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相关论文: Long-range nature of surface-enhanced Raman scatte…

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The spectral relationships between surface enhanced resonant Raman scattering (SERRS) and plasmon resonance observed in far field scattering cross are investigated using single silver nanoparticle dimers with focusing on the lowest energy…

光学 · 物理学 2023-04-07 Tamitake Itoh , Yuko S. Yamamoto

Surface-Enhanced Raman Scattering (SERS) allows for detection and identification of molecular vibrational fingerprints in minute sample quantities. The SERS process can be also exploited for optical manipulation of molecular vibrations. We…

Giant field enhancement and field singularities are a natural consequence of the commonly employed local-response framework. We show that a more general nonlocal treatment of the plasmonic response leads to new and possibly fundamental…

We present an in-depth analysis of the experimental estimation of cross sections in Surface Enhanced Raman Scattering (SERS) by vibrational pumping. The paper highlights the advantages and disadvantages of the technique, pinpoints the main…

化学物理 · 物理学 2007-05-23 R. C. Maher , L. F. Cohen , E. C. Le Ru , P. G. Etchegoin

Tip enhanced Raman scattering (TERS) amplifies the intensity of vibrational Raman scattering by employing the tip of a probe interacting, in ultra close proximity, with a surface. Although a general understanding of the TERS process is…

Dynamic surface-enhanced Raman spectroscopy (SERS) is nowadays one of the most interesting applications of SERS, in particular for single molecule studies. In fact, it enables the study of real-time processes at the molecular level. This…

We propose an explanation for the recently measured slow fluctuations and ``blinking'' in the surface enhanced Raman scattering (SERS) spectrum of single molecules adsorbed on a silver colloidal particle. We suggest that these fluctuations…

软凝聚态物质 · 物理学 2009-11-10 D. B. Lukatsky , G. Haran , S. A. Safran

The present approach to SERS does not rely on a hihj electrical conductivity substrate or admixture to enable the SERS process. The novelty of our method is to create an artificial periodic electron distribution on a surface by illumination…

材料科学 · 物理学 2007-10-22 Martin S. Piltch , Perry C. Gray , Michael Manley

A method is proposed to pin down an unambiguous proof for single molecule surface enhanced Raman spectroscopy (SERS). The simultaneous use of two analyte molecules enables a clear confirmation of the single (or few) molecule nature of the…

化学物理 · 物理学 2007-05-23 E. C. Le Ru , M. Meyer , P. G. Etchegoin

The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…

光学 · 物理学 2014-11-17 V. P. Chelibanov , A. M. Polubotko

Surface-enhanced Raman scattering (SERS) is a critical tool for chemical sensing and spectroscopy, and a key question is how to optimally design nanostructures for maximizing SERS. We present fundamental limits on spatially-averaged SERS…

光学 · 物理学 2025-02-17 Pengning Chao , Ian M. Hammond , Steven G. Johnson

We theoretically investigate the enhancement of surface enhanced Raman spectroscopy (SERS) using hyperbolic stratified nanostructures and compare to metal nanoresonators. The photon Green function of each nanostructure within its…

Surface enhanced Raman scattering (SERS) in nanoscale hotspots has been placed great hopes upon for identification of minimum chemical traces and in-situ investigation of single molecule structures and dynamics. However, previous work…

光学 · 物理学 2016-09-19 Jing Long , Hui Yi , Hongquan Li , Tian Yang

We propose an integrated surface enhanced Raman scattering (SERS) chip based on liquid-core waveguide with total reflection, through which the depression of leaky mode enable a long propagating distance. An Raman enhancement factor for…

光学 · 物理学 2015-12-08 Chunhong Lai , Gang Chen , Li Chen , Junhui Li , Qinghao Liu , Yi Xu

Surface Enhanced Raman Spectroscopy (SERS) is exploited here to investigate the interaction of isolated sp carbon chains (polyynes) in a methanol solution with silver nanoparticles. Hydrogen-terminated polyynes show a strong interaction…

Surface-enhanced Raman spectroscopy (SERS) is a powerful tool for vibrational spectroscopy as it provides several orders of magnitude higher sensitivity than inherently weak spontaneous Raman scattering by exciting localized surface plasmon…

A periodic arrangement of chains of gold discs shows pronounced plasmonic grating resonances. These have a clear impact on the Surface Enhanced Raman Scattering (SERS)-signal from 4-methylbenzenethiol molecules which form self-assembled…

We discuss the effect of the local field polarization in metallic nanostructures where large field enhancements can be induced by excitation of localized surface plasmons. To demonstrate the importance of these effects, we study a few model…

化学物理 · 物理学 2007-05-23 E. C. Le Ru , P. G. Etchegoin

Synthesis and characterization of high-quality single-crystal WSe2 films on highly-insulating substrate is presented. We demonstrate for the first time that the presence of gold nanoparticles in the basal plane of a WSe2 film can enhance…

介观与纳米尺度物理 · 物理学 2018-11-21 Bablu Mukherjee , Wei Sun Leong , Yida Li , Hao Gong , Linfeng Sun , Ze Xiang Shen , Ergun Simsek , John T. L. Thong

The Raman scattering of light by molecular vibrations offers a powerful technique to 'fingerprint' molecules via their internal bonds and symmetries. Since Raman scattering is weak, methods to enhance, direct and harness it are highly…