 lensing galaxy in the PKS B 1830-211 gravitational lens system. Comparison of the…
Methanol is an abundant molecule in space. The column density of CH$_3^{18}$OH is in some star-forming regions so high that the search for CH$_3^{17}$OH is promising. But only very few transition frequencies of CH$_3^{17}$OH with a…
Transitions in atoms and molecules provide an ideal test ground for constraining or detecting a possible variation of the fundamental constants of nature. In this Perspective, we review molecular species that are of specific interest in the…
A comprehensive study of the mass sensitivity of the vibration-rotation-inversion transitions of $^{14}$NH$_3$, $^{15}$NH$_3$, $^{14}$ND$_3$, and $^{15}$ND$_3$ is carried out variationally using the TROVE approach. Variational calculations…
Observations of Serpens have been performed at the JCMT using Harp-B. Maps over a 4.5'x5.4' region were made in a frequency window around 338 GHz, covering the 7-6 transitions of methanol. Emission is extended over each source, following…
We present results on simultaneous observations of Class~I methanol masers at 25, 36, and 44 GHz towards 22 Galactic targets carried out with the Effelsberg 100-m telescope. The study investigates relations between the hyperfine (HF)…
We report an extensive rotational spectroscopic analysis of singly deuterated methyl mercaptan (CH$_{2}$DSH) using both millimeter and far-infrared synchrotron spectra to achieve a global torsional analysis of the three lowest torsional…
We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…
Molecular vibrational transitions are prime candidates for model-independent searches for variation of the proton-to-electron mass ratio. Searches for present-day variation achieve highest sensitivity with deep molecular potentials. We…
We estimate sensitivity coefficients to variation of the fine-structure constant alpha and electron-to-proton mass ratio mu for microwave Lambda-type transitions in CH molecule and for inversion-rotational transitions in partly deuterated…
The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…