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Photoirradiation of silver nanoparticles in water solution of NaNO3 (0.01M) and in dissolved DNA was investigated by spectrophotometric and thermodynamic kinetic approaches. It is shown that only the irradiated complexes AgNPs-DNA have…

生物物理 · 物理学 2012-06-22 Vasil G. Bregadze , Zaza G. Melikishvili , Tamar G. Giorgadze

The aim of the present work is spectroscopic and thermodynamic study of DNA catalytic properties in the following processes: a) redox; b) formation of inter-strand cross-links; c) performing of photo-dynamic effects; d) nanoscale resonance…

生物物理 · 物理学 2014-06-30 Vasil G. Bregadze , Zaza G. Melikishvili , Tamar G. Giorgadze

Real time laser induced fluorescence spectroscopy usage for microanalysis of DNA double helix defects is shown. The method is based on Forster resonance energy transfer (FRET) in intercalator-donor pair (acridine orange as a donor and…

Hydrogen bonding between nucleobases produces diverse DNA structural motifs, including canonical duplexes, guanine (G) quadruplexes and cytosine (C) i-motifs. Incorporating metal-mediated base pairs into nucleic acid structures can…

生物大分子 · 定量生物学 2019-05-14 Steven M. Swasey , Frederic Rosu , Stacy M. Copp , Valerie Gabelica , Elisabeth G. Gwinn

Melting and hybridization of DNA-capped gold nanoparticle networks are investigated with optical absorption spectroscopy. Single-stranded, 12-base DNA-capped gold nanoparticles are linked with complementary, single-stranded, 24-base linker…

生物物理 · 物理学 2009-11-07 Ching-Hwa Kiang

Intracellular positive ions neutralise negative charges on the phosphates of a DNA strand conferring greater strength on the hydrogen bonds that connect complementary strands into a double helix and so confer enhanced stability. Beyond a…

软凝聚态物质 · 物理学 2016-04-25 Arghya Maity , Amar Singh , Navin Singh

Recent research on silver nanowires prepared on DNA templates has focused on two fundamental applications: nano-scale circuits and sensors. Despite its broad potential, the formation kinetics of DNA-templated silver nanowires remains…

A mechanism of double strand breaking (DSB) in DNA due to the action of two electrons is considered. These are the electrons produced in the vicinity of DNA molecules due to ionization of water molecules with a consecutive emission of two…

生物物理 · 物理学 2015-06-03 Eugene Surdutovich , Andrey V. Solov'yov

The electrodynamic response of DNA in the millimeter wave range is investigated. By performing measurements under a wide range of humidity conditions and comparing the response of single strand DNA and double strand DNA, we show that the…

无序系统与神经网络 · 物理学 2015-06-24 M. Briman , N. P. Armitage , E. Helgren , G. Gruner

The structure of DNA double helix is stabilized by metal counterions condensed to a diffuse layer around the macromolecule. The dynamics of counterions in real conditions is governed by the electric fields from DNA and other biological…

生物物理 · 物理学 2020-10-27 O. O. Zdorevskyi , S. M. Perepelytsya

Structuring of DNA counterions around the double helix has been studied by the molecular dynamics method. A DNA dodecamer d(CGCGAATTCGCG) in water solution with the alkali metal counterions Na$^{+}$, K$^{+}$, and Cs$^{+}$ has been…

生物大分子 · 定量生物学 2015-03-19 O. O. Liubysh , A. V. Vlasiuk , S. M. Perepelytsya

We present a short review of various experiments that measure charge transfer and charge transport in DNA. Some general comments are made on the possible connection between 'chemistry-style' charge transfer experiments that probe…

无序系统与神经网络 · 物理学 2009-11-10 N. P. Armitage , M. Briman , G. Gruner

Changes in the medium of biological cell nucleus under ion beam action is considered as a possible cause of cell functioning disruption in the living body. As the most long-lived molecular product appeared in the cell after the passage of…

生物物理 · 物理学 2015-06-12 D. V. Piatnytskyi , O. O. Zdorevskyi , S. M. Perepelytsya , S. N. Volkov

We report experimental observations on the effect of disorder on the phase behavior of DNA-linked nanoparticle assemblies. Variation in DNA linker lengths results in different melting temperatures of the DNA-linked nanoparticle assemblies.…

生物物理 · 物理学 2009-11-11 Nolan C. Harris , Ching-Hwa Kiang

The interaction between metal atoms and nucleobases has been a topic of high interest due to the wide scientific and technological implications. Combining density functional theory simulations with a literature overview, we achieved an…

材料科学 · 物理学 2020-02-10 Leonardo Andres Espinosa Leal , Olga Lopez-Acevedo

DNA melting and hybridization is a fundamental biological process as well as a crucial step in many modern biotechnology applications. DNA confined on surfaces exhibits different behavior from that in free solutions. The system of…

生物物理 · 物理学 2007-05-23 Y. Sun , N. C. Harris , C. -H. Kiang

Due to its polyionic character the DNA double helix is stable and biologically active only in salty aqueous media where its charge is compensated by solvent counterions. Monovalent metal ions are ubiquitous in DNA environment and they are…

生物物理 · 物理学 2007-05-23 Alexey K. Mazur

Ion-mediated interaction is critical to the structure and stability of nucleic acids. Recent experiments suggest that the multivalent ion-induced aggregation of double-stranded (ds) RNAs and DNAs may strongly depend on the topological…

生物物理 · 物理学 2015-07-13 Yuan-Yan Wu , Zhong-Liang Zhang , Jin-Si Zhang , Xiao-Long Zhu , Zhi-Jie Tan

The synthesis of Ag nanoclusters in sodalime silicate glasses and silica was studied by optical absorption (OA) and electron spin resonance (ESR) experiments under both low (gamma-ray) and high (MeV ion) deposited energy density irradiation…

材料科学 · 物理学 2007-12-23 R. Espiau de Lamaestre , H. Béa , H. Bernas , J. Belloni , J. L. Marignier

TiO$_{2}$ nanoparticles (NPs) have unique photocatalytic properties, which are used in food industries, medicine, biosensorics, and solar energy conversion. Since the toxic properties of TiO$_{2}$ NPs have been insufficiently studied,…

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