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The THERMOS toolkit has been developed to calculate radiative properties of plasmas. This article contains a brief survey of some of its key features used by calculation of opacities and emissivities and by analysis of specific experiments.…

等离子体物理 · 物理学 2019-10-23 I. Yu. Vichev , A. D. Solomyannaya , A. S. Grushin , D. A. Kim

Chemical modelling serves two purposes in dynamical models: accounting for the effect of microphysics on the dynamics and providing observable signatures. Ideally, the former must be done as part of the hydrodynamic simulation but this…

计算物理 · 物理学 2021-09-15 J. Holdship , S. Viti , T. J. Haworth , J. D. Ilee

An algebraic model based on Lie-algebraic and discrete symmetry techniques is applied to the analysis of thermodynamic vibrational properties of molecules. The local anharmonic effects are described by a Morse-like potential and the…

统计力学 · 物理学 2017-08-23 Maia Angelova , A. Frank

Determining the properties of molecules and materials is one of the premier applications of quantum computing. A major question in the field is: how might we use imperfect near-term quantum computers to solve problems of practical value? We…

量子物理 · 物理学 2023-08-29 Phillip W. K. Jensen , Peter D. Johnson , Alexander A. Kunitsa

Studies of quantum thermal effects on molecular excitation dynamics have often relied on oversimplified models, such as energy eigenstates or low-dimensional potentials, which fail to capture the complexity of real chemical systems. In…

化学物理 · 物理学 2025-12-30 Yankai Zhang , Yoshitaka Tanimura , So Hirata

We introduce property-independent kernels for machine learning modeling of arbitrarily many molecular properties. The kernels encode molecular structures for training sets of varying size, as well as similarity measures sufficiently diffuse…

化学物理 · 物理学 2015-03-18 Raghunathan Ramakrishnan , O. Anatole von Lilienfeld

A proof-of-concept framework for identifying molecules of unknown elemental composition and structure using experimental rotational data and probabilistic deep learning is presented. Using a minimal set of input data determined…

化学物理 · 物理学 2020-07-01 Michael C. McCarthy , Kin Long Kelvin Lee

In this introductory review, we give an overview of the computational chemistry methods commonly used in the field of metal-organic frameworks (MOFs), to describe or predict the structures themselves and characterize their various…

材料科学 · 物理学 2016-02-02 François-Xavier Coudert , Alain H. Fuchs

The calculation of the molecular column density from molecular spectral (rotational or ro-vibrational) transition measurements is one of the most basic quantities derived from molecular spectroscopy. Starting from first principles where we…

天体物理仪器与方法 · 物理学 2017-04-10 Jeffrey G. Mangum , Yancy L. Shirley

Molecular science is governed by the dynamics of electrons, atomic nuclei, and their interaction with electromagnetic fields. A reliable physicochemical understanding of these processes is crucial for the design and synthesis of chemicals…

Computational chemistry allows researchers to experiment in sillico: by running a computer simulations of a biological or chemical processes of interest. Molecular dynamics with molecular mechanics model of interactions simulates N-body…

分布式、并行与集群计算 · 计算机科学 2014-03-03 Jana Pazúriková

Evaluating multi-center molecular integrals with Cartesian Gaussian-type basis sets has been a long-standing bottleneck in electronic structure theory calculation for solids and molecules. We have developed a vector-coupling and…

量子物理 · 物理学 2024-05-17 Hang Hu , Gilles Peslherbe , Hsu Kiang Ooi , Anguang Hu

Classical algorithms for predicting the equilibrium geometry of strongly correlated molecules require expensive wave function methods that become impractical already for few-atom systems. In this work, we introduce a variational quantum…

Computational study of molecules and materials from first principles is a cornerstone of physics, chemistry, and materials science, but limited by the cost of accurate and precise simulations. In settings involving many simulations, machine…

计算物理 · 物理学 2022-03-17 Marcel F. Langer , Alex Goeßmann , Matthias Rupp

Our knowledge about the "cold" Universe often relies on molecular spectra. A general property of such spectra is that the energy level populations are rarely at local thermodynamic equilibrium. Solving the radiative transfer thus requires…

天体物理仪器与方法 · 物理学 2018-01-23 Jérôme Loreau , François Lique , Alexandre Faure

eQuilibrator (equilibrator.weizmann.ac.il) is a calculator for biochemical equilibrium constants and Gibbs free energies, originally designed as a web-based interface. While the website now counts ${\sim}1000$ distinct monthly users, its…

分子网络 · 定量生物学 2021-03-02 Moritz E. Beber , Mattia G. Gollub , Dana Mozaffari , Kevin M. Shebek , Elad Noor

In order to understand the physics phenomea on the fundamental aspects, the software simulations are a good exercise to succed in this way. Some work of heat transport and molecular physics laboratory are studied in a comparative mode…

物理教育 · 物理学 2007-05-23 Gabriel Murariu , Dorina Toma

We study the rotational and vibrational heating of diatomic molecules placed near a surface at finite temperature on the basis of macroscopic quantum electrodynamics. The internal molecular evolution is governed by transition rates that…

量子物理 · 物理学 2009-12-14 Stefan Yoshi Buhmann , M. R. Tarbutt , Stefan Scheel , E. A. Hinds

We present the graph-based molecule software Molassembler for building organic and inorganic molecules. Molassembler provides algorithms for the construction of molecules built from any set of elements from the periodic table. In…

化学物理 · 物理学 2022-05-12 Jan-Grimo Sobez , Markus Reiher