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Over the past years, radiofrequency ion traps have become an attractive platform for studying chemical reactions as they enable a high degree of control over ion-molecule dynamics. In this review, we summarize techniques for the trapping…

化学物理 · 物理学 2025-10-13 Prerna Paliwal , Jutta Toscano , Stefan Willitsch

Studying chemical reactions at very low temperatures is of importance for the understanding of fundamental physical and chemical processes. At very low energies, collisions are dominated by only a few partial waves. Thus, studies in this…

化学物理 · 物理学 2017-03-30 Dongdong Zhang , Stefan Willitsch

Studies of chemical reactions by a single pair of atoms in a well defined quantum state constitute a corner stone in quantum chemistry. Yet, the number of demonstrated techniques which enable observation and control of a single chemical…

原子物理 · 物理学 2023-11-06 Or Katz , Meirav Pinkas , Nitzan Akerman , Roee Ozeri

The control of the ultracold collisions between neutral atoms is an extensive and successful field of study. The tools developed allow for ultracold chemical reactions to be managed using magnetic fields, light fields and spin-state…

原子物理 · 物理学 2017-09-05 Tomas Sikorsky , Ziv Meir , Ruti Ben-shlomi , Nitzan Akerman , Roee Ozeri

Quantum-logic techniques for state preparation, manipulation, and non-destructive interrogation are increasingly being adopted for experiments on single molecular ions confined in traps. The ability to control molecular ions on the quantum…

量子物理 · 物理学 2022-04-20 Mudit Sinhal , Stefan Willitsch

The dynamical control of tunneling processes of single particles plays a major role in science ranging from Shapiro steps in Josephson junctions to the control of chemical reactions via light in molecules. Here we show how such control can…

Cooling atoms to ultralow temperatures has produced a wealth of opportunities in fundamental physics, precision metrology, and quantum science. The more recent application of sophisticated cooling techniques to molecules, which has been…

原子物理 · 物理学 2017-09-21 John L Bohn , Ana Maria Rey , Jun Ye

Controllability of chemical reactions is an important problem in chemical engineering science. In control theory, analysis of the controllability of linear systems is well-founded, however the dynamics of chemical reactions is usually…

最优化与控制 · 数学 2015-08-14 Dániel András Drexler , János Tóth

Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…

原子物理 · 物理学 2017-01-16 Lee R. Liu , Jessie T. Zhang , Yichao Yu , Nicholas R. Hutzler , Yu Liu , Till Rosenband , Kang-Kuen Ni

Experimental setups that study laser-cooled ions immersed in baths of ultracold atoms merge the two exciting and well-established fields of quantum gases and trapped ions. These experiments benefit both from the exquisite read-out and…

原子物理 · 物理学 2022-06-30 Rianne S. Lous , Rene Gerritsma

We demonstrate a method for controlling the outcome of an ultracold chemical few-body reaction by redirecting a tunable fraction of reaction flux from one selected product channel to another one. In the reaction, three ultracold atoms…

The recent advances in single atom detection and manipulation in experiments with ultracold quantum gases are reviewed. The discussion starts with the basic principles of trapping, cooling and detecting single ions and atoms. The…

量子物理 · 物理学 2017-08-16 Herwig Ott

An increasingly large variety of molecular species are being cooled down to low energies in recent years, and innovative ideas and powerful techniques continue to emerge to gain ever more precise control of molecular motion. In this brief…

量子气体 · 物理学 2024-05-24 Tim Langen , Giacomo Valtolina , Dajun Wang , Jun Ye

We study the reaction kinetics of chemical processes occurring in the ultracold regime and systematically investigate their dynamics. Quantum entanglement is found to play a key role in driving an ultracold reaction towards a dynamical…

Progress on researches in the field of molecules at cold and ultracold temperatures is reported in this review. It covers extensively the experimental methods to produce, detect and characterize cold and ultracold molecules including…

量子物理 · 物理学 2015-05-13 Olivier Dulieu , Carlo Gabbanini

Quantum control is concerned with active manipulation of physical and chemical processes on the atomic and molecular scale. This work presents a perspective of progress in the field of control over quantum phenomena, tracing the evolution…

量子物理 · 物理学 2010-07-20 Constantin Brif , Raj Chakrabarti , Herschel Rabitz

This article reviews the current state of the art in the field of cold and ultracold molecules and demonstrates that chemical reactions, inelastic collisions and dissociation of molecules at subKelvin temperatures can be manipulated with…

原子物理 · 物理学 2015-06-26 R. V. Krems

The extraordinary success in laser cooling, trapping, and coherent manipulation of atoms has energized the efforts in extending this exquisite control to molecules. Not only are molecules ubiquitous in nature, but the control of their…

原子物理 · 物理学 2022-04-27 D. Mitra , K. H. Leung , T. Zelevinsky

We study cold heteronuclear atom ion collisions by immersing a trapped single ion into an ultracold atomic cloud. Using ultracold atoms as reaction targets, our measurement is sensitive to elastic collisions with extremely small energy…

原子物理 · 物理学 2010-10-19 Christoph Zipkes , Stefan Palzer , Lothar Ratschbacher , Carlo Sias , Michael Köhl

We investigate the thermodynamic implications of two control mechanisms of open chemical reaction networks. The first controls the concentrations of the species that are exchanged with the surroundings, while the other controls the exchange…

统计力学 · 物理学 2022-02-22 Francesco Avanzini , Massimiliano Esposito
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