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A microscopically motivated theory of glassy dynamics based on an underlying random first order transition is developed to explain the magnitude of free energy barriers for glassy relaxation. A variety of empirical correlations embodied in…

无序系统与神经网络 · 物理学 2009-10-31 Xiaoyu Xia , Peter G. Wolynes

While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…

材料科学 · 物理学 2022-11-03 Matthias Lerbinger , Armand Barbot , Damien Vandembroucq , Sylvain Patinet

The Adam-Gibbs relation between relaxation times and the configurational entropy has been tested extensively for glass formers using experimental data and computer simulation results. Although the form of the relation contains no dependence…

无序系统与神经网络 · 物理学 2015-06-05 Shiladitya Sengupta , Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

We numerically investigate the dynamics and linear rheology of disordered systems made of patchy particles, focussing on the role of valence, temperature and bonding mechanism. We demonstrate that the dynamics is enslaved to bonding, giving…

软凝聚态物质 · 物理学 2024-03-20 Samuel S. Gomez , Lorenzo Rovigatti

We review the anomalous behavior of solid He-4 at low temperatures with particular attention to the role of structural defects present in solid. The discussion centers around the possible role of two level systems and structural glassy…

材料科学 · 物理学 2013-08-27 A. V. Balatsky , M. J. Graf , Z. Nussinov , J. -J. Su

The growth of correlation lengths in equilibrium glass-forming liquids near the glass transition is considered a critical finding in the quest to understand the physics of glass formation. These understandings helped us understand various…

软凝聚态物质 · 物理学 2023-08-16 Anoop Mutneja , Smarajit Karmakar

Among all fluids, water has always been of special concern for scientists from a broad variety of research fields due to its rich behavior. In particular, some questions remain unanswered nowadays concerning the temperature dependence of…

化学物理 · 物理学 2022-07-06 Cecilia Herrero , Michela Pauletti , Gabriele Tocci , Marcella Iannuzzi , Laurent Joly

Measuring, characterizing and modelling the slow dynamics of glassy soft matter is a great challenge, with an impact that ranges from industrial applications to fundamental issues in modern statistical physics, such as the glass transition…

软凝聚态物质 · 物理学 2009-11-11 Luca Cipelletti , Laurence Ramos

Recent experiments and computer simulations show that supercooled liquids around the glass transition temperature are "dynamically heterogeneous" [1]. Such heterogeneity is expected from the random first order transition theory of the glass…

无序系统与神经网络 · 物理学 2009-10-31 Xiaoyu Xia , Peter G. Wolynes

Understanding the connection between thermodynamics and dynamics in glass-forming liquids remains a central challenge in condensed matter physics. In this study, we investigate a novel model system that enables a continuous crossover from a…

软凝聚态物质 · 物理学 2025-05-30 Ehtesham Anwar , Ujjwal Kumar Nandi , Palak Patel , Sanket Kumawat , Sarika Maitra Bhattacharyya

We study the growing time scales and length scales associated with dynamical slow down for a realistic glass former, using computer simulations. We perform finite size scaling to evaluate a length scale associated with dynamical…

统计力学 · 物理学 2009-11-13 Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

State-of-the-art techniques for simulating deeply supercooled liquids require a high degree of size polydispersity to be effective. While these techniques have enabled great insight into the microscopic dynamics near the glass transition,…

软凝聚态物质 · 物理学 2023-08-10 Ilian Pihlajamaa , Corentin C. L. Laudicina , Liesbeth M. C. Janssen

The two-dimensional freezing transition is very different from its three-dimensional counterpart. In contrast, the glass transition is usually assumed to have similar characteristics in two and three dimensions. Using computer simulations…

软凝聚态物质 · 物理学 2019-06-26 Elijah Flenner , Grzegorz Szamel

We present Monte Carlo simulation results on the equilibrium relaxation dynamics in the two dimensional lattice Coulomb gas, where finite fraction $f$ of the lattice sites are occupied by positive charges. In the case of high order rational…

统计力学 · 物理学 2009-11-07 Sung Jong Lee , Bongsoo Kim , Jong-Rim Lee

The rapid rise of viscosity or relaxation time upon supercooling is universal hallmark of glassy liquids. The temperature dependence of the viscosity, however, is quite non universal for glassy liquids and is characterized by the system's…

软凝聚态物质 · 物理学 2022-10-12 Indrajit Tah , Sean A. Ridout , Andrea J. Liu

We consider the diffusion constant, D, of a probe particle coupled to the East model, extending previous numerical results for this model to encompass a total of twelve orders of magnitude in relaxation time, {\tau}. Our considerations thus…

统计力学 · 物理学 2013-09-24 YounJoon Jung , Soree Kim , Juan P. Garrahan , David Chandler

If a liquid is cooled rapidly to form a glass, its structural relaxation becomes retarded, producing a drastic increase in viscosity. In two dimensions, strong long-wavelength fluctuations persist, even at low temperature, making it…

软凝聚态物质 · 物理学 2019-12-25 Hayato Shiba , Takeshi Kawasaki , Kang Kim

When a liquid freezes, a change in the local atomic structure marks the transition to the crystal. When a liquid is cooled to form a glass, however, no noticeable structural change marks the glass transition. Indeed, characteristic features…

软凝聚态物质 · 物理学 2015-11-24 Samuel S. Schoenholz , Ekin D. Cubuk , Daniel M. Sussman , Efthimios Kaxiras , Andrea J Liu

Hierarchical dynamics in glass-forming systems span multiple timescales, from fast vibrations to slow structural rearrangements, appearing in both supercooled fluids and glassy states. Understanding how these diverse processes interact…

软凝聚态物质 · 物理学 2025-05-28 Wensi Sun , Yanshuang Chen , Wencheng Ji , Yi Zhou , Hua Tong , Ke Chen , Xiaosong Chen , Hajime Tanaka , Peng Tan

Glass is a microscopically disordered, solid form of matter that results when a fluid is cooled or compressed in such a fashion that it does not crystallise. Almost all types of materials are capable of glass formation -- polymers, metal…

统计力学 · 物理学 2009-10-31 Srikanth Sastry