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Perovskite ruthenates are fascinating playgrounds for exploring topological spin textures, but generally rely on extrinsic mechanisms to trigger the noncoplanar states. Here we report the discovery of an emergent chiral spin crystal phase…

Inorganic halide perovskites have emerged as a promising platform in a wide range of applications from solar energy harvesting to computing, and light emission. The recent advent of epitaxial thin film growth of halide perovskites has made…

介观与纳米尺度物理 · 物理学 2021-08-16 K. Nasyedkin , I. King , L. Zhang , P. Chen , L. Wang , R. J. Staples , R. R. Lunt , J. Pollanen

The electronic and magnetic properties in ABO3 perovskite oxides are extremely sensitive to lattice structure but also the dimensionality, such as the thickness in thin film form. Here, we report the thickness-dependent electro-magnetic…

材料科学 · 物理学 2022-12-26 Zeeshan Ali , Mohammad Saghayezhian , Prahald Siwakoti , Roshan Nepal , Jiandi Zhang

A combined experimental and computational investigation of coupling between polarization and epitaxial strain in highly polar ferroelectric PbZr_0.2Ti_0.8O_3 (PZT) thin films is reported. A comparison of the properties of relaxed…

Intermetallic binary compounds of europium reveal a variety of interesting phenomena due to the interconnection between two different magnetic and 4f electronic (valence) states, which are particularly close in energy. The valence states or…

强关联电子 · 物理学 2024-01-11 Sebastian Kölsch , Alfons Georg Schuck , Michael Huth

While nature provides a plethora of perovskite materials, only a few exhibits large ferroelectricity and possibly multiferroicity. The majority of perovskite materials have the non-polar CaTiO$_3$(CTO)structure, limiting the scope of their…

材料科学 · 物理学 2022-05-25 Hongwei Wang , Fujie Tang , Massimiliano Stengel , Hongjun Xiang , Qi An , Tony Low , Xifan Wu

Molecular beam epitaxy (MBE) is a state-of-the-art technique for depositing thin films with precise stoichiometric control. However, when depositing oxides of perovskite-type ABO3, this process becomes challenging as controlling the flux…

Oxide electronics relies on the availability of epitaxial oxide thin films. The extreme flexibility of the chemical composition of ABO3 perovskites and the broad spectrum of properties they cover, inspire the creativity of scientists and…

材料科学 · 物理学 2014-04-01 Florencio Sanchez , Carmen Ocal , Josep Fontcuberta

We report the epitaxial thin film synthesis of SrCu$_3$O$_4$ with infinitely stacked Cu$_3$O$_4$ layers composed of edge-sharing CuO$_4$ square-planes, using molecular beam epitaxy. Experimental and theoretical characterizations showed that…

Epitaxial ferroelectric HfO2 films are the most suitable to investigate intrinsic properties of the material and for prototyping emerging devices. Ferroelectric Hf0.5Zr0.5O2(111) films have been epitaxially stabilized on La2/3Sr1/3MnO3(001)…

材料科学 · 物理学 2020-06-05 Saul Estandía , Nico Dix , Matthew F. Chisholm , Ignasi Fina , Florencio Sánchez

The structure and microstrucutre of fully-strained BiCrO3 thin films have been investigated by X-rays diffraction and transmission electron microscopy, at room temperature. Interestingly, three structural variants are simultaneously…

Perovskite ferroelectric oxides are usually considered to be brittle materials, however, recent work [Dong et al., Science 366, 475 (2019)] demonstrated the super-elasticity in the freestanding BaTiO3 thin films. This property may originate…

材料科学 · 物理学 2020-04-15 Changqing Guo , Guohua Dong , Ziyao Zhou , Ming Liu , Houbing Huang , Jiawang Hong , Xueyun Wang

Ferromagnetic insulators play a crucial role in the development of low-dissipation quantum magnetic devices for spintronics. Epitaxial LaCoO3 thin film is a prominent ferromagnetic insulator, in which the robust ferromagnetic ordering…

材料科学 · 物理学 2022-06-17 Dongwon Shin , Sangmoon Yoon , Sehwan Song , Sungkyun Park , Ho Nyung Lee , Woo Seok Choi

The instability of ferroelectric ordering in ultra-thin films is one of the most important fundamental issues pertaining realization of a number of electronic devices with enhanced functionality, such as ferroelectric and multiferroic…

The subtle balance of electronic correlations, crystal field splitting and spin--orbit coupling in layered Ir$^{4+}$ oxides can give rise to novel electronic and magnetic phases. Experimental progress in this field relies on the synthesis…

材料科学 · 物理学 2018-08-20 A. Gutiérrez-Llorente , L. Iglesias , B. Rodríguez-González , F. Rivadulla

Epitaxial strain in transition-metal oxides can induce dramatic changes in electronic and magnetic properties. A recent study on the epitaxially strained SrCoO$_3$ thin films revealed persistent ferromagnetism even across a metal-insulator…

The metastability of the polar phase in HfO2, despite its excellent compatibility with the complementary metal-oxide-semiconductor process, remains a key obstacle for its industrial applications. Traditional stabilization approaches, such…

The synthesis of stoichiometric and epitaxial pyrochlore iridate thin films presents significant challenges yet is critical for unlocking experimental access to novel topological and magnetic states. Towards this goal, we unveil an in-situ…

Over the past few years, intensive studies of ultrathin epitaxial films of perovskite oxides have often revealed exciting properties like giant magnetoresistive tunnelling and electric field effects. Spinel oxides appear as even more…

Structural softness - often characterized by unstable phonon modes and large electromechanical responses - is a hallmark of ferroelectric perovskites like BaTiO3 or Pb(Ti,Zr)O3. Whether HfO2 ferroelectrics present any such structural…

材料科学 · 物理学 2024-12-30 Binayak Mukherjee , Natalya S. Fedorova , Jorge Íñiguez-González