相关论文: Structural phase transition below 250 K in superco…

We investigate the high-pressure phase of the iron-based superconductor FeSe$_{0.89}$S$_{0.11}$ using transport and tunnel diode oscillator studies. We construct detailed pressure-temperature phase diagrams that indicate that outside of the…

The optical properties of the iron-chalcogenide superconductor K{0.8}Fe{2-y}Se2, with a critical temperature Tc = 31 K, have been measured over a wide frequency range in the a-b planes above and below Tc. The conductivity is incoherent at…

Raman-scattering measurements are performed in K${_x}$phenanthrene with the nominal value ${x}$ ranging from 0 to 6.0 at room temperature. Based on the Raman spectra, two phases (${x}$ = 3.0 and 4.0) are observed among the…

The study of the iron-based superconductor FeSe has blossomed with the availability of high quality single crystals, obtained through flux/vapor-transport growth techniques below the structural transformation temperature of its tetragonal…

This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

Potassium intercalated FeSe has been reported as a superconductor with superconducting transition temperatures ($T_{\rm c}$'s) of 30-48 K. However, there is no clear answer to identify the relationship between the surface morphology,…

Temperature dependent single-crystal x-ray diffraction (XRD) in transmission mode probing the bulk of the newly discovered K0.8Fe1.6Se2 superconductor (Tc = 31.8 K) using synchrotron radiation is reported. A clear evidence of intrinsic…

Since there is both strong electron-phonon coupling during a ferroelectric/FE transition and superconducting/SC transition, it has been an important topic to explore superconductivity from the FE instability. Sn$_2$P$_2$Se$_6$ arouses broad…

The optical properties of the superconducting K$_{0.8}$Fe$_{1.7}$(Se$_{0.73}$S$_{0.27}$)$_2$ single crystals with a critical temperature $T_c\approx 26$ K have been measured in the {\it ab} plane in a wide frequency range using both…

We report neutron scattering and transport measurements on semiconducting Rb$_{0.8}$Fe$_{1.5}$S$_2$, a compound isostructural and isoelectronic to the well-studied $A_{0.8}$Fe$_{y}$Se$_2 (A=$ K, Rb, Cs, Tl/K) superconducting systems. Both…

The search for new superconducting materials has been spurred on by the discovery of iron-based superconductors whose structure and composition is qualitatively different from the cuprates. The study of one such material,…

We use neutron diffraction to study the temperature evolution of the average structure and local lattice distortions in insulating and superconducting potassium iron selenide K$_y$Fe$_{1.6+x}$Se$_2$. In the high temperature paramagnetic…

The quasi-skutterudite superconductor La$_3$Co$_4$Sn$_{13}$ undergoes a phase transition at $T^*=152$ K. By measuring the temperature dependence of heat capacity, electrical resistivity, and the superlattice reflection intensity using…

K$_x$Fe$_{2-y}$Se$_2$ exhibits an iron-vacancy ordering at $T_{\rm s} {\sim}270{\deg}$C and separates into two phases: a minor superconducting (iron-vacancy-disordered) phase and a major non-superconducting (iron-vacancy-ordered) phase. The…

Using muon spin rotation (\muSR) and infrared spectroscopy we investigated the recently discovered superconductor K0.73Fe1.67Se2 with Tc = 32 K. We show that the combined data can be consistently described in terms of a macroscopically…

III-VI post-transition metal chalcogenides (InSe and GaSe) are a new class of layered semiconductors, which feature a strong variation of size and type of their band gaps as a function of number of layers (N). Here, we investigate…

Spin excitations stemming from the metallic phase of the ferrochalcogenide superconductor K(0.77)Fe(1.85)Se(2) (T_c=32 K) were mapped out in the ab plane by means of the time-of-flight neutron spectroscopy. We observed a magnetic resonant…

We report here that a new superconducting phase with much higher Tc has been found in K intercalated FeSe compound with excess Fe. We successfully grew crystals by precisely controlling the starting amount of Fe. Besides the superconducting…

Structural phase transition can occur due to complex mechanisms other than simple dynamical instability, especially when the parent and daughter structure is of low dimension. This article reports such an inversion symmetry-breaking…

Raman Spectroscopic measurements are carried out to investigate the structural phase transitions as a function of composition in modified sodium niobate [(1-x) NaNbO3-xBaTiO3:NNBTx] for x=0.0 to 0.15 at room temperature. The characteristic…