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The spin states and electronic structure of layered perovskite La1.5Ca0.5CoO4 are investigated using fullpotential linearized augmented plane-wave method. All the computational results indicate that the Co2+ ion is in a high-spin state and…

强关联电子 · 物理学 2013-05-29 Ting Jia , Hua Wu , Guoren Zhang , Xiaoli Zhang , Ying Guo , Zhi Zeng , H. Q. Lin

We present first principles LDA+U calculations of electronic structure and magnetic state for LaCoO3 and HoCoO3. Low Spin to Intermediate Spin state transition was found in our calculations using experimental crystallographic data for both…

强关联电子 · 物理学 2009-11-10 I. A. Nekrasov , S. V. Streltsov , M. A. Korotin , V. I. Anisimov

This study reports the synthesis and characterization of nanocrystalline Ni0.5Co0.2Zn0.3BixFe2-xO4 x varis by 0.0, 0.025, 0.050, 0.075, 0.100 ferrites synthesized via the sol-gel auto combustion method.The low coercivity values 23.68 to…

We present measurements of the magnetic susceptibility and of the thermal expansion of a LaCoO$_3$ single crystal. Both quantities show a strongly anomalous temperature dependence. Our data are consistently described in terms of a…

强关联电子 · 物理学 2009-11-07 C. Zobel , M. Kriener , D. Bruns , J. Baier , M. Gr"uninger , T. Lorenz , P. Reutler , A. Revcolevschi

We present a study of delta ($\delta$) doping at LaTiO$_3$/SrTiO$_3$ (LTO/STO) interface with iso-structural antiferromagnetic perovskite LaCrO$_3$ (LCO) that dramatically alters the properties of the two dimensional electron gas (2-DEG) at…

强关联电子 · 物理学 2015-06-03 Shubhankar Das , A. Rastogi , Lijun Wu , Jin-Cheng Zheng , Z. Hossain , Yimei Zhu , R. C. Budhani

The structural properties of LaCoO3 were studied by means of high-resolution neutron powder diffraction in the temperature range 5<T<1000 K. Changes of the Co+3 spin states in this temperature interval are shown to affect not only the unit…

强关联电子 · 物理学 2009-11-07 Paolo G. Radaelli , Sang-Wook Cheong

We investigate the doping dependence of the nanoscale electronic and magnetic inhomogeneities in the hole-doping range 0.002<x<0.1 of cobalt based perovskites, La{1-x}Sr_xCoO_3. Using single crystal inelastic neutron scattering and…

We use the x-ray diffraction, magnetic susceptibility, isothermal magnetization, and photoelectron spectroscopy to study the structural, magnetic and electronic properties of La$_{(1-x)}$$A_x$CoO$_3$ ($A=$ Sr, Ca; $x=$ 0 -- 0.2)…

介观与纳米尺度物理 · 物理学 2017-09-07 Ravi Prakash , Rishabh Shukla , Priyanka , Anita Dhaka , R. S. Dhaka

Using soft x-ray absorption spectroscopy and magnetic circular dichroism at the Co-$L_{2,3}$ edge we reveal that the spin state transition in LaCoO$_{3}$ can be well described by a low-spin ground state and a triply-degenerate high-spin…

The role of doping Fe on the structural, magnetic and dielectric properties of frustrated antiferromagnet YMn1-xFexO3 (x less than or equal to 0.5) has been investigated. The neutron diffraction analysis shows that the structure of these…

材料科学 · 物理学 2014-05-28 Neetika Sharma , A. Das , S. K. Mishra , C. L. Prajapat , M. R. Singh , S. S. Meena

The electronic and magnetic states in doped perovskite cobaltites, (La, Sr)CoO_3, are studied in the numerically exact diagonalization method on Co_2O_{11} clusters. For realistic parameter values, it is shown that a high spin state and an…

强关联电子 · 物理学 2009-10-31 K. Tsutsui , J. Inoue , S. Maekawa

We have measured the electrical resistivity and the thermopower of the electron-doped perovskite cobaltites LaCo$_{1-y}$Te$_y$O$_3$. In contrast to the hole-doped systems such as metallic ferromagnets La$_{1-x}M_x$CoO$_3$ ($M$ = Ca, Sr,…

强关联电子 · 物理学 2022-02-02 Ryuji Okazaki , Keisuke Tomiyasu

Inelastic neutron scattering (INS), electron spin (ESR) and nuclear magnetic resonance (NMR) measurements were employed to establish the origin of the strong magnetic signal in lightly hole-doped La_{1-x}Sr_xCoO_3, x=0.002. Both, INS and…

We present a study of the structure, the electric resistivity, the magnetic susceptibility, and the thermal expansion of La$_{1-x}$Eu$_x$CoO$_3$. LaCoO$_3$ shows a temperature-induced spin-state transition around 100 K and a metal-insulator…

强关联电子 · 物理学 2009-11-10 J. Baier , S. Jodlauk , M. Kriener , A. Reichl , C. Zobel , H. Kierspel , A. Freimuth , T. Lorenz

The nanoscopic magneto-electronic phase separation in doped La1-xSrxCoO3 perovskites was studied with local probes. The phase separation is directly observed by M\"ossbauer spectroscopy in the studied doping range of 0.05 <= x <= 0.25 both…

We present a study of modulation of spin-orbit interaction (SOI) at the interface of LaTiO$_3$/SrTiO$_3$ by $\delta$-doping with an iso-structural ferromagnetic perovskite LaCoO$_3$. The sheet carrier density at the interface decreases…

强关联电子 · 物理学 2016-10-18 Shubhankar Das , Z. Hossain , R. C. Budhani

The structural and magnetic properties of polycrystalline YMn1-xMxO3 (M = Ti, Fe, Ga; x = 0, 0.1) have been studied by neutron powder diffraction and magnetic measurements to probe the effect of Mn site doping on the frustration behavior…

材料科学 · 物理学 2013-08-13 Neetika , A. Das , C. L. Prajapat , S. S. Meena

Hexagonal RMnO3 is a multiferroic compound with a giant spin-lattice coupling at an antiferromagnetic transition temperature [1]. Despite extensive studies over the past two decades, however, the origin and underlying microscopic mechanism…

强关联电子 · 物理学 2017-03-08 Seongil Choi , Hasung Sim , Sunmin Kang , Ki-Young Choi , Je-Geun Park

Spin fluctuations have been generally believed as the pairing glue of high-$T_c$ superconductivity. Recent inelastic neutron scattering (INS) studies have revealed a weak flat spin-fluctuation signal around 45 meV in the bilayer nickelate…

The electronic structure of the perovskite LaCoO$_3$ for different spin states of Co ions was calculated in the LDA+U approach. The ground state was found to be a nonmagnetic insulator with Co ions in a low-spin state. Somewhat higher in…

强关联电子 · 物理学 2008-02-03 M. A. Korotin , S. Yu. Ezhov , I. V. Solovyev , V. I. Anisimov , D. I. Khomskii , G. A. Sawatzky