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By means of Metropolis Monte Carlo simulations of a coarse-grained model for flexible polymers, we investigate how the integrated autocorrelation times of different energetic and structural quantities depend on the temperature. We show…

计算物理 · 物理学 2014-08-19 Kai Qi , Michael Bachmann

We analyze diffusion of small particles in a solid polymeric medium taking into account a short range particle-polymer interaction. The system is modeled by a particle diffusion on a ternary lattice where the sites occupied by polymer…

统计力学 · 物理学 2015-06-11 Federico Camboni , Andreas Koher , Igor M. Sokolov

We report site percolation thresholds for square lattice with neighbor interactions at various increasing ranges. Using Monte Carlo techniques we found that nearest neighbors (N$^2$), next nearest neighbors (N$^3$), next next nearest…

统计力学 · 物理学 2007-05-23 K. Malarz , S. Galam

By an efficient algorithm we evaluate exactly the disorder-averaged statistics of globally neutral self-avoiding chains with quenched random charge $q_i=\pm 1$ in monomer i and nearest neighbor interactions $\propto q_i q_j$ on square (22…

软凝聚态物质 · 物理学 2009-10-31 P. Monari , A. L. Stella

We report Monte Carlo simulations of a lattice-polymer model that can account for both polymer crystallization and liquid-liquid demixing in solutions of semiflexible homopolymers. In our model, neighboring polymer segments can have…

软凝聚态物质 · 物理学 2009-11-07 Wenbing Hu , Daan Frenkel , Vincent B. F. Mathot

The adhesion between a polymer melt and substrate is studied in the presence of chemically attached chains on the substrate surface. Extensive molecular dynamics simulations have been carried out to study the effect of temperature, tethered…

材料科学 · 物理学 2016-08-31 Scott W. Sides , Gary S. Grest , Mark J. Stevens

We present a statistical model of a dilute polymer solution in good solvent in the presence of low-molecular weight cosolvent. We investigate the conformational changes of the polymer induced by a change of the cosolvent concentration and…

统计力学 · 物理学 2014-11-10 Yu. A. Budkov , A. L. Kolesnikov , N. Georgi , M. G. Kiselev

Interest in the protein folding problem has motivated a wide range of theoretical and experimental studies of the kinetics of the collapse of flexible homopolymers. In this Paper a phenomenological model is proposed for the kinetics of the…

软凝聚态物质 · 物理学 2009-10-31 A. Halperin , Paul M. Goldbart

We investigate the internal structure of a polymer during collapse from an expanded coil to a compact globule. Collapse is more probable in local regions of high curvature, so a smoothing of the fractal polymer structure occurs that…

软凝聚态物质 · 物理学 2008-11-07 G. E. Crooks , B. Ostrovsky , Y. Bar-Yam

Collapse of the polymer chain upon the sharp decrease of solvent quality is studied. During collapse, any pair of polymer units appearing in a sufficiently close vicinity in space has the possibility with a certain probability to form an…

软凝聚态物质 · 物理学 2019-11-07 A. M. Astakhov , S. K. Nechaev , K. E. Polovnikov

We theoretically investigate the kinetics of the folding transition of a single semiflexible polymer. In the folding transition, the growth rate decrease with an increase in the number of monomers in a collapsed domain, suggesting that the…

软凝聚态物质 · 物理学 2009-11-13 Natsuhiko Yoshinaga

We study numerically the tightness of prime flat knots in a model of self-attracting polymers with excluded volume. We find that these knots are localised in the high temperature swollen regime, but become delocalised in the low temperature…

软凝聚态物质 · 物理学 2009-11-07 E. Orlandini , A. L. Stella , C. Vanderzande

A new quantitative theory for polyelectrolytes in salt free dilute solutions is developed. Depending on the electrostatic interaction strength, polyelectrolytes in solutions can undergo strong stretching (with polyelectrolyte dimension…

软凝聚态物质 · 物理学 2009-10-31 N. V. Brilliantov , D. V. Kuznetsov , R. Klein

We use an alternative approach to study the quantum phase transition in a coupled cavity lattice at finite temperature. As an illustrative example, we investigate the behaviors of the trace distance and quantum phase transition in a…

量子物理 · 物理学 2016-09-08 Da-Wei Luo , Jing-Bo Xu

Dynamics of a polymer chain in solution gets significantly affected by the temperature and the frictional forces arising due to solvent viscosity. Here, using an explicit solvent framework for polymer simulation with the liberty to tune the…

软凝聚态物质 · 物理学 2024-09-11 Suman Majumder , Henrik Christiansen , Wolfhard Janke

Molecular process of polymer collapse was reproduced by isothermal molecular dynamics simulation. The initial polymer chains were obtained by mean of random walks in continuum space. Two potential models were considered to represent short…

软凝聚态物质 · 物理学 2007-05-23 S. A. Sabeur , F. Hamdache , M. Bouarkat

We present data of Monte Carlo simulations for monodisperse linear polymer chains in dense melts with degrees of polymerization between N=16 and N=512. The aim of this study is to investigate the crossover from Rouse-like dynamics for short…

软凝聚态物质 · 物理学 2009-10-31 T. Kreer , J. Baschnagel , M. Mueller , K. Binder

We have simulated four-dimensional interacting self-avoiding trails (ISAT) on the hyper-cubic lattice with standard interactions at a wide range of temperatures up to length 4096 and at some temperatures up to length 16384. The results…

统计力学 · 物理学 2009-11-07 Thomas Prellberg , Aleksander L. Owczarek

The surface critical behaviour of the interacting self-avoiding trail is examined using transfer matrix methods coupled with finite-size scaling. Particular attention is paid to the critical exponents at the ordinary and special points…

统计力学 · 物理学 2015-05-19 Damien P Foster

We consider the thermodynamics of a uniformly charged polyelectrolyte with harmonic bonds. For such a system there is at high temperatures an approximate scaling of global properties like the end-to-end distance and the interaction energy…

chem-ph · 物理学 2016-08-15 Carsten Peterson , Ola Sommelius , Bo Söderberg